Related papers: Screening length for finite-size ions in concentra…
Temperature gradients drive asymmetric ion distributions via thermodiffusion (the Soret effect), leading to deviations from the classical Debye--H\"uckel potential.We introduce the Eastman entropy of transfer, $\hat{S}_\pm = \alpha_\pm…
Electrostatic interactions fundamentally govern the structure and transport of electrolytes. In concentrated electrolytes, however, electrostatic and steric correlations, together with ion-solvent coupling, give rise to complex behavior,…
An ubiquitous property of plasmas is the so-called Debye shielding of the electrostatic potential. Important aspects of Debye screening concern, in particular, the investigation of non-linear charge screening effects taking place in…
We study the electric double layer by combining the effects of ion finite size and dielectric decrement. At high surface potential, both mechanisms can cause saturation of the counter-ion concentration near a charged surface. The modified…
The free energy of a weakly curved, isolated macroion embedded in a symmetric 1:1 electrolyte solution is calculated on the basis of linear Debye-H\"uckel theory, thereby accounting for non-electrostatic Yukawa pair interactions between the…
Ionic liquids offer unique bulk and interfacial characteristics as battery electrolytes. Our continuum approach naturally describes the electrolyte on a macroscale. An integral formulation for the molecular repulsion,which can be…
Previous experimental reports of long-range interactions in ionic liquids (ILs) stand in contradiction with theoretical predictions and numerical simulations. To provide insights into the literature discrepancies regarding the experimental…
Recently an improved long-range model for electrolyte solutions was developed that is applicable from infinite dilution to pure salt. This paper tests this claim for the first time applying it to the calculation of liquid-liquid equilibria…
Recent laboratory experiments have measured fusion cross sections at center-of-mass energies low enough for the effects of atomic and molecular electrons to be important. To extract the cross section for bare nuclei from these data (as…
The charge reduction effect, produced by the nonlinear Debye screening of high-Z charges occuring in strongly-coupled plasmas, is investigated. An analytic asymptotic expression is obtained for the charge reduction factor which determines…
The effect of plasma screening on the electronic and vibrational properties of the H2+ molecular ion was analyzed within the Born-Oppenheimer approximation. When a molecule is embedded in a plasma, the plasma screens the electrostatic…
Extensive Monte Carlo simulations and scaling arguments are used to study the colloidal charge reversal. The critical colloidal surface charge density $\sigma_c$ at which the reversal first appears is found to depend strongly on the ionic…
How do charge and density fluctuations compete in ionic fluids near gas-liquid criticality when quantum mechanical effects play a role ? To gain some insight, long-range $\Phi^{{\mathcal{L}}}_{\pm \pm} / r^{d+\sigma}$ interactions (with…
Hypothesis. The dielectric constant of an electrolyte solution, which determines electrostatic interactions between colloids and interfaces, depends nonlinearly on the salinity and also on the type of salt. The linear decrement at dilute…
A fundamental task of statistical physics is to predict the system's statistical properties and compare them with observable data. We formulate the theory of dipolaron solutions and analyze the screening effects for permanent and…
The effect of Coulomb interaction screening on non-relativistic free-free absorption is investigated by integrating the numerical continuum wave functions. The screened potential is taken to be in Debye-H\H{u}ckel (Yukawa) form with a…
Underscreening is a collective term for charge correlations in electrolytes decaying slower than the Debye length. Anomalous underscreening refers to phenomenology that cannot be attributed alone to steric interactions. Experiments with…
The influence of pressure on finite-nuclear-size corrections to atomic energy levels and electron-capture decay rate is investigated in confined hydrogenlike ions. The ions are modeled inside an impenetrable spherical cavity, with a…
Studies of the thermodynamics of complex coacervation of pairs of symmetric, strongly ionizable, oppositely charged polyelectrolyte chains are abundant. To generalize such understanding to asymmetric chain lengths and variable ionizability…
It is well established that the long-range component of the thermal van der Waals interaction between two semi-infinite dielectrics becomes short-range when an electrolyte is present between them, this is the well known phenomenon of…