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A framework for developing new approximate electronic structure methods is presented, in which the correlation energy of a many-electron system in the ground state is computed as in the single-reference second-order many-body perturbation…

Chemical Physics · Physics 2011-06-15 Dimitri Laikov

The energy density functional (EDF) method is very widely used in nuclear physics, and among the various existing functionals those based on the relativistic Hartree (RH) approximation are very popular because the exchange contributions…

Nuclear Theory · Physics 2014-05-16 Nguyen Van Giai , Haozhao Liang , Huai-Qiang Gu , Wenhui Long , Jie Meng

In the description of the interaction between electrons beyond the classical Hartree picture, bare exchange often yields a leading contribution. Here we discuss its effect on optical spectra of solids, comparing three different frameworks:…

Other Condensed Matter · Physics 2009-11-11 Fabien Bruneval , Francesco Sottile , Valerio Olevano , Lucia Reining

The spinless relativistic Coulomb problem is the bound-state problem for the spinless Salpeter equation (a standard approximation to the Bethe--Salpeter formalism as well as the most simple generalization of the nonrelativistic…

High Energy Physics - Phenomenology · Physics 2008-11-26 Wolfgang Lucha , Franz F. Schöberl

We study the properties of two electrons with Coulomb interactions in a tight-binding model of La-based cuprate superconductors. This tight-binding model is characterized by long-range hopping obtained previously by advanced quantum…

Superconductivity · Physics 2021-10-26 K. M. Frahm , D. L. Shepelyansky

A rigorous derivation of the density functional in the Hohenberg-Kohn theory is presented. With no assumption regarding the magnitude of the electric coupling constant $e^2$ (or correlation), this work provides a firm basis for…

Other Condensed Matter · Physics 2010-09-20 Yi-Kuo Yu

We present here a model of the exchange-correlation hole for strongly correlated systems using a simple nonlocal generalization of the Wigner--Seitz radius. The model behaves similarly to the strictly correlated electron approach, which…

Chemical Physics · Physics 2014-10-13 Lucas O. Wagner , Paola Gori-Giorgi

In the framework of density-functional theory, several popular density functionals for exchange and correlation have been constructed to satisfy a local form of the Lieb-Oxford bound. In its original global expression, the bound represents…

Other Condensed Matter · Physics 2012-05-31 J. G. Vilhena , E. Rasanen , L. Lehtovaara , M. A. L. Marques

We construct and apply an exchange-correlation functional for the one-dimensional Hubbard model. This functional has built into it the Luttinger-liquid and Mott-insulator correlations, present in the Hubbard model, in the same way in which…

Strongly Correlated Electrons · Physics 2007-05-23 K. Capelle , N. A. Lima , M. F. Silva , L. N. Oliveira

We use the two-electron wavefunctions (geminals) and the simple screened Coulomb potential proposed by Overhauser [Can. J. Phys. 73, 683 (1995)] to compute the pair-distribution function for a uniform electron gas. We find excellent…

Condensed Matter · Physics 2009-11-07 Paola Gori-Giorgi , John P. Perdew

Structural and thermodynamic properties of ionic fluids are related to those of a simpler ``mimic'' system with short ranged intermolecular interactions in a spatially varying effective field by use of Local Molecular Field (LMF) theory,…

Statistical Mechanics · Physics 2007-05-23 Yng-gwei Chen , Charanbir Kaur , John D. Weeks

This paper deals with the relativistic, quantized electromagnetic and Dirac field equations in the arena of discrete phase space and continuous time. The mathematical formulation involves partial difference equations. In the consequent…

General Physics · Physics 2021-01-26 Anadijiban Das , Rupak Chatterjee , Ting Yu

Motivated by current interest in strongly correlated quasi-one-dimensional (1D) Luttinger liquids subject to axial confinement, we present a novel density-functional study of few-electron systems confined by power-low external potentials…

Strongly Correlated Electrons · Physics 2007-05-23 S. H. Abedinpour , M. Polini , Gao Xianlong , M. P. Tosi

The Breit interaction is implemented in the no-pair variational Dirac-Coulomb (DC) framework using an explicitly correlated Gaussian basis reported in the previous paper [Paper I: P. Jeszenszki, D. Ferenc, and E. M\'atyus (2022)]. Both a…

Chemical Physics · Physics 2022-03-14 Dávid Ferenc , Péter Jeszenszki , Edit Mátyus

We introduce a generalization (gLDA) of the traditional Local Density Approximation (LDA) within density functional theory. The gLDA uses both the one-electron Seitz radius $\rs$ and a two-electron hole curvature parameter $\eta$ at each…

Chemical Physics · Physics 2015-06-18 Pierre-François Loos , Caleb J. Ball , Peter M. W. Gill

The accuracy of applying density functional theory to noncovalent interactions is hindered by errors arising from low-density regions of interaction-induced change in the density gradient, error compensation between correlation and exchange…

Chemical Physics · Physics 2014-10-22 Marcin Modrzejewski , Grzegorz Chałasiński , Małgorzata M. Szczęśniak

Semi-local density functionals for the exchange-correlation energy of electrons are extensively used as it produce realistic and accurate results for finite and extended systems. The choice of techniques play crucial role in constructing…

Materials Science · Physics 2017-11-01 Subrata Jana , Prasanjit Samal

The numerical implementation of an exchange-correlation functional is not always an accurate reproduction of its theoretical specification. For example, density functionals for exchange and correlation can be defined by an exchange or…

Materials Science · Physics 2012-11-01 Jonathan E. Moussa , Peter A. Schultz

The present work proposes to use density-functional theory (DFT) to correct for the basis-set error of wave-function theory (WFT). One of the key ideas developed here is to define a range-separation parameter which automatically adapts to a…

The electron-hole states of semiconductor quantum dots are investigated within the framework of empirical tight-binding descriptions for Si, as an example of an indirect gap material, and InAs and CdSe as examples of typical III-V and II-VI…

Condensed Matter · Physics 2009-10-31 Seungwon Lee , Lars Jonsson , John W. Wilkins , Garnett W. Bryant , Gerhard Klimeck