Related papers: Thermodynamic limits to energy conversion in solar…
Hot-carrier solar cells are envisioned to utilize energy filtering to extract power from photogenerated electron-hole pairs before they thermalize with the lattice, and thus potentially offer higher power conversion efficiency compared to…
In the present work we propose "nanofluid filled enclosures" as potential photo-thermal energy conversion and sensible heat storage devices. Herein, the optical charging of the nanofluid has been modeled as "solar radiant energy -…
Photosynthesis is nature's route to convert intermittent solar irradiation into storable energy, while its use for an industrial energy supply is impaired by low efficiency. Artificial photosynthesis provides a promising alternative for…
We theoretically demonstrate the fundamental limit in volume for given materials (e.g. Si, a-Si, CdTe) to fully absorb the solar radiation above bandgap, which we refer as solar superabsorption limit. We also point out the general…
The Shockley-Queisser (SQ) limit, introduced by W. Shockley and H. J. Queisser in 1961, is the most well-established fundamental efficiency limit for single-junction photovoltaic solar cells. For widely-studied semiconductors such as Si,…
The identification and use of reversible Martensitic transformations, typically described as shape memory transformations, as a new class of solid-solid phase change material is experimentally demonstrated here for the first time. To prove…
In a recent paper, Guillemoles et al [J.F. Guillemoles, T. Kirchartz, D. Cahen and U Rau, Guide for the perplexed to the Shockley-Queisser model for solar cells, Nat. Photonics, 13, 501 (2019)] attempt to clarify and explain the often cited…
Solar-to-fuel direct conversion devices are a key component to realize a full transition to a renewable-energy based chemistry and energy, but their limits and possibilities are still under large debate. In this review article, we focus on…
Elementary physics of photovoltaic energy conversion in a two-level atomic PV is considered. We explain the conditions for which the Carnot efficiency is reached and how it can be exceeded! The loss mechanisms - thermalization, angle…
The Shockley-Queisser limit is one of the most fundamental results in the field of photovoltaics. Based on the principle of detailed balance, it defines an upper limit for a single junction solar cell that uses an absorber material with a…
Although spectrally selective materials play a key role in existing and emerging solar thermal technologies, temperature-related degradation currently limits their use to below 700C in vacuum, and even lower temperatures in air. Here we…
Energy storage becomes crucial for energy systems with an increasing share of renewable energy sources. Artificial photosynthesis, in particular photovoltaic water splitting, provides both sustainable energy generation and energy storage in…
Taking into account the temperature gradients in solar cells, it is shown that their efficiency can be increased beyond the Shockley-Queisser limit (J. Appl. Phys. 32 (1961) 510). The driving force for this gain is the temperature gradient…
The Shockley-Queisser model is a landmark in photovoltaic device analysis by defining an ideal situation as reference for actual solar cells. However, the model and its implications are easily misunderstood. Thus, we present a guide to help…
Inversion techniques applied to the radiative transfer equation for polarized light are capable of inferring the physical parameters in the solar atmosphere (temperature $T$, magnetic field ${\bf B}$, and line-of-sight velocity $v_{\rm…
Efficient storage of solar thermal energy is still one of the major bottlenecks in realizing dispatchable solar thermal systems. Present work is a significant step in this direction, wherein, we propose, thermochromism assisted photon…
The selfconsistent model for the temperature dependence of photoconversion efficiency $\eta$ for highly efficient silicon solar cells (SCs) is developed. It is demonstrated that effect of the efficiency decrease due to increasing…
There is a renewed interest in photovoltaic solar thermal (PVT) hybrid systems, which harvest solar energy for heat and electricity. Typically, a main focus of a PVT system is to cool the photovoltaic (PV) cells to improve the electrical…
We report a low cost and scalable method to synthesize solar selective nanofluids from 'used engine oil'. The as-prepared nanofluids exhibit excellent long-term stability and photo-thermal conversion efficiency. Moreover, these were found…
We analyse the process of conversion of near-field thermal radiation into usable work by considering the radiation emitted between two planar sources supporting surface phonon-polaritons. The maximum work flux that can be extracted from the…