Related papers: Gas phase detection and rotational spectroscopy of…
Ethyl phosphaethyne, C2H5CP, has been characterized spectroscopically in the gas phase for the first time, employing millimeter- and submillimeter-wave spectroscopy in the frequency regime from 75 to 760 GHz. Spectroscopic detection and…
We present the first detection in space of 1,4-pentadiyne. It has been found towards TMC-1 with the QUIJOTE line survey in the 31-50 GHz range. We observed a total of 17 transitions with J = 2 up to 13 and Ka = 0, 1 and 2. The observed…
This work aims to spectroscopically characterize and provide for the first time direct experimental frequencies of the ground vibrational state and two excited states of the simplest alkynyl thiocyanate (HCCSCN) for astrophysical use. Both…
The ketenyl radical, HCCO, has recently been detected in the ISM for the first time. Further astronomical detections of HCCO will help us understand its gas-grain chemistry, and subsequently revise the oxygen-bearing chemistry towards dark…
We have used the Australia Telescope National Facility Mopra 22m millimetre telescope to search for emission from the 85.5-GHz and 86.6-GHz transitions of methanol. The search was targeted towards 22 star formation regions which exhibit…
Thioformaldehyde is an abundant molecule in various regions of the interstellar medium. However, available laboratory data limit the accuracies of calculated transition frequencies in the submillimeter region, in particular for minor…
The rovibrational spectrum of the molecular ion H$_2$CCCH$^+$ was investigated in a 4~K cryogenic ion trap instrument employing the leak-out spectroscopy method. Transitions within the fundamental $\nu_1$ (C-H stretch) and the combination…
The reaction between carbon atoms and vinyl cyanide, CH2CHCN, is a formation route to interstellar 3-cyano propargyl radical, CH2C3N, a species that has recently been discovered in space. The 1-cyano propargyl radical (HC3HCN), an isomer of…
We report the detection of methyl ketene towards TMC-1 with the QUIJOTE line survey. Nineteen rotational transitions with rotational quantum numbers ranging from J = 3 up to J = 5 and Ka =< 2 were identified in the frequency range 32.0-50.4…
Iram 30-m Observations towards eight protostellar outflow sources were taken in the 96-\SI{176}{\giga\hertz} range. Transitions of CH$_3$OH and CH$_3$CHO were detected in seven of them. The integrated emission of the transitions of each…
We report the detection of the millimeter CH$_3$OH masers including a new detection of class I (11$_{0,11}$-10$_{1,10}$A) and class II (6$_{1,5}$-5$_{2,4}$E) maser transitions toward the high-mass protostar S255IR NIRS3 in post-burst phase.…
We report the first observations in a rare family of class II methanol maser transitions in both CH$_3$OH and $^{13}$CH$_3$OH toward three southern high-mass star formation regions, along with the first maser detected in the $^{13}$CH$_3$OH…
Our observations of TMC-1 with the Yebes 40 m radio telescope in the 31.0-50.3 GHz range allowed us to detect a group of unidentified lines, showing a complex line pattern indicative of an open-shell species. {}The observed frequencies of…
Here we report the first evidence for a reversible phase change in an ethanethiol ice prepared under astrochemical conditions. InfraRed (IR) spectroscopy was used to monitor the morphology of the ice using the S-H stretching vibration, a…
A southern hemisphere survey of methanol emission sources in two millimeter wave transitions has been carried out using the ATNF Mopra millimetre telescope. Sixteen emission sources have been detected in the 3(1)-4(0)A+ transition of…
We report the detection of the propargyl radical (CH2CCH) in the cold dark cloud TMC-1 in the lambda 3 mm wavelength band. We recently discovered this species in space toward the same source at a wavelength of lambda 8 mm. In those…
Context. Class II methanol masers at 6.7 and 12.2 GHz occur close to high-mass young stellar objects (HMYSOs). When they are observed simultaneously, such studies may contribute to refining the characterisation of local physical conditions.…
We use both chirped-pulse Fourier transform and frequency modulated absorption spectroscopy to study the rotational spectrum of 2-methoxyethanol in several frequency regions ranging from 8.7-500 GHz. The resulting rotational parameters…
We report the first detection in space of the single deuterated isotopologue of methyldiacetylene, CH2DC4H. A total of 12 rotational transitions, with J = 8-12 and Ka = 0 and 1, were identified for this species in TMC-1 in the 31.0-50.4 GHz…
We report the first laboratory and interstellar detection of the alpha-cyano vinyl radical (H2CCCN). This species was produced in the laboratory by an electric discharge of a gas mixture of vinyl cyanide, CH2CHCN, and Ne, and its rotational…