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Black phosphorus (BP) is a layered material with anisotropic properties. We study interfaces formed by a pentacene monolayer adsorbed on monolayer BP, a prototypical system for BP surface passivation. We place the pentacene monolayer along…

Materials Science · Physics 2022-12-09 Naseem Ud Din , Zhen-Fei Liu

We study the size-dependent exciton fine structure in monolayer black phosphorus quantum dots (BPQDs) deposited on different substrates (isolated, Si and SiO$_2$) using a combination of tight-binding method to calculate the single-particle…

Mesoscale and Nanoscale Physics · Physics 2017-07-19 J. S. de Sousa , M. A. Lino , D. R. da Costa , A. Chaves , J. M. Pereira , G. A. Farias

Anisotropy refers to the property of a material exhibiting directionally dependent features. In this paper, we introduce black phosphorous (BP), the most stable allotrope of phosphorus in layered orthorhombic structure with a bandgap of 0.3…

Mesoscale and Nanoscale Physics · Physics 2014-07-30 Fengnian Xia , Han Wang , Yichen Jia

We study the energetics of quasi-particle excitations in CsPbBr3 perovskite nanocrystals using path integral molecular dynamics simulations. Employing detailed molecular models, we elucidate the interplay of anharmonic lattice degrees of…

Chemical Physics · Physics 2023-07-14 Yoonjae Park , David T. Limmer

Low-dimensional systems based on black phosphorus (BP) have recently attracted much interest. Since the crystal structure of BP consists of 2D layers with a strong in-plane anisotropy, its electronic properties at a high magnetic field…

Mesoscale and Nanoscale Physics · Physics 2025-03-26 H. Okamura , S. Iguchi , T. Sasaki , Y. Ikemoto , T. Moriwaki , Y. Akahama

We examine the excitonic properties of layered configurations of low dimensional transition metal dichalcogenides (LTMDCs) using the fractional dimensional space approach. The binding energies of the exciton, trion and biexciton in LTMDCs…

Materials Science · Physics 2015-06-22 A. Thilagam

Phosphorene is a recently developed two-dimensional (2D) material that has attracted tremendous attention because of its unique anisotropic optical properties and quasi-one-dimensional (1D) excitons. We use first-principles calculations…

Materials Science · Physics 2024-01-09 A. F. P. de Oliveira , A. L. da Rosa , A. C. Dias

First-principles density functional theory plus Bethe-Salpeter equation calculations are employed to investigate the electronic and excitonic properties of monolayer titanium trichalcogenide alloys TiS$_{3-x}$Se$_x$ ($x$=1 and 2). It is…

Materials Science · Physics 2020-12-02 Shan Dong , Yuanchang Li

The Li2SiO3 compound, a ternary electrolyte compound of Lithium-ion based batteries, exhibits unique geometric and band structures, an atom-dominated energy spectrum, charge densities distributions, atom and orbital-projected density of…

Materials Science · Physics 2020-10-23 Nguyen Thi Han , Vo Khuong Dien , Ming-Fa Lin

Black phosphorus (BP) exhibits highly anisotropic properties and dynamical behavior that are unique even among two-dimensional and van der Waals (vdW) layered materials. Here, we show that an interlayer lattice contraction and concerted,…

Mesoscale and Nanoscale Physics · Physics 2022-07-27 Mazhar Chebl , Xing He , Ding-Shyue Yang

We report about the energy and momentum resolved optical response of black phosphorus (BP) in its bulk form. Along the armchair direction of the puckered layers we find a highly dispersive mode that is trongly suppressed in the…

Mesoscale and Nanoscale Physics · Physics 2015-03-10 R. Schuster , J. Trinckauf , M. Knupfer , B. Büchner

To date, the intrinsic thermal conductivity tensor of bulk black phosphorus (BP), an important 2D material, is still unknown, since recent studies focus on BP flakes not on bulk BP. Here we report the anisotropic thermal conductivity tensor…

Materials Science · Physics 2016-11-22 Bo Sun , Xiaokun Gu , Qingsheng Zeng , Xi Huang , Yuexiang Yan , Zheng Liu , Ronggui Yang , Yee Kan Koh

In this article, we explore the anisotropic electron energy loss spectrum (EELS) in monolayer phosphorene based on ab-initio time dependent density functional theory calculations. Similar to black phosphorous, the EELS of undoped monolayer…

Mesoscale and Nanoscale Physics · Physics 2017-07-26 Barun Ghosh , Piyush Kumar , Anmol Thakur , Yogesh Singh Chauhan , Somnath Bhowmick , Amit Agarwal

We study the mechanical and electronic properties of heterobilayers composed of black phosphorus (BP) on hexagonal boron nitride (hBN) and of blue phosphorus (\Pblue) on hBN by means of ab-intio density functional theory. Emphasis is put on…

Materials Science · Physics 2020-07-15 Baptiste Bienvenu , Hakim Amara , François Ducastelle , Lorenzo Sponza

Direct-gap materials hold promises for excitonic insulator. In contrast to indirect-gap materials, here the difficulty to distinguish from a Peierls charge density wave is circumvented. However, direct-gap materials still suffer from the…

Materials Science · Physics 2018-08-29 Zeyu Jiang , Yuanchang Li , Shengbai Zhang , Wenhui Duan

Low-dimensional materials differ from their bulk counterpart in many respects. In particular, the screening of the Coulomb interaction is strongly reduced, which can have important consequences such as the significant increase of exciton…

Phosphorene is a bidimensional material that has properties useful for semiconductor devices. In this work we studied the electronic and optical properties of this material using the $GW$ approximation and the Bethe-Salpeter equation (BSE)…

Mesoscale and Nanoscale Physics · Physics 2017-11-16 Fábio Ferreira , Ricardo Mendes Ribeiro

Black phosphorus (BP), a layered van der Waals (vdW) crystal, has unique in-plane band anisotropy and many resulting anisotropy properties such as the effective mass, electron mobility, optical absorption, thermal conductivity and plasmonic…

Materials Science · Physics 2020-08-14 Zhimin Liu , Ye Yang , Yueshao Zheng , Qinjun Chen , Yexin Feng

Black phosphorus (BP), an emerging two-dimensional (2D) material with intriguing optical properties, forms a promising building block in optics and photonics devices. In this work, we propose a simple structure composed of BP sandwiched by…

Optics · Physics 2019-09-18 Tingting Liu , Xiaoyun Jiang , Chaobiao Zhou , Shuyuan Xiao

We carry out a detailed theoretical study of the electronic and optical properties of bulk and monolayer bismuth triiodide (BiI$_{3}$), a layered metal halide, using the ab initio GW+BSE scheme with a full spinorial formulation. We discuss…