Related papers: A microcanonical entropy correcting finite-size ef…
The theory of thermal macroeconomics (TM) analyses economic phenomena within the mathematical framework of classical thermodynamics, using a set of axioms that apply to the purely macroscopic aspects of an economy [CM]. The theory shows…
We present an exact microcanonical formulation, in the thermodynamic limit, for a system of $N$ noninteracting particles with $p$ equally spaced energy levels $\{0,\epsilon,2\epsilon,\ldots,(p-1)\epsilon\}$. Writing the microcanonical…
We study the entropy of small subsystems in thermalizing quantum many-body systems governed by local Hamiltonians. Assuming the eigenstate thermalization hypothesis, we derive an analytical formula for the von Neumann entropy of…
Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the $N-$body phase space with the given total energy. Due to Boltzmann's principle,…
Traditionally, phase transitions are defined in the thermodynamic limit only. We discuss how phase transitions of first order (with phase separation and surface tension), continuous transitions and (multi)-critical points can be seen and…
Phase transitions in nuclei, small atomic clusters and self-gravitating systems demand the extension of thermo-statistics to ``Small'' systems. The main obstacle is the thermodynamic limit. It is shown how the original definition of the…
The canonical ensemble describes an open system in equilibrium with a heat bath of fixed temperature. The probability distribution of such a system, the Boltzmann distribution, is derived from the uniform probability distribution of the…
Symmetry properties of the microcanonical entropy surface as a function of the energy and the order parameter are deduced from the invariance group of the Hamiltonian of the physical system. The consequences of these symmetries for the…
We consider a small Hamiltonian system strongly interacting with a much larger Hamiltonian system (the bath), while being driven by both a time-dependent control parameter and non-conservative forces. The joint system is assumed to be…
A statistical approach to the description of the thermodynamic properties of the Fermi particle system occupying a half-space over a plane of finite size in a uniform external field is proposed. The number of particles per unit area is…
Very recently, the validity of the concept of negative temperature has been challenged by several authors since they consider Boltzmann's entropy (that allows negative temperatures) inconsistent from a mathematical and statistical point of…
Statistical fragment emission from excited nuclear systems is studied within the framework of a schematic Fermi-gas model combined with Weisskopf's detailed balance approach. The formalism considers thermal expansion of finite nuclear…
In systems with detailed balance, the stationary distribution and the equilibrium distribution are identical, creating a clear connection between energetic and entropic quantities. Many driven systems violate detailed balance and still pose…
We develop the stochastic approach to thermodynamics based on the stochastic dynamics, which can be discrete (master equation) continuous (Fokker-Planck equation), and on two assumptions concerning entropy. The first is the definition of…
We study the simplest possible model of nanocrystal consisting in a simple cubic lattice with a small number of atoms (NA ~ 10-10^3), where each atom is linked to its nearest neighbor by a quantum harmonic potential. Some properties…
The paper examines and critiques the expression of entropy as the logarithm of the number of quantum states of a physical system. Boltzmann method of expressing entropy as the logarithm of the number of states of a gas with a given total…
The postulates of thermodynamics were originally formulated for macroscopic systems. They lead to the definition of the entropy, which, for a homogeneous system, is a homogeneous function of order one in the extensive variables and is…
It has been suggested recently that the microcanonical entropy of a system may be accurately reproduced by including a logarithmic correction to the canonical entropy. In this paper we test this claim both analytically and numerically by…
The paper moves a step towards the full integration of statistical mechanics and information theory. Starting from the assumption that the thermodynamical system is composed by particles whose quantized energies can be modelled as…
We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…