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We show that in transition metal compounds containing structural metal dimers there may exist in the presence of different orbitals a special state with partial formation of singlets by electrons on one orbital, while others are effectively…

Strongly Correlated Electrons · Physics 2014-04-22 Sergey V. Streltsov , Daniel I. Khomskii

Crystal and electronic structure, lattice dynamics and thermodynamic stability of little known mixed valent diamagnetic AgIAgIIIF4 beta form of AgF2 is thoroughly examined for the first time and compared with well known antiferromagnetic…

Materials Science · Physics 2021-01-06 Kamil Tokar , Mariana Derzsi , Wojciech Grochala

We review the basic ideas of the dynamical mean field theory (DMFT) and some of the insights into the electronic structure of strongly correlated electrons obtained by this method in the context of model Hamiltonians. We then discuss the…

Strongly Correlated Electrons · Physics 2007-05-23 G. Kotliar , S. Y. Savrasov

The electronic structure of the VAs compound in the zinc-blende structure is investigated using a combined density-functional and dynamical mean-field theory approach. Contrary to predictions of a ferromagnetic semiconducting ground state…

Strongly Correlated Electrons · Physics 2007-05-23 L. Chioncel , Ph. Mavropoulos , M. Ležaić , S. Blügel , E. Arrigoni , M. I. Katsnelson , A. I. Lichtenstein

Motivated by the unexplored complexity of phases present in the multiorbital Hubbard model, we analyze in this work the behavior of a degenerate two-orbital anisotropic Hubbard model at half filling where both orbitals have equal bandwidths…

Strongly Correlated Electrons · Physics 2015-05-20 Hunpyo Lee , Yu-Zhong Zhang , Harald O. Jeschke , Roser Valenti

The electronic structures of element cerium under high pressure remain unclear all the time. We tried to calculate the electronic structures of $\alpha'$, $\alpha"$, and $\epsilon$-Ce which only exist in the presence of pressure, by using…

Strongly Correlated Electrons · Physics 2018-11-02 Haiyan Lu , Li Huang

First principles linear combinations of Gaussian type orbitals-fitting function (LCGTO-FF) electronic structure calculations are used to study thickness dependencies in the surface energies and work functions of ultra-thin (111) films of…

Strongly Correlated Electrons · Physics 2009-11-10 A. K. Ray , J. C. Boettger

Using density functional plus dynamical mean-field theory method (DFT+DMFT) with full self-consistency over the charge density, we study the effect of electronic correlations on the electronic structure, magnetic properties,…

Strongly Correlated Electrons · Physics 2019-12-25 S. L. Skornyakov , I. Leonov

Extending density functional theory (DFT) to an {\it ab initio} orbital functional theory (OFT) requires new methodology for nonlocal exchange and correlation potentials. This paper describes such modifications to a standard Dirac-Slater…

Condensed Matter · Physics 2007-05-23 R. K. Nesbet

In this article, density functional theory (DFT) and natural bond orbital (NBO) calculations are performed to understand experimental observations of dissociative electron attachment (DEA) to SO$_2$. The molecular structure, fundamental…

Atomic and Molecular Clusters · Physics 2018-07-09 Irina Jana , Sumit Naskar , Mousumi Das , Dhananjay Nandi

First-principles density functional theory (DFT) calculations of Lu-H-N compounds reveal low-energy configurations of Fm$\overline{3}$m Lu$_{8}$H$_{23-x}$N structures that exhibit novel electronic properties such as flat bands, sharply…

Materials Science · Physics 2024-02-27 Adam Denchfield , Hyowon Park , Russell J. Hemley

Complex oxides with $4d$ and $5d$ transition-metal ions recently emerged as a new paradigm in correlated electron physics, due to the interplay between spin-orbit coupling and electron interactions. For $4d$ and $5d$ ions, the spin-orbit…

Strongly Correlated Electrons · Physics 2021-05-19 Tomohiro Takayama , Jiri Chaloupka , Andrew Smerald , Giniyat Khaliullin , Hidenori Takagi

In contrast to the original Kohn-Sham (KS) formalism, we propose a density functional theory (DFT) with fractional orbital occupations for the study of ground states of many-electron systems, wherein strong static correlation is shown to be…

Chemical Physics · Physics 2015-06-03 Jeng-Da Chai

We employ dynamical mean-field theory (DMFT) combined with density functional theory (DFT) and the non-equilibrium Green's function technique to investigate the steady-state transport properties of an Fe/MgO/Fe magnetic tunnel junction…

Strongly Correlated Electrons · Physics 2024-10-11 Declan Nell , Stefano Sanvito , Ivan Rungger , Andrea Droghetti

We study the electronic band-structure and transport properties of a CuO2-plane within the three-band Hubbard model. The Dynamical Mean-Field Theory (DMFT) is used to solve the many particle problem. The calculations show that the optical…

Strongly Correlated Electrons · Physics 2007-05-23 M. B. Zoelfl , Th. Maier , Th. Pruschke , J. Keller

By means of the density functional theory in combination with the dynamical mean-field theory, we tried to examine the electronic structure of hexagonal FeGe, in which the Fe atoms form a quasi-2D layered Kagome lattice. We predict that it…

Strongly Correlated Electrons · Physics 2020-09-18 Li Huang , Haiyan Lu

The organic salt $\alpha$-(BEDT-TTF)$_2$I$_3$ is considered a model system for metal-insulator transition due to electronic charge ordering at $T_{\rm CO}=135$~K. The optical properties obtained from polarized reflection measurements above…

Strongly Correlated Electrons · Physics 2016-03-25 T. Peterseim , M. Dressel

The correlated Kondo insulator state of the plutonium monochalcogenides is investigated using the dynamical mean field theory (DMFT) and the local density approximation +U (LDA+U). The DMFT-dynamical fluctuations lead to a correlated…

Strongly Correlated Electrons · Physics 2015-05-14 M. -T. Suzuki , P. M. Oppeneer

We present an orbital-resolved extension of the Hubbard $U$ correction to density-functional theory (DFT). Compared to the conventional shell-averaged approach, the prediction of energetic, electronic and structural properties is strongly…

Materials Science · Physics 2024-09-18 Eric Macke , Iurii Timrov , Nicola Marzari , Lucio Colombi Ciacchi

Motivated by experimental suggestions of anionic redox processes helping to design higher energy lithium ion-battery cathode materials, we investigate this effect using first-principles electronic structure calculations for Li-rich layered…

Strongly Correlated Electrons · Physics 2023-05-16 Jae-Hoon Sim , D. D. Sarma , Jean-Marie Tarascon , Silke Biermann