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This work concerns \emph{ab initio} calculations of the complete potential energy curve and spectroscopic constants for the ground state $X^1\Sigma_g^+$ of the beryllium dimer, Be$_2$. High accuracy and reliability of the results is one of…

The combination of the many-body Green's function $GW$ approximation and the Bethe-Salpeter equation (BSE) formalism has shown to be a promising alternative to time-dependent density-functional theory (TD-DFT) for computing vertical…

Chemical Physics · Physics 2020-06-05 Pierre-François Loos , Anthony Scemama , Ivan Duchemin , Denis Jacquemin , Xavier Blase

The Bethe-Salpeter equation (BSE) is the key equation in many-body perturbation theory based on Green's functions to access response properties. Within the $GW$ approximation to the exchange-correlation kernel, the BSE has been successfully…

Chemical Physics · Physics 2023-02-15 Roberto Orlando , Pina Romaniello , Pierre-François Loos

This review outlines the main results which show the dual nature of the chemical bond in diatomic beryllium molecule in the ground $X^1\Sigma_g^+$ state. It has been shown that the beryllium atoms are covalently bound at low-lying…

Chemical Physics · Physics 2024-12-30 A. V. Mitin , A. A. Gusev , O. Chuluunbaatar , S. I. Vinitsky , V. L. Derbov , Luong Le Hai

We investigate various approximations to the correlation energy of a H$_2$ molecule in the dissociation limit, where the ground state is poorly described by a single Slater determinant. The correlation energies are derived from the density…

Strongly Correlated Electrons · Physics 2014-05-06 Thomas Olsen , Kristian S. Thygesen

The correlation energy of the homogeneous electron gas is evaluated by solving the Bethe-Salpeter equation (BSE) beyond the Tamm-Dancoff approximation for the electronic polarisation propagator. The BSE is expected to improve upon the…

Materials Science · Physics 2016-06-15 Emanuele Maggio , Georg Kresse

Here, we build on the works of Scuseria (et al.) http://dx.doi.org/10.1063/1.3043729 and Berkelbach https://doi.org/10.1063/1.5032314 to show connections between the Bethe-Salpeter equation (BSE) formalism combined with the $GW$…

Chemical Physics · Physics 2022-12-19 Raúl Quintero-Monsebaiz , Enzo Monino , Antoine Marie , Pierre-François Loos

Ab initio QED calculations of the ground-state binding energies of berylliumlike ions are performed for the wide range of the nuclear charge number: Z=18-96. The calculations are carried out in the framework of the extended Furry picture…

Atomic Physics · Physics 2015-03-11 A. V. Malyshev , A. V. Volotka , D. A. Glazov , I. I. Tupitsyn , V. M. Shabaev , G. Plunien

We review the Bethe-Salpeter equation (BSE) approach to the calculation of electronic excitation energies of molecular systems. We recall the general Green's function many-theory formalism and give the working equations of the BSE approach…

Chemical Physics · Physics 2013-04-05 Elisa Rebolini , Julien Toulouse , Andreas Savin

We check the ab initio GW approximation and Bethe-Salpeter equation (BSE) many-body methodology against the exact solution benchmark of the hydrogen molecule H$_2$ ground state and excitation spectrum, and in comparison with the…

Chemical Physics · Physics 2021-01-27 Jing Li , Valerio Olevano

When calculating the ground-state energy of a weakly interacting Bose gas with the help of the customary contact pseudopotential, one meets an artifical ultraviolet divergence which is caused by the incorrect treatment of the true…

Statistical Mechanics · Physics 2007-05-23 Andre Eckardt , Christoph Weiss , Martin Holthaus

In this paper we present results of ab-initio calculations for the beryllium dimer with basis set of Slater-type orbitals (STOs). Nonrelativistic interaction energy of the system is determined using the frozen-core full configuration…

Chemical Physics · Physics 2015-01-21 Michał Lesiuk , Michał Przybytek , Monika Musiał , Bogumił Jeziorski , Robert Moszynski

Helium atom is the simplest many-body electronic system provided by nature. The exact solution to the Schr\"odinger equation is known for helium ground and excited states, and represents a workbench for any many-body methodology. Here, we…

Atomic Physics · Physics 2017-04-26 Jing Li , Markus Holzmann , Ivan Duchemin , Xavier Blase , Valerio Olevano

The Bethe-Salpeter equation (BSE) can provide an accurate description of low-energy optical spectra of insulating crystals - even when excitonic effects are important. However, due to high computational costs it is only possible to include…

Large-scale relativistic configuration-interaction method combined with many-body perturbation theory is consistently applied to calculations of the energy levels of the ground and inner-L-shell excited states of berylliumlike ions in the…

With the consideration of identity principle and atomic shell structure, we calculated the ground state energy of Lithium atom and Beryllium atom based on variational method, which accords quite well with the experimental results.

Atomic Physics · Physics 2025-05-20 Mei-Qin Deng , Ren-Hong Fang

We calculate the ground state energies of a system of two dipolar fermions trapped in a harmonic oscillator potential. The dipoles are assumed to be aligned parallel to each other. We perform the calculations of ground state energy as a…

Atomic and Molecular Clusters · Physics 2014-10-09 Amit K. Das , Arup Banerjee

The precision of the photoassociation spectroscopy of Yb dimer in degenerate gases is enough to improve the constraints on the new short-range gravity-like forces if the theoretical knowledge of the Born-Oppenheimer interatomic potential…

Atomic Physics · Physics 2021-11-12 Giorgio Visentin , Alexei A. Buchachenko , Paweł Tecmer

Using the exact Bethe Ansatz solution, we investigate methods for calculating the ground-state energy for the $p + ip$-pairing Hamiltonian. We first consider the Hamiltonian isolated from its environment (closed model) through two forms of…

Exactly Solvable and Integrable Systems · Physics 2018-11-14 Yibing Shen , Phillip S. Isaac , Jon Links

Ionization energies for the ground state of berylliumlike ions with nuclear charge numbers in the range Z=16-96 are rigorously evaluated. The calculations merge the ab initio QED treatment in the first and second orders of the perturbation…

Atomic Physics · Physics 2015-07-22 A. V. Malyshev , A. V. Volotka , D. A. Glazov , I. I. Tupitsyn , V. M. Shabaev , G. Plunien
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