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We consider the mesoscopic model for the liquid crystalline brush that might serve as a photoswitchable aligning surface for preorientation of low molecular weight liquid crystals in a bulk. The brush is built by grafting the polymer chains…

Soft Condensed Matter · Physics 2022-10-20 D. Yaremchuk , T. Patsahan , J. Ilnytskyi

Poly(ethylene terephthalate) (PET) is a semi--crystalline polymer that can be crystallized to different degrees heating from the amorphous state. Even when primary crystallization has been completed, secondary crystallization can take place…

Materials Science · Physics 2015-05-13 J. Sellares , J. A. Diego , J. Belana

Surface freezing is a phenomenon in which crystallization is enhanced at a vapor-liquid interface. In some systems, such as $n$-alkanes, this enhancement is dramatic, and results in the formation of a crystalline layer at the free interface…

Soft Condensed Matter · Physics 2017-09-13 Amir Haji Akbari , Pablo G. Debenedetti

We investigate the switching dynamics of multistable nematic liquid crystal devices. In particular we identify a remarkably simple 2-dimensional (2D) device which exploits hybrid alignment at the surfaces to yield a bistable response. We…

Soft Condensed Matter · Physics 2011-02-08 A. Tiribocchi , G. Gonnella , D. Marenduzzo , E. Orlandini

We use a method of molecular dynamics to investigate the distribution of liquid crystal 5CB molecules in a polymeric matrix. Temperature dependences of parameters of an order <P2> are calculated. Calculations have shown that depending on…

Mesoscale and Nanoscale Physics · Physics 2011-11-28 M. A. Korshunov

Systems with holes, such as colloidal handlebodies and toroidal droplets, have been studied in the nematic liquid crystal (NLC) 4-cyano-4'-pentylbiphenyl (5CB): both point and ring topological defects can occur within each hole and around…

Soft Condensed Matter · Physics 2023-12-01 Lisa Tran , Maxim O. Lavrentovich , Daniel A. Beller , Ningwei Li , Kathleen J. Stebe , Randall D. Kamien

By means of atomistic molecular dynamics simulations we investigate the behaviour of poly(N-isopropylacrylamide), PNIPAM, in water at temperatures below and above the lower critical solution temperature (LCST), including the undercooled…

Soft Condensed Matter · Physics 2019-02-11 L. Tavagnacco , E. Zaccarelli , E. Chiessi

Thin elastic films can spontaneously attach to liquid interfaces, offering a platform for tailoring their physical, chemical, and optical properties. Current understanding of the elastocapillarity of thin films is based primarily on studies…

Boiling is a prevalent phase-change process that plays a vital role in facilitating efficient heat transfer from a heating surface. While this heat transfer mechanism is generally effective, a rapid increase in surface temperature can lead…

In this work, we provide mechanistic insight into the initial stages of formation of ice across the limit of stability of supercooled water. Such an analysis is particularly important since crystal nucleation is not a relevant mechanism…

Statistical Mechanics · Physics 2026-05-26 Ashutosh Srivastava , Pankaj A. Apte

Falling liquid films become unstable due to inertial effects when the fluid layer is sufficiently thick or the slope sufficiently steep. This free surface flow of a single fluid layer has industrial applications including coating and heat…

Capillary microflows of liquid crystal phases are central to material, biological and bio-inspired systems. Despite their fundamental and applied significance, a detailed understanding of the stationary behaviour of nematic liquid crystals…

Soft Condensed Matter · Physics 2021-07-21 Paul Steffen , Eric Stellamanns , Anupam Sengupta

Thermodynamic multi-component solution solidification approach to liquid-to-glass transition is proposed and actual mechanisms underlying vitrification, other than viscous slowdown, are identified. Due to polydisperse aggregation in liquid…

Materials Science · Physics 2022-09-14 Vladimir Belostotsky

Current vapor-compression technology is based on the gas-liquid transition of hazardous gas. The alternative cooling technology focuses on the solid caloric material. A new liquid barocaloric material, i.e. the liquid crystal, is proved to…

Soft Condensed Matter · Physics 2016-09-27 Zhongjian Xie , Yao Zhu

Partially wetting nematic liquid crystal (NLC) films on substrates are unstable to dewetting-type instabilities due to destablizing solid/NLC interaction forces. These instabilities are modified by the nematic nature of the films, which…

Soft Condensed Matter · Physics 2021-01-05 M. Lam , L. Kondic , L. Cummings

Highly directional and lossless surface wave has significant potential applications in the two-dimensional photonic circuits and devices. Here we experimentally demonstrate a selective Dyakonov surface wave coupling at the interface between…

Optics · Physics 2020-02-19 Yan Li , Jingbo Sun , Yongzheng Wen , Ji Zhou

We study, by means of computer simulations, the crystal-melt interface of three different systems: hard-spheres, Lennard Jones and the TIP4P/2005 water model. In particular, we focus on the dynamics of surface waves. We observe that the…

Chemical Physics · Physics 2014-10-02 Jorge Benet , Luis G. MacDowell , Eduardo Sanz

By Monte Carlo simulations of a soft ellipsoid model for liquid crystals, we study whether a layer of grafted liquid-crystalline chain molecules can induce tilt in a nematic fluid. The chains are fairly short (four monomers) and made of the…

Materials Science · Physics 2009-11-07 Harald Lange , Friederike Schmid

In the present work, a detailed analysis of the glassy behavior and the relaxation dynamics of the liquid crystal dimer {\alpha}-(4-cyanobiphenyl-4'-yloxy)-{\omega}-(1-pyrenimine-benzylidene-4'-oxy) heptane (CBO7O.Py) throughout both…

Soft Condensed Matter · Physics 2018-10-02 David O. López , Josep Salud , María Rosario de la Fuente , Nerea Sebastián , Sergio Diez-Berart

A novel liquid-liquid phase transition has been proposed and investigated in a wide variety of pure substances recently, including water, silica and silicon. From computer simulations using the Stillinger-Weber classical empirical…

Statistical Mechanics · Physics 2015-05-27 Vishwas V Vasisht , Shibu Saw , Srikanth Sastry