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A multi-high-frequency electron paramagnetic resonance method is used to probe the magnetic excitations of a dimer of single-molecule magnets. The measured spectra display well resolved quantum transitions involving coherent superposition…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 S. Hill , R. S. Edwards , N. Aliaga-Alcalde , G. Christou

Dynamic nuclear polarisation (DNP) refers to a class of techniques used to increase the signal in nuclear magnetic resonance measurements by transferring spin polarisation from ensembles of highly polarised electrons to target nuclear…

Quantum Physics · Physics 2020-12-24 L. T. Hall , D. A. Broadway , A. Stacey , D. A. Simpson , J-P. Tetienne , L. C. L. Hollenberg

Exotic spin-multipolar ordering in spin transition metal insulators has so far eluded unambiguous experimental observation. A less studied, but perhaps more feasible fingerprint of multipole character emerges in the excitation spectrum in…

Strongly Correlated Electrons · Physics 2017-12-07 Mitsuru Akaki , Daichi Yoshizawa , Akira Okutani , Takanori Kida , Judit Romhányi , Karlo Penc , Masayuki Hagiwara

A family of double-quantum excitation schemes is described for the solution nuclear magnetic resonance (NMR) of near-equivalent spin-1/2 pairs. These new methods exploit the spinor behaviour of 2-level systems, whose signature is the change…

Electron and nuclear spins are very promising candidates to serve as quantum bits (qubits) for proposed quantum computers, as the spin degrees of freedom are relatively isolated from their surroundings, and can be coherently manipulated…

Quantum Physics · Physics 2010-08-24 J. van Tol , G. W. Morley , S. Takahashi , D. R. McCamey , C. Boehme , M. E. Zvanut

By applying Berry-phase theory for the effective half-filled Hubbard model, we derive an analytical expression for the electronic polarization driven by the relativistic spin-orbit (SO) coupling. The model itself is constructed in the…

Materials Science · Physics 2017-06-14 I. V. Solovyev

It is well known that the association of parahydrogen (pH2) with an unsaturated molecule or a transient metalorganic complex can enhance the intensity of NMR signals; the effect is known as parahydrogen-induced polarization (PHIP). During…

Chemical Physics · Physics 2024-09-26 Andrey N. Pravdivtsev , Danila A. Barskiy , Jan-Bernd Hövener , Igor V. Koptyug

We propose a robust and highly efficient NMR technique to create singlet spin order from longitudinal spin magnetization in coupled spin-1/2 pairs and to perform backward conversion (singlet order)$\to$magnetization. In this method we…

Electric fields represent an ideal means for controlling spins at the nanoscale and, more specifically, for manipulating protected degrees of freedom in multispin systems. Here we perform low-temperature magnetic far-IR spectroscopy on a…

Mesoscale and Nanoscale Physics · Physics 2025-02-03 Florian le Mardelé , Ivan Mohelský , Jan Wyzula , Milan Orlita , Philippe Turek , Filippo Troiani , Athanassios K. Boudalis

The quantum antiferromagnet Cu2Te2O5Br2 was investigated by NMR and NQR. The 125Te NMR investigation showed that there is a magnetic transition around 10.5K at 9T, in agreement with previous studies. From the divergence of the spin-lattice…

Strongly Correlated Electrons · Physics 2015-05-20 Arnaud Comment , Hadrien Mayaffre , Vesna Mitrovic , Mladen Horvatic , Claude Berthier , Beatrice Grenier , Patrice Millet

Spin-orbit coupling (SOC) is expected to partly determine the topologically nontrivial electronic structure of heavy half-Heusler ternary compounds. However, to date, attempts to experimentally observe either the strength of SOC or how it…

Strongly Correlated Electrons · Physics 2016-03-01 Xiaoming Zhang , Zhipeng Hou , Yue Wang , Guizhou Xu , Chenglong Shi , EnKe Liu , Xuekui Xi , Wenhong Wang , Guangheng Wu , Xi-xiang Zhang

Para-hydrogen induced polarization (PHIP) achieves efficient hyperpolarisation of nuclear spins with the transfer of the singlet order of parahydrogen to target molecules through catalytic hydrogenation reactions and subsequent coherent…

Quantum Physics · Physics 2025-08-12 Martin C. Korzeczek , Ilai Schwartz , Martin B. Plenio

In this work, we describe essential tools of linear algebra necessary for calculating the effect of chemical exchange on spin dynamics and polarization transfer in various nuclear magnetic resonance (NMR) experiments. We show how to…

Chemical Physics · Physics 2023-08-01 Jingyan Xu , Danila A. Barskiy

Optical spectroscopy has been the primary tool to study the electronic structure of molecules. However the strict spin selection rule has severely limited its ability to access states of different spin multiplicities. Here we propose a new…

Mesoscale and Nanoscale Physics · Physics 2019-09-16 Sai Duan , Zilvinas Rinkevicius , Yi Luo

We propose an experimentally-feasible system based on spin transitions in the fractional quantum Hall effect regime where parafermions, high-order non-abelian excitations, can be potentially realized. We provide a proof-of-concept…

The use of nuclear spins as physical sensing systems is disadvantaged by their low signal responsivity, particularly when compared to sensing techniques based on electron spins. This primarily results from the small nuclear gyromagnetic…

Nuclear spins and paramagnetic centers in a solid randomly group to form clusters featuring nearly-degenerate, hybrid states whose dynamics are central to processes involving nuclear spin-lattice relaxation and diffusion. Their…

The recently developed hybrid magnonics provides new opportunities for advances in both the study of magnetism and the development of quantum information processing. However, engineering coherent quantum state transfer between magnons and…

Quantum Physics · Physics 2023-07-25 Yan Wang , Hui-Lai Zhang , Jin-Lei Wu , Jie Song , Kun Yang , Wei Qin , Hui Jing , Le-Man Kuang

Due to its broken spin and orbit rotation symmetries, superfluid $^3$He plays a unique role for testing rotational quantum properties on a macroscopic scale. In this system the orbital momentum forms textures that provide an effective…

Superconductivity · Physics 2007-05-23 A. S. Chen , Yu. M. Bunkov , H. Godfrin , R. Schanen , F. Scheffler

Magnetization of a spin1/2 set is determined by means of their individual wave function. The theoretical treatment based on the fundamental axioms of quantum mechanics and solving explicitly Schr\"odinger equation gives the evolution of…

Quantum Physics · Physics 2023-08-22 Tarek Khalil , Daniel Grucker