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We propose an algorithm, that scales with the fifth power of the system size, for computing the second-order dispersion energy for monomers described with multiconfigurational wave functions. This scaling can be achieved when the number of…

In large-scale quantum-chemical calculations the electron-repulsion integral (ERI) tensor rapidly becomes the bottleneck in terms of memory and disk space. When an external finite magnetic field is employed, this problem becomes even more…

Chemical Physics · Physics 2022-02-16 Simon Blaschke , Stella Stopkowicz

Low-rank approximations are essential in modern data science. The interpolative decomposition provides one such approximation. Its distinguishing feature is that it reuses columns from the original matrix. This enables it to preserve matrix…

Numerical Analysis · Mathematics 2022-06-08 Rishi Advani , Sean O'Hagan

We consider fast deterministic algorithms to identify the "best" linearly independent terms in multivariate mixtures and use them to compute, up to a user-selected accuracy, an equivalent representation with fewer terms. One algorithm…

Numerical Analysis · Mathematics 2019-02-20 Gregory Beylkin , Lucas Monzon , Xinshuo Yang

A rigorous analysis is carried out concerning the use of Cholesky decomposition (CD) of two-electron integrals in the case of quantum-chemical calculations with finite or perturbative magnetic fields and gauge-including atomic orbitals. We…

This note presents fast Cholesky/LU/QR decomposition algorithms with $O(n^{2.529})$ time complexity when using the fastest known matrix multiplication. The algorithms have potential application, since a quickly made implementation using…

Numerical Analysis · Computer Science 2018-12-06 Cristóbal Camarero

Fixman's work in 1974 and the follow-up studies have developed a method that can factorize the inverse of mass matrix into an arithmetic combination of three sparse matrices---one of them is positive definite and need to be further…

Computational Physics · Physics 2017-09-13 Xiankun Xu , Peiwen Li

The randomly pivoted partial Cholesky algorithm (RPCholesky) computes a factorized rank-k approximation of an N x N positive-semidefinite (psd) matrix. RPCholesky requires only (k + 1) N entry evaluations and O(k^2 N) additional arithmetic…

Numerical Analysis · Mathematics 2024-10-23 Yifan Chen , Ethan N. Epperly , Joel A. Tropp , Robert J. Webber

An algorithm for irreducible decomposition of representations of finite groups over fields of characteristic zero is described. The algorithm uses the fact that the decomposition induces a partition of the invariant inner product into a…

Representation Theory · Mathematics 2019-06-05 Vladimir V Kornyak

Unitary decomposition is a widely used method to map quantum algorithms to an arbitrary set of quantum gates. Efficient implementation of this decomposition allows for translation of bigger unitary gates into elementary quantum operations,…

Quantum Physics · Physics 2024-03-14 A. M. Krol , A. Sarkar , I. Ashraf , Z. Al-Ars , K. Bertels

Determinantal point processes (DPPs) enable the modeling of repulsion: they provide diverse sets of points. The repulsion is encoded in a kernel $K$ that can be seen as a matrix storing the similarity between points. The diversity comes…

Machine Learning · Statistics 2021-02-24 Claire Launay , Bruno Galerne , Agnès Desolneux

Numerical algorithms have two kinds of costs: arithmetic and communication, by which we mean either moving data between levels of a memory hierarchy (in the sequential case) or over a network connecting processors (in the parallel case).…

Numerical Analysis · Computer Science 2011-02-02 Grey Ballard , James Demmel , Olga Holtz , Oded Schwartz

Direct factorization methods for the solution of large, sparse linear systems that arise from PDE discretizations are robust, but typically show poor time and memory scalability for large systems. In this paper, we describe an efficient…

Numerical Analysis · Computer Science 2015-07-21 Jeffrey N. Chadwick , David S. Bindel

We present a fast sparse matrix permutation algorithm tailored to linear systems arising from triangle meshes. Our approach produces nested-dissection-style permutations while significantly reducing permutation runtime overhead. Rather than…

The high computational cost involved in modeling of the progressive fracture simulations using large discrete lattice networks stems from the requirement to solve {\it a new large set of linear equations} every time a new lattice bond is…

Materials Science · Physics 2009-11-11 Phani Kumar V. V. Nukala , Srdjan Simunovic

This paper develops and analyzes a new algorithm for QR decomposition with column pivoting (QRCP) of rectangular matrices with many more rows than columns. The algorithm carefully combines methods from randomized numerical linear algebra to…

Numerical Analysis · Mathematics 2025-03-18 Maksim Melnichenko , Oleg Balabanov , Riley Murray , James Demmel , Michael W. Mahoney , Piotr Luszczek

An alternative methodology to evaluate two-electron-repulsion integrals based on numerical approximation is proposed. Computational chemistry has branched into two major fields with methodologies based on quantum mechanics and classical…

Chemical Physics · Physics 2016-09-22 Pedro E. M. Lopes

We present a fast randomized algorithm that computes a low rank LU decomposition. Our algorithm uses random projections type techniques to efficiently compute a low rank approximation of large matrices. The randomized LU algorithm can be…

Numerical Analysis · Mathematics 2016-02-02 Gil Shabat , Yaniv Shmueli , Yariv Aizenbud , Amir Averbuch

This paper introduces a novel general-purpose algorithm for Pauli decomposition that employs matrix slicing and addition rather than expensive matrix multiplication, significantly accelerating the decomposition of multi-qubit matrices. In a…

Quantum Physics · Physics 2024-09-25 Lukas Hantzko , Lennart Binkowski , Sabhyata Gupta

In this article, we present a parallel recursive algorithm based on multi-level domain decomposition that can be used as a precondtioner to a Krylov subspace method to solve sparse linear systems of equations arising from the discretization…

Numerical Analysis · Mathematics 2012-10-24 Rahul S. Sampath , Bobby Philip , Srikanth Allu , Srdjan Simunovic