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Recent advances in polaritonic chemistry suggest that chemical reactions can be controlled via collective vibrational strong coupling (VSC) in a cavity. In this fully analytical work, we demonstrate that the collective vibrations of a…

Quantum Physics · Physics 2025-04-15 Vasil Rokaj , Ilia Tutunnikov , H. R. Sadeghpour

A series of experiments demonstrate that strong light-matter coupling between vibrational excitations in isotropic solutions of molecules and resonant infrared optical microcavity modes leads to modified thermally-activated kinetics.…

Chemical Physics · Physics 2020-06-23 Jorge A. Campos-Gonzalez-Angulo , Joel Yuen-Zhou

We present a detailed study of the electroluminescence of intersubband devices operating in the light-matter strong coupling regime. The devices have been characterized by performing angle resolved spectroscopy that shows two distinct light…

Mesoscale and Nanoscale Physics · Physics 2012-12-27 Pierre Jouy , Angela Vasanelli , Yanko Todorov , Luca Sapienza , Raffaele Colombelli , Ulf Gennser , Carlo Sirtori

Semiconductor nanoparticles and nanostructures in the strong coupling regime exhibit an intriguing energy scale in the optical frequencies, which is specified by the Rabi splitting between the upper and lower exciton-polariton states.…

Optics · Physics 2019-11-19 Burak Gerislioglu , Arash Ahmadivand

Thanks to their exceptional spatial, spectral and temporal resolution, highly-coherent free-electron beams have emerged as powerful probes for material excitations, enabling their characterization even in the quantum regime. Here, we…

Quantum Physics · Physics 2023-12-12 J. Abad-Arredondo , A. I. Fernández-Domínguez

Dynamically probing systems of ultrastrongly coupled light and matter by advanced coherent control has been recently proposed as a unique tool for detecting peculiar quantum features of this regime. Coherence allows in principle on-demand…

Quantum Physics · Physics 2021-05-26 A. Ridolfo , J. Rajendran , L. Giannelli , E. Paladino , G. Falci

Optical cavities provide a powerful means to engineer light-matter hybrid states by coupling confined electromagnetic fields with matter excitations. Achieving in situ control of the coupling strength is essential for investigating how such…

We study the strong coupling between the molecular excited state and the plasmonic modes of silver hole arrays with a resonant frequency very close to the asymptotic line of the plasmonic dispersion relation, at the nonlinear regime. We…

Mesoscale and Nanoscale Physics · Physics 2017-01-26 Lihi Efremushkin , Maxim Sukharev , Adi Salomon

Controlling light polarization is one of the most essential routines in modern optical technology. Since the demonstration of optical pulse shaping by spatial light modulators and its potential in controlling the quantum reaction pathways,…

Optical resonators have shown outstanding abilities to tailor chemical landscapes through enhanced light-matter interaction between confined optical modes and molecule vibrations. We propose a theoretical model to study cooperative…

Optics · Physics 2024-12-11 Mingxuan Xiao , Wei Wang , Wenjing Liu , Zheng Li , Shui-Jing Tang , Yun-Feng Xiao

Modeling the dielectric behavior of molecular materials made up of large pi-conjugated molecules is an interesting and complex task. Here we address linear polarizabilities, and the related dielectric constant, of molecular crystals and…

Chemical Physics · Physics 2007-05-23 Francesca Terenziani , Anna Painelli , Zoltan G. Soos

Maximizing the interaction between chiral light and chiral matter is pivotal for the advancement of technologies enabling optical detection that distinguishes between different handedness in chiral organic molecules. One strategy involves…

We introduce a theory of chemical equilibrium in optical microcavities, which allows us to relate equilibrium reaction quotients in different electromagnetic environments. Our theory shows that in planar microcavities under strong coupling…

Chemical Physics · Physics 2023-05-02 Kaihong Sun , Raphael F. Ribeiro

Vibrational strong coupling is emerging as a promising tool to modify molecular properties, by making use of hybrid light-matter states known as polaritons. Fabry-Perot cavities filled with organic molecules are typically used, and the…

Strong light-matter interactions facilitate not only emerging applications in quantum and non-linear optics but also modifications of materials properties. In particular the latter possibility has spurred the development of advanced…

Mesoscale and Nanoscale Physics · Physics 2021-08-17 Jakub Fojt , Tuomas P. Rossi , Tomasz J. Antosiewicz , Mikael Kuisma , Paul Erhart

Light-matter strong coupling (LMSC) is intriguing state in which light and matter are coherently hybridized inside cavity. It has been gaining widespread recognition as an excellent way for controlling material properties without any…

Optics · Physics 2024-03-19 Daichi Okada , Fumito Araoka

Recently considerable effort is devoted to the realization of the strong coupling regime of the radiation matter interaction in the context of emitter at a meta surface. The strong interaction is well realized in cavity quantum…

Quantum Physics · Physics 2018-03-01 Svend-Age Biehs , Chenran Xu , Girish S. Agarwal

The problem of coupling multiple spin ensembles through cavity photons is revisited by using PyBTM organic radicals and a high-$T_c$ superconducting coplanar resonator. An exceptionally strong coupling is obtained and up to three spin…

Mesoscale and Nanoscale Physics · Physics 2016-07-06 A. Ghirri , C. Bonizzoni , F. Troiani , N. Buccheri , L. Beverina , A. Cassinese , M. Affronte

Rayleigh scattering is usually considered to be the elastic scattering of photons from sub-wavelength physical objects, such as small particles or molecules. Here, we present the spectroscopic study of the scattering properties of molecules…

Quantum Physics · Physics 2020-04-28 Adina Golombek , Mukundakumar Balasubrahmaniyam , Maria Kaeek , Keren Hadar , Tal Schwartz

The strong coupling between molecules and photons in resonant cavities offers a new toolbox to manipulate photochemical reactions. While the quenching of photochemical reactions in the strong coupling regime has been demonstrated before,…

Mesoscale and Nanoscale Physics · Physics 2019-12-24 Jacop Fregoni , Giovanni Granucci , Maurizio Persico , Stefano Corni