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We report on a first-principles study of the structure of O/Rh(001) at half a monolayer of oxygen coverage, performed using density-functional theory. We find that oxygen atoms sit at the center of the black squares of a chess-board,…

Materials Science · Physics 2009-10-31 Dario Alfe` , Stefano de Gironcoli , Stefano Baroni

We have studied the chemisorption processes of O2 on the (100) surface of uranium using generalized gradient approximation to density functional theory. Dissociative adsorptions of O2 are significantly favored compared to molecular…

Strongly Correlated Electrons · Physics 2015-06-24 M. N. Huda , A. K. Ray

Strain-engineering is a powerful means to tune the polar, structural, and electronic instabilities of incipient ferroelectrics. KTaO3 is near a polar instability and shows anisotropic superconductivity in electron-doped samples. Here, we…

Over the past decades, superconducting qubits have emerged as one of the leading hardware platforms for realizing a quantum processor. Consequently, researchers have made significant effort to understand the loss channels that limit the…

Environmental oxidation has a great impact in tuning the physical, chemical and electronic properties of two-dimensional (2D) monolayers which can affect their practical applications in nanoscale engineering devices under ambient…

Materials Science · Physics 2025-11-18 Soumendra Kumar Das , Prasanjit Samal , Brahmananda Chakraborty , Sridhar Sahu

The knowledge of how oxygen atoms are distributed at a magnetic-metal / oxide, or magnetic-metal / non-magnetic-metal interface, can be an useful tool to optimize device production. Multilayered Ni81Fe19 / Ta samples consisting of 15…

Materials Science · Physics 2021-11-15 T. J. A. Mori , R. D. D. Pace , W. H. Flores , M. Carara , L. F. Schelp , L. S. Dorneles

We demonstrate a substantial reduction in two-level system loss in tantalum coplanar waveguide resonators fabricated on high-resistivity silicon substrates through the use of an ultrathin titanium sacrificial layer. A 0.2nm titanium film,…

Although (103) is a stable nominal orientation for both silicon and germanium, experimental observations revealed that in the case of silicon this surface remains disordered on an atomic scale even after careful annealing. We report here a…

Materials Science · Physics 2009-11-13 C. V. Ciobanu , F. C. Chuang , D. E. Lytle

Electronic and atomic structures of the clean, and As and Te covered Si(211) surface are studied using pseudopotential density functional method. The clean surface is found to have (2 X 1) and rebonded (1 X 1) reconstructions as stable…

Materials Science · Physics 2009-11-10 Prasenjit Sen , Inder P. Batra , S. Sivananthan , C. H. Grein , Nibir Dhar , S. Ciraci

We report a simple technique for the synthesis of uniaxially textured, metastable hexagonal close-packed-like uranium thin films with thicknesses between 175-2800 \r{A}. The initial structure and texture of the layers have been studied via…

Materials Science · Physics 2022-10-11 Rebecca Nicholls , Chris Bell , Johann Bouchet , Ross Springell , Gerard H. Lander

The evolution of titanyl-phthalocyanine (TiOPc) thin films on Ag(111) has been investigated using IRAS, SPA-LEED and STM. In the (sub)monolayer regime various phases are observed that can be assigned to a 2D gas, a commensurate and a…

We consider counterions in the presence of a single planar surface with a spatially inhomogeneous charge distribution using Monte-Carlo simulations and strong-coupling theory. For high surface charges, multivalent counterions, or pronounced…

Soft Condensed Matter · Physics 2009-11-07 Andre G Moreira , Roland R Netz

Atomic nanolines are one dimensional systems realized by assembling many atoms on a substrate into long arrays. The electronic properties of the nanolines depend on those of the substrate. Here, we demonstrate that to fully understand the…

Materials Science · Physics 2017-12-20 M. Longobardi , C. J. Kirkham , R. Villarreal , S. A. Koster , D. R. Bowler , Ch. Renner

Anatase TiO2 (a-TiO2) exhibits a strong X-ray absorption linear dichroism with the X-ray incidence angle in the pre-edge, the XANES and the EXAFS at the titanium K-edge. In the pre-edge region the behaviour of the A1-A3 and B peaks,…

We present a first-principles atomistic thermodynamics framework to describe the structure, composition and segregation profile of an alloy surface in contact with a (reactive) environment. The method is illustrated with the application to…

Materials Science · Physics 2009-11-13 John Kitchin , Karsten Reuter , Matthias Scheffler

The structure property of non-ideal Si/GaAs heterostructures that were integrated with the ultra-thin oxide (UO) tunneling interfacial layer has been systematically investigated. Si nanomembranes (NMs) were oxidized in different time…

The discovery of high-mobility two-dimensional electron gas and low carrier density superconductivity in multiple SrTiO$_3$-based heterostructures has stimulated intense interest in the surface properties of SrTiO$_3$. The recent discovery…

Mesoscale and Nanoscale Physics · Physics 2024-05-31 Cui Ding , Wenfeng Dong , Xiaotong Jiao , Zhiyu Zhang , Guanming Gong , Zhongxu Wei , Lili Wang , Jin-Feng Jia , Qi-Kun Xue

We present and discuss the results of calculations of surface relaxations and rumplings for the (001) and (011) surfaces of BaTiO3 and PbTiO3, using a hybrid B3PW description of exchange and correlation. On the (001) surfaces, we consider…

Materials Science · Physics 2009-11-13 R. I. Eglitis , David Vanderbilt

We have carried out an ab-initio study of $\alpha$-Sn (111), with the aim of predicting and understanding its structure, reconstructions, and electronic states. We consider a variety of structural possibilities, and optimize them by moving…

Condensed Matter · Physics 2009-10-28 Zhong-Yi Lu , Guido L. Chiarotti , S. Scandolo , E. Tosatti

In oxide heterostructures, different materials are integrated into a single artificial crystal, resulting in a breaking of inversion-symmetry across the heterointerfaces. A notable example is the interface between polar and non-polar…