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Previous experiments have shown that spherical colloidal particles relax to equilibrium slowly after they adsorb to a liquid-liquid interface, despite the large interfacial energy gradient driving the adsorption. The slow relaxation has…

Soft Condensed Matter · Physics 2016-11-08 Anna Wang , Ryan McGorty , David M. Kaz , Vinothan N. Manoharan

We present an analytical calculation of the hydrodynamic interaction between two spherical particles near an elastic interface such as a cell membrane. The theory predicts the frequency dependent self- and pair-mobilities accounting for the…

Fluid Dynamics · Physics 2016-08-03 Abdallah Daddi-Moussa-Ider , Stephan Gekle

The numerically exact evaluation of the van der Waals interaction, also known as Casimir interaction when including retardation effects, constitutes a challenging task. We present a new approach based on the plane-wave basis and demonstrate…

Soft Condensed Matter · Physics 2020-07-13 Benjamin Spreng , Paulo A. Maia Neto , Gert-Ludwig Ingold

Phospholipid monolayers at the air-water interface serve as model systems for various biological interfaces, e.g. lung surfactant layers and outer leaflets of cell membranes. Although the dynamical (viscoelastic) properties of these…

Fluid Dynamics · Physics 2009-11-19 Siyoung Q. Choi , Todd M. Squires

Dielectric interfaces are crucial to the behavior of charged membranes, from graphene to synthetic and biological lipid bilayers. Understanding electrolyte behavior near these interfaces remains a challenge, especially in the case of rough…

Soft Condensed Matter · Physics 2024-04-03 Nicholas Pogharian , Alexandre P. dos Santos , Ali Ehlen , Monica Olvera de la Cruz

Colloidal systems observed in video microscopy are often analysed using the displacements correlation matrix of particle positions. In non-thermal systems, the inverse of this matrix can be interpreted as a pair-interaction potential…

Soft Condensed Matter · Physics 2016-02-03 Michael Schindler , A. C. Maggs

We consider the surface pressure of a colloid-laden liquid interface. As micron-sized particles of suitable wettability can be irreversibly bound to the liquid interface on experimental timescales, we use the canonical ensemble to derive an…

Soft Condensed Matter · Physics 2022-03-07 R. Mears , I. Muntz , J. H. J. Thijssen

We investigate the liquid-vapor interface of the restricted primitive model (RPM) for an ionic fluid using a density-functional approximation based on correlation functions of the homogeneous fluid as obtained from the mean-spherical…

Condensed Matter · Physics 2009-10-30 B. Groh , R. Evans , S. Dietrich

Optical microscopy and multi-particle tracking are used to investigate the spatially correlated motion of weakly charged silica spheres at an air-water interface for different area fraction $n$ occupied by the particles. When the area…

Soft Condensed Matter · Physics 2012-04-11 Wei Zhang , Wei Chen , Penger Tong

Self-assembly of polymers at liquid interfaces using non-covalent interactions has emerged as a promising technique to reversibly produce self-healing membranes. Besides the assembly process, it is also crucial to control the mechanical…

Soft pair potentials predict a reentrant liquid phase for high concentrations, a behavior not observed experimentally. Here, very soft microgels confined at an oil-water interface are used as a model system of particles interacting via a…

We study a fluid-fluid phase transition of the explicit solvent model represented as a mixture of the restricted primitive model (RPM) of ionic fluid and neutral hard spherocylinders (HSC). To this end, we combine two theoretical…

Soft Condensed Matter · Physics 2022-07-26 M. Hvozd , T. Patsahan , O. Patsahan , M. Holovko

The role of electrostatics on the interfacial properties of polyelectrolyte microgels has been discussed controversially in the literature. It is not yet clear if, or how, Coulomb interactions affect their behavior under interfacial…

We study the asymptotic long-range behavior of the time-dependent correlation function of the surface charge density induced on the interface between two media of distinct dielectric functions which are in thermal equilibrium with one…

Statistical Mechanics · Physics 2016-10-26 Ladislav Samaj

Within a general theoretical framework we study the effective, deformation-induced interaction between two colloidal particles trapped at a fluid interface in the regime of small deformations. In many studies, this interaction has been…

Soft Condensed Matter · Physics 2010-06-18 Alvaro Dominguez , Martin Oettel , Siegfried Dietrich

We perform a study of the interfacial properties of a model suspension of hard sphere colloids with diameter $\sigma_c$ and non-adsorbing ideal polymer coils with diameter $\sigma_p$. For the mixture in contact with a planar hard wall, we…

Soft Condensed Matter · Physics 2009-11-11 Andrea Fortini , Marjolein Dijkstra , Matthias Schmidt , Paul P. F. Wessels

In this thesis, the electrostatic interaction between two chemically identical colloids, both carrying constant surface potential is studied in the limit of short inter-particle separation at the interface of two immiscible fluids. Using an…

Soft Condensed Matter · Physics 2020-01-01 Rick Bebon

We report experimental and computational observations of dynamic contact networks for colloidal suspensions undergoing shear thickening. The dense suspensions are comprised of sterically stabilized poly(methyl methacrylate) hard sphere…

Soft Condensed Matter · Physics 2021-10-13 Shravan Pradeep , Mohamad Nabizadeh , Alan R. Jacob , Safa Jamali , Lilian C. Hsiao

Polyelectrolyte surfactant mixtures and their interactions with fluid interfaces are an important research field due to their use in technological applications. Most of the existing knowledge on these systems is based on models in which the…

We present a collision model for particle-particle and particle-wall interactions in interface-resolved simulations of particle-laden flows. Three types of inter-particle interactions are taken into account: (1) long- and (2) short-range…

Fluid Dynamics · Physics 2021-02-23 Pedro Costa , Bendiks Jan Boersma , Jerry Westerweel , Wim-Paul Breugem