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Related papers: Simulating X-ray absorption spectra with linear-re…

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We present a new methodology for the linear-response time-dependent density functional theory (LR-TDDFT) calculation of the dynamic density response function of warm dense matter in an adiabatic approximation that can be used with any…

Computational Physics · Physics 2023-05-12 Zhandos A. Moldabekov , Michele Pavanello , Maximilian P. Boehme , Jan Vorberger , Tobias Dornheim

We have performed systematic large-scale all-electron correlated calculations on boron Bn, aluminum Aln and magnesium Mgn clusters (n=2--5), to study their linear optical absorption spectra. Several possible isomers of each cluster were…

Atomic and Molecular Clusters · Physics 2016-07-26 Ravindra Shinde

Biased enhanced sampling methods utilizing collective variables (CVs) are powerful tools for sampling conformational ensembles. Due to high intrinsic dimensions, efficiently generating conformational ensembles for complex systems requires…

Machine Learning · Computer Science 2023-12-19 Yikai Liu , Tushar K. Ghosh , Guang Lin , Ming Chen

Vision-based 3D occupancy prediction is significantly challenged by the inherent limitations of monocular vision in depth estimation. This paper introduces CVT-Occ, a novel approach that leverages temporal fusion through the geometric…

Computer Vision and Pattern Recognition · Computer Science 2024-09-26 Zhangchen Ye , Tao Jiang , Chenfeng Xu , Yiming Li , Hang Zhao

We present algebraic diagrammatic construction theory for simulating spin-orbit coupling and electron correlation in charged electronic states and photoelectron spectra. Our implementation supports Hartree-Fock and multiconfigurational…

Chemical Physics · Physics 2025-05-12 Rajat Majumder , Alexander Yu. Sokolov

Quantum--Mechanical methods that are both computationally fast and accurate are not yet available for electronic excitations having charge transfer character. In this work, we present a significant step forward towards this goal for those…

Chemical Physics · Physics 2015-06-12 Michele Pavanello , Troy Van Voorhis , Lucas Visscher , Johannes Neugebauer

Using Linear Response Theory, with appropriate wave functions and energies from perturbation method, the absorption profiles can be calculated for all three classes of mixed-valence systems as defined by Robin and Day : Class III…

Materials Science · Physics 2024-10-18 Kin Yip Wong

Time-dependent equation-of-motion coupled cluster (TD-EOM-CC) is used to simulate impulsive stimulated x-ray Raman scattering (ISXRS) of ultrashort laser pulses by neon, carbon monoxide, pyrrole, and p-aminophenol. The TD-EOM-CC equations…

Chemical Physics · Physics 2023-10-10 Alice Balbi , Andreas S. Skeidsvoll , Henrik Koch

Widely employed Near-Edge X-Ray Absorption Fine Structure (NEXAFS) spectroscopy probes a system by excitation of core electrons to unoccupied states. A variety of different methodologies are available to simulate corresponding spectra from…

Chemical Physics · Physics 2019-02-14 Georg S. Michelitsch , Karsten Reuter

We present the theory and implementation of a core-valence separated similarity transformed EOM-CCSD (STEOM-CCSD) method for K-edge core excitation spectra. The method can select an appropriate active space using CIS natural orbitals and…

Chemical Physics · Physics 2020-11-03 Santosh Ranga , Achintya Kumar Dutta

This paper is concerned with the optimal approximation of a given multivariate Dirac mixture, i.e., a density comprising weighted Dirac distributions on a continuous domain, by an equally weighted Dirac mixture with a reduced number of…

Systems and Control · Computer Science 2014-11-18 Uwe D. Hanebeck

We assess the performance of different protocols for simulating excited-state X-ray absorption spectra. We consider three different protocols based on equation-of-motion coupled-cluster singles and doubles, two of them combined with the…

Chemical Physics · Physics 2022-11-24 Shota Tsuru , Marta L. Vidal , Mátyás Pápai , Anna I. Krylov , Klaus B. Møller , Sonia Coriani

Molecular dynamics (MD) simulations are useful in obtaining thermodynamic and kinetic properties of bio-molecules but are limited by the timescale barrier, i.e., we may be unable to efficiently obtain properties because we need to run…

Chemical Physics · Physics 2017-08-23 Surl-Hee Ahn , Jay W. Grate , Eric F. Darve

An accurate treatment of electronic spectra in large systems with a technique such as time dependent density functional theory (TDDFT) is computationally challenging. Due to the Nyquist sampling theorem, direct real time simulations must be…

Materials Science · Physics 2024-01-17 Matthias Kick , Ezra Alexander , Anton Beiersdorfer , Troy Van Voorhis

Modern challenges arising in the fields of theoretical and experimental physics require new powerful tools for high-precision electronic structure modelling; one of the most perspective tools is the relativistic Fock space coupled cluster…

Computational Physics · Physics 2020-12-08 Alexander V. Oleynichenko , Andréi Zaitsevskii , Ephraim Eliav

Context. The overdensity inside a cosmological sub-volume and the tidal fields from its surroundings affect the matter distribution of the region. The resulting difference between the local and global power spectra is characterized by the…

Cosmology and Nongalactic Astrophysics · Physics 2022-05-11 Gábor Rácz , István Szapudi , István Csabai

We report an implementation of the core-valence separation approach to the 4-component relativistic Hamiltonian based equation-of-motion coupled-cluster with singles and doubles theory (CVS-EOM-CCSD), for the calculation of relativistic…

A prevailing approach for learning visuomotor policies is to employ reinforcement learning to map high-dimensional visual observations directly to action commands. However, the combination of high-dimensional visual inputs and agile…

Robotics · Computer Science 2025-10-08 Yuhang Zhang , Jiaping Xiao , Chao Yan , Mir Feroskhan

Light trapping and radiation process from linear reciprocal photonic resonators is one of the fundamental processes in optical science and engineering. Recently, the concept of coherent virtual absorption (CVA) of light was introduced and…

Optics · Physics 2020-04-01 Q. Zhong , L. Simonson , T. Kottos , R. El-Ganainy

There is an urgent need to build models to tackle Indoor Air Quality issue. Since the model should be accurate and fast, Reduced Order Modelling technique is used to reduce the dimensionality of the problem. The accuracy of the model, that…