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In the quest for better energy storage solutions, the role of designing effective electrodes is crucial. Previous research has shown that using materials like single-side fluorinated graphene can improve the stability of ion insertion in…

Materials Science · Physics 2024-08-28 Yu-Hsiu Lin , Jose L. Mendoza-Cortes

$^{13}$CO molecules are intercalated under a single layer graphene film on Ru(0001) and interrogated with helium low energy ion scattering. Single scattering is used to determine the mass distribution of atomic species visible to the ion…

Mesoscale and Nanoscale Physics · Physics 2018-11-14 Tianbai Li , Jory A. Yarmoff

The electronic structure of graphene on Cu(111) and Cu(100) single crystals is investigated using low energy electron microscopy, low energy electron diffraction and angle resolved photoemission spectroscopy. On both substrates the graphene…

We present detailed multi frequency resonant Raman measurements of potassium graphite intercalation compounds (GICs). From a well controlled and consecutive in-situ intercalation and high temperature de-intercalation approach the response…

Materials Science · Physics 2013-10-25 J. C. Chacon-Torres , L. Wirtz , T. Pichler

We study the formation of epitaxial graphene on Ru(0001) using fast x-ray photoelectron spectroscopy during the growth process. The assignment of different C 1s and Ru 3d core level components and their evolution during the growth process…

Previous experimental observations for H intercalation under graphene on SiC surfaces motivate clarification of configuration stabilities and kinetic processes related to intercalation. From first-principles density-functional-theory (DFT)…

Mesoscale and Nanoscale Physics · Physics 2021-12-08 Yong Han , James W. Evans , Michael C. Tringides

We have used first-principles methods to investigate how metal atoms dispersed in the interlayer space of graphitic materials affect their hydrogen-binding properties. We have considered ideal stage-one metal-intercalated graphites of…

Materials Science · Physics 2008-06-19 Manuel Cobian , Jorge Iniguez

Graphene is a fascinating 2D material that is being widely investigated for use in electronic devices due to its unique electronic and materials properties. Also, because of its high thermal stability and inertness, it is considered a…

Mesoscale and Nanoscale Physics · Physics 2017-10-25 Tianbai Li , Jory A. Yarmoff

Epitaxial growth critically influences structural and electronic properties of organic semiconductors. Graphene serves as a prominent van der Waals template for molecular self-assembly; however, graphene on SiC is intrinsically…

Realization of a free-standing graphene is always a demanding task. Here we use scanning probe microscopy and spectroscopy to study the crystallographic structure and electronic properties of the uniform free-standing graphene layers…

Materials Science · Physics 2016-02-09 Elena Voloshina , Nikolai Berdunov , Yuriy Dedkov

Intercalation of metal atoms at the SiC(0001)-graphene (Gr) interface can provide confined 2D metal layers with interesting properties. The intercalated Pb monolayer (ML) has shown the coexistence of the Gr(10x10)-moire and a stripe phase,…

Materials Science · Physics 2024-12-10 Lin-Lin Wang , Shen Chen , Marek Kolmer , Yong Han , Michael C. Tringides

We present a comprehensive investigation of the structural and electronic properties of Sn intercalated buffer layers on SiC(0001) using low-temperature scanning tunneling microscopy and spectroscopy (LT-STM/STS), spot-profile analysis…

Mesoscale and Nanoscale Physics · Physics 2025-12-24 Huu Thoai Ngo , Zamin Mamiyev , Niklas Witt , Tim Wehling , Christoph Tegenkamp

We investigate the fine structure of graphene on iridium, which is a model for graphene weakly interacting with a transition metal substrate. Even the highest quality epitaxial graphene displays tiny imperfections, i.e. small biaxial…

Materials Science · Physics 2013-02-25 Nils Blanc , Johann Coraux , Chi Vo-Van , Alpha T. N'Diaye , Olivier Geaymond , Gilles Renaud

Graphite is the most widely used anode material in lithium-ion batteries with over 98% market share. However, despite its first application over 30 years ago, the lithium insertion processes and associated dynamics in graphite remain poorly…

The diffusion, penetration and intercalation of metallic atomic dopants is an important question for various graphite applications in engineering and nanotechnology. We have performed systematic first-principles calculations of the…

Materials Science · Physics 2022-10-19 James G. McHugh , Pavlos Mouratidis , Kenny Jolley

We show that strong coupling between graphene and the substrate is mitigated when 0.8 monolayer of Na is adsorbed and consolidated on top graphene-on-Ni(111). Specifically, the {\pi} state is partially restored near the K-point and the…

Recent intensive research on two-dimensional materials (2DMs) rekindle the interest in the intercalation of various atoms and molecules into layered compounds as a tool to manufacture 2DMs and tune their optoelectronic, magnetic and…

Mesoscale and Nanoscale Physics · Physics 2025-07-10 Arkady V. Krasheninnikov , Yung-Chang Lin , Kazu Suenaga

We present a study by Scanning Tunneling Microscopy, supported by ab initio calculations, of the interaction between graphene and monolayer (semiconducting) PtSe$_2$ as a function of the twist angle ${\theta}$ between the two layers. We…

Mesoscale and Nanoscale Physics · Physics 2023-12-22 P. Mallet , F. Ibrahim , K. Abdukayumov , A. Marty , C. Vergnaud , F. Bonell , M. Chshiev , M. Jamet , J-Y. Veuillen

The electronic and magnetic properties of the graphene/Eu/Ni(111) intercalation-like system are studied in the framework of the GGA+U approach with dispersive interactions taken into account. Intercalation of monoatomic Eu layer underneath…

Materials Science · Physics 2014-07-17 E. N. Voloshina , Yu. S. Dedkov

We describe the reversible intercalation of Na under graphene on Ir(111) by photo-dissociation of a previously adsorbed NaCl overlayer. After room temperature evaporation, NaCl adsorbs on top of graphene forming a bilayer. With a…

Materials Science · Physics 2019-04-26 I. Palacio , L. Aballe , M. Foerster , D. G. de Oteyza , M. García-Hernández , J. A. Martín-Gago