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The stability and mechanism underlying the formation of deposits of casein micelles during ultrafiltration process were investigated by small-angle (SAXS) and ultra small-angle X-ray scattering(USAXS) which allowed us to probe the structure…

We observe that small drops of a Bacillus subtilis suspension deposited on agar strongly increase in volume while similar bacteria-void drops do not. By measuring the bacterial concentration within the drop at different heights, we show…

Soft Condensed Matter · Physics 2017-07-31 Marc Hennes , Julien Tailleur , Gaëlle Charron , Adrian Daerr

In recent experiments on sodium chloride clusters structural transitions between nanocrystals with different cuboidal shapes were detected. Here we presents results for the thermodynamics and dynamics of one of these clusters, (NaCl)35Cl-.…

Condensed Matter · Physics 2007-05-23 Jonathan Doye , David Wales

We report the behavior of particle-stabilized bubbles (armored bubbles) when exposed to various classes and concentrations of surfactants. The bubbles are non-spherical due to the jamming of the particles on the interface and are stable to…

Soft Condensed Matter · Physics 2010-11-23 Anand Bala Subramaniam , Cecile Mejean , Manouk Abkarian , Howard A. Stone

We report the presence of a correlation between the bulk and interfacial properties of electrostatic coacervate complexes. Complexes were obtained by co-assembly between cationic-neutral diblocks and oppositely charged surfactant micelles…

Soft Condensed Matter · Physics 2007-10-12 Ling Qi , Jean-Paul Chapel , Jean-Christophe Castaing , Jerome Fresnais , Jean-Francois Berret

We report on the complexation between charged-neutral block copolymers and oppositely charged surfactants studied by small-angle neutron scattering. Two block copolymers/surfactant systems are investigated, poly(acrylic…

Soft Condensed Matter · Physics 2007-05-23 Jean-Francois Berret

Long-chained surfactant solutions have found widespread use in the oil and gas industry due to a host of attractive properties. In this paper, we characterize one such commercially used viscoelastic surfactant that forms a wormlike micellar…

Soft Condensed Matter · Physics 2021-08-23 Ronak Gupta , Rodrigo Mitishita , Ian A. Frigaard , Gwynn J. Elfring

Self-assembly structures of gemini surfactants are characterized, among others, for their low CMC. This characteristic could be due to great hydrophobic parts in their molecular structures. That availability could imply great stability of…

Soft Condensed Matter · Physics 2020-04-07 Vicente Domínguez-Arca , Juan Sabín , Pablo Taboada , Luís García-Río , Gerardo Prieto

This work discusses the sedimentation stability and aging of aqueous suspension of Laponite in the presence of cetyltrimethylammonium bromide (CTAB). The concentration of Laponite was fixed at the constant level $C_l=2$ %wt, which…

Soft Condensed Matter · Physics 2015-06-16 V. Savenko , L. Bulavin , M. Rawiso , M. Loginov , E. Vorobiev , N. I. Lebovka

The self-assembly mechanism of one-end-open carbon nanotubes (CNTs) suspended in an aqueous solution was studied by molecular dynamics simulations. It was shown that two one-end-open CNTs with different diameters can coaxially self-assemble…

Mesoscale and Nanoscale Physics · Physics 2017-07-31 Hang Xiao , Xiaoyang Shi , Xi Chen

End-group-functionalized hyperbranched polymers were synthesized to act as a carbon nanotube (CNT) surfactant in aqueous solutions. Variation of the percentage of triphenylmethyl (trityl) functionalization and of the molar mass of the…

Soft Condensed Matter · Physics 2015-05-20 Ellen Bertels , Kevin Bruyninckx , Mert Kurttepeli , Mario Smet , Sara Bals , Bart Goderis

In this work, we use large-scale molecular dynamics simulations coupled to free energy calculations to identify for the first time a limit of stability (spinodal) and a change in the nucleation mechanism in aqueous NaCl solutions. This is a…

Chemical Physics · Physics 2019-05-01 Hao Jiang , Pablo G. Debenedetti , Athanassios Z. Panagiotopoulos

In recent experiments involving PNIPAM copolymers it has been observed that stable spherical nanoparticles are being formed by association of several chains in poor aqueous solution instead of aggregation. This type of mesoscopic structures…

Soft Condensed Matter · Physics 2007-05-23 E. G. Timoshenko , R. Basovsky , Yu. A. Kuznetsov

A micelle consists of monolayer of lipid molecules containing hydrophilic head and hydrophobic tail. These amphiphilic molecules in aqueous environment aggregate spontaneously into monomolecular layer held together due to hydrophobic effect…

Biological Physics · Physics 2016-08-05 David V. Svintradze

Many ionic surfactants, such as sodium dodecyl sulphate (SDS) crystallize out of solution if the temperature falls below the crystallization boundary. The crystallization temperature is impacted by solution properties, and can be decreased…

Sodium chloride (NaCl), a ubiquitous and chemically stable compound, has been considered inert under ambient conditions. Its typical B1 structure is highly isotropic without preferential direction, favoring the growth of a three-dimensional…

Materials Science · Physics 2025-01-24 Ping Ning , Yifan Tian , Guangtao Liu , Hongbo Wang , Qingyang Hu , Hanyu Liu , Mi Zhou , Yanming Ma

We report a simple route to form robust, inorganic, semi-permeable compartments composed of montmorillonite, a natural plate-like clay mineral that occurs widely in the environment. Mechanical forces due to shear in a narrow gap assemble…

Soft Condensed Matter · Physics 2011-03-14 Anand B. Subramaniam , Jiandi Wan , Arvind Gopinath , Howard A. Stone

Surfaces of surfactant-templated polyacrylamide hydrogels were imaged by atomic force microscopy (AFM), and the surface morphology was studied by numerical scaling analysis. The templated gels were formed by polymerizing acrylamide plus a…

Soft Condensed Matter · Physics 2007-05-23 Mukundan Chakrapani , S. J. Mitchell , D. H. Van Winkle , P. A. Rikvold

We develop a theoretical model for the solubilization of phospholipid bilayers by micelle-forming surfactants. Cylindrical micelles, disc-like micelles and spherical micelles are considered as alternative resultant structures. The main…

Soft Condensed Matter · Physics 2007-05-23 M. M. Kozlov , D. Lichtenberg , D. Andelman

We propose a new type of surfactants, namely, tetrazole derivatives which can be controllably removed from the nanoparticle surface. Tetrazoles are a peculiar class of heterocyclic compounds. The presence of four nitrogen atoms in the…

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