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In what has been described as the fourth age of Quantum Chemistry, variational nuclear motion programs are now routinely being used to obtain the vibration-rotation levels and corresponding wavefunctions of small molecules to the sort of…

Chemical Physics · Physics 2016-09-23 Jonathan Tennyson

Astrophysical molecular spectroscopy is an important means of searching for new physics through probing the variation of the proton-to-electron mass ratio, $\mu$. New molecular probes could provide tighter constraints on the variation of…

Atomic Physics · Physics 2020-08-26 Anna-Maree Syme , Laura K. McKemmish

A procedure for calculation of rotation-vibration states of medium sized molecules is presented. It combines the advantages of variational calculations and perturbation theory. The vibrational problem is solved by diagonalizing a…

Chemical Physics · Physics 2015-04-13 A. I. Pavlyuchko , S. N. Yurchenko , Jonathan Tennyson

Boson sampling (BS) is a multimode linear optical problem that is expected to be intractable on classical computers. It was recently suggested that molecular vibronic spectroscopy (MVS) is computationally as complex as BS. In this review,…

Quantum Physics · Physics 2018-09-19 Seungbeom Chin , Joonsuk Huh

We propose new quantum algorithms for estimating spectral sums of positive semi-definite (PSD) matrices. The spectral sum of an PSD matrix $A$, for a function $f$, is defined as $ \text{Tr}[f(A)] = \sum_j f(\lambda_j)$, where $\lambda_j$…

Quantum Physics · Physics 2024-06-11 Alessandro Luongo , Changpeng Shao

The system of two $Q$-deformed oscillators coupled so that the total Hamiltonian has the su$_Q$(2) symmetry is proved to be equivalent, to lowest order approximation, to a system of two identical Morse oscillators coupled by the…

Quantum Physics · Physics 2009-10-30 Dennis Bonatsos , C. Daskaloyannis , P. Kolokotronis

With advanced fabrication techniques it is possible to make nanoscale electronic structures that have discrete energy levels. Such structures are called artificial atoms because of analogy with true atoms. Examples of such atoms are quantum…

Mesoscale and Nanoscale Physics · Physics 2012-06-07 David Gunnarsson , Jani Tuorila , Antti Paila , Jayanta Sarkar , Erkki Thuneberg , Yuriy Makhlin , Pertti Hakonen

In this introductory review, we focus on applications of quantum computation to problems of interest in physics and chemistry. We describe quantum simulation algorithms that have been developed for electronic-structure problems,…

Quantum Physics · Physics 2014-04-16 Man-Hong Yung , James D. Whitfield , Sergio Boixo , David G. Tempel , Alán Aspuru-Guzik

For decades, computational chemistry has been posited as one of the areas in which quantum computing would revolutionize. However, the algorithmic advantages that fault-tolerant quantum computers have for chemistry can be overwhelmed by…

The exact evaluation of the molecular ground state in quantum chemistry requires an exponentially increasing computational cost. Quantum computation is a promising way to overcome the exponential problem using polynomial-time quantum…

Quantum Physics · Physics 2023-05-30 Changsu Cao , Jiaqi Hu , Wengang Zhang , Xusheng Xu , Dechin Chen , Fan Yu , Jun Li , Hanshi Hu , Dingshun Lv , Man-Hong Yung

The development of tailored materials for specific applications is an active field of research in chemistry, material science and drug discovery. The number of possible molecules that can be obtained from a set of atomic species grow…

Variational quantum algorithms are hybrid quantum-classical approaches extensively studied for their potential to leverage near-term quantum hardware for computational advantages. In this work, we successfully execute two variational…

Quantum Physics · Physics 2025-01-03 Alessio Baldazzi , Matteo Sanna , Massimo Borghi , Stefano Azzini , Lorenzo Pavesi

Obtaining the free energy of large molecules from quantum mechanical energy functions is a longstanding challenge. We describe a method that allows us to estimate, at the quantum mechanical level, the harmonic contributions to the…

Chemical Physics · Physics 2023-03-07 Alec F. White , Chenghan Li , Xing Zhang , Garnet Kin-Lic Chan

We present quantum algorithms for the estimation of n-time correlation functions, the local and non-local density of states, and dynamical linear response functions. These algorithms are all based on block-encodings - a versatile technique…

Quantum Physics · Physics 2020-08-19 Patrick Rall

The calculation time for the energy of atoms and molecules scales exponentially with system size on a classical computer but polynomially using quantum algorithms. We demonstrate that such algorithms can be applied to problems of chemical…

Quantum Physics · Physics 2007-05-23 Alán Aspuru-Guzik , Anthony D. Dutoi , Peter J. Love , Martin Head-Gordon

Development of quantum architectures during the last decade has inspired hybrid classical-quantum algorithms in physics and quantum chemistry that promise simulations of fermionic systems beyond the capability of modern classical computers,…

Quantum Physics · Physics 2023-01-03 Frank T. Cerasoli , Kyle Sherbert , Jagoda Sławińska , Marco Buongiorno Nardelli

Harnessing the full power of nascent quantum processors requires the efficient management of a limited number of quantum bits with finite lifetime. Hybrid algorithms leveraging classical resources have demonstrated promising initial results…

In classical computation, a problem can be solved in multiple steps where calculated results of each step can be copied and used repeatedly. While in quantum computation, it is difficult to realize a similar multi-step computation process…

Quantum Physics · Physics 2023-01-19 Hefeng Wang , Sixia Yu , Hua Xiang

Quantum machine learning algorithms aim to take advantage of quantum computing to improve classical machine learning algorithms. In this paper, we have applied a quantum machine learning algorithm, the variational quantum classifier for the…

High Energy Physics - Lattice · Physics 2025-06-10 He-Xing Yin , Zhi-Yuan Hu , Huan-Huan Zeng , Jia-Bao Guan , Ji-ke Wang

We introduce a variational quantum algorithm to solve unconstrained black box binary optimization problems, i.e., problems in which the objective function is given as black box. This is in contrast to the typical setting of quantum…

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