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Recent developments in the percolation theory of passivation have shown that chemical short-range order (SRO) affects the aqueous passivation behavior of alloys. However, there has been no systematic exploration to quantify these SRO…

Materials Science · Physics 2025-12-22 Abhinav Roy , Karl Sieradzki , Michael J. Waters , James M. Rondinelli , Ian D. McCue

Hydrogen embrittlement (HE) in austenitic stainless steels is advanced by hydrogen enhanced localized plasticity (HELP), typically accompanied by a transition from homogeneous to localized slip. Short-range order (SRO) in face-centered…

Short-range order (SRO) in Fe-rich Fe-Cr alloys is investigated by means of atomistic off-lattice Monte Carlo simulations in the semi-grand canonical ensemble using classical interatomic potentials. The SRO parameter defined by Cowley…

Materials Science · Physics 2010-09-03 Paul Erhart , Alfredo Caro , Magdalena Serrano de Caro , Babak Sadigh

Recent research in multi-principal element alloys (MPEAs) has increasingly focused on the exploration and exploitation of short-range order (SRO) to enhance material performance. However, the understanding of SRO formation and the precise…

Short-range ordering (SRO) in Fe-Cr has been the subject of a number of recent experimental and theoretical investigations, as ordering effects are significant for the phase stability of this technologically important alloy. Recently,…

Materials Science · Physics 2012-04-30 G. Apostolopoulos , K. Mergia , S. Messoloras

We present a thorough theoretical study of ordering phenomena in nitride ternary alloys GaInN, AlInN, and AlGaN. Using the Monte Carlo approach and energetics based on the Keating model we analyze the influence of various factors on…

Materials Science · Physics 2015-03-19 Michal Lopuszynski , Jacek A. Majewski

High entropy oxides (HEOs) are a rapidly growing class of compositionally complex ceramics in which configurational disorder is engineered to unlock novel functionality. While average crystallographic symmetry is often retained, local…

The exceptional mechanical strengths of medium and high-entropy alloys have been attributed to hardening in random solid solutions. Here, we evidence non-random chemical mixings in CrCoNi alloys, resulting from short range ordering. A novel…

Materials Science · Physics 2022-06-07 H. W. Hsiao , R. Feng , H. Ni , K. An , J. D. Poplawsky , P. K. Liaw , J. M. Zuo

Short-range order (SRO) in the cation-disordered state is a controlling factor influencing the probability of finding Li$_{4}$ tetrahedron clusters in disordered rocksalt (DRX) cathode materials. However, the prevalent Li$_4$ probability…

Materials Science · Physics 2026-03-13 Tzu-chen Liu , Steven B. Torrisi , Chris Wolverton

Local chemical order (LCO) is a key descriptor linking composition, atomic arrangement, and function in high-entropy alloys (HEAs), yet remains difficult to quantify. This Perspective highlights how X-ray absorption spectroscopy (XAS)…

Materials Science · Physics 2026-02-24 David Morris , Yonggang Yao , Peng Zhang

We develop a percolation model for face centered cubic binary alloys with chemical short-range order (SRO) to account for chemical ordering/clustering that occurs in nominally random solid solutions. We employ a lattice generation scheme…

Materials Science · Physics 2024-08-28 Abhinav Roy , Karl Sieradzki , James M. Rondinelli , Ian D. McCue

The chemical short-range order (CSRO) in the crystalline materials influences the properties and its effect is particularly important in the context of the multicomponent materials. We propose a scheme for CSRO parameter or…

Materials Science · Physics 2022-10-20 G. Anand , Swarnava Ghosh , Markus Eisenbach

Using an all-electron, first principles, Landau-type theory, we study the nature of short-range order and compositional phase stability in equiatomic refractory high entropy alloys, NbMoTa, NbMoTaW, and VNbMoTaW. We also investigate…

Materials Science · Physics 2024-03-13 Christopher D. Woodgate , Julie B. Staunton

We investigate the short-range order (SRO) and phase stability of the equiatomic CoCrFeMnNi high-entropy alloy using cluster expansion supplemented by an eigen-decomposition analysis of the SRO parameters. Our results reveal that the…

Materials Science · Physics 2026-05-19 Wei Chen , Gian-Marco Rignanese , Geoffroy Hautier

The impact of magnetism on predicted atomic short-range order in three medium- and high-entropy alloys is studied using a first-principles, all-electron, Landau-type linear response theory, coupled with lattice-based atomistic modelling. We…

Materials Science · Physics 2023-05-04 Christopher D. Woodgate , Daniel Hedlund , L. H. Lewis , Julie B. Staunton

Multi-principal element materials (MPEMs) have been attracting a rapidly growing interest due to their exceptional performance under extreme conditions, from cryogenic conditions to extreme-high temperatures and pressures. Despite the…

Materials Science · Physics 2022-11-28 Okan K. Orhan , Mewael Isiet , Mauricio Ponga , David D. O'Regan

We provide strong numerical evidence for a hidden multihyperuniform long-range order (MHLRO) in SiGeSn medium-entropy alloys (MEAs), in which the normalized infinite-wavelength composition fluctuations for all three atomic species are…

Materials Science · Physics 2021-11-23 Duyu Chen , Xinyu Jiang , Duo Wang , Houlong Zhuang , Yang Jiao

Order versus disorder in the structure of materials plays a key role in the theoretical prediction of their properties. However, this structural description appears to be ineffective for new families of materials such as high entropy alloys…

Local, or short-range, order in disordered alloys is an important and exciting phenomenon which is quantified in electron, X-ray and neutron scattering experiments. It is discussed in many excellent reviews and books, as well as in the…

Statistical Mechanics · Physics 2007-05-23 Igor Tsatskis

To investigate the formation of Mg-based long-period stacking ordered (LPSO) structure, we systematically study the preference of the short-range order (SRO) in metastable disordered phases of Mg-RE-Zn (RE = Y, La, Er, Ho, Dy, Tb) and…

Materials Science · Physics 2016-11-10 Ryohei Tanaka , Koretaka Yuge