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We develop coupled-cluster theory for systems of electrons strongly coupled to photons, providing a promising theoretical tool in polaritonic chemistry with a perspective of application to all types of fermion-boson coupled systems. We show…

We use molecular dynamics simulations to unravel the physics underpinning the light-induced density changes caused by the dynamic trans-cis-trans isomerization cycles of azo-mesogens embedded in a liquid crystal polymer network, an…

Soft Condensed Matter · Physics 2024-04-18 Akhil Reddy Peeketi , Edwin Joseph , Narasimhan Swaminathan , Ratna Kumar Annabattula

The photoisomerization of chromophores embedded in biological environments is of high importance for biomedical applications, but it is still challenging to define the photoisomerization mechanism both experimentally and computationally. We…

Soft Condensed Matter · Physics 2024-10-10 Silvio Osella , Giovanni Granucci , Maurizio Persico , Stefan Knippenberg

Multilayer assemblies of metal nanoparticles can act as photonic structures, where collective plasmon resonances hybridize with cavity modes to create plasmon-polariton states. For sufficiently strong coupling, plasmon polaritons…

Plexciton is the formation of new hybridized energy states originated from the coupling between plasmon and exciton. To reveal the optical properties of both exciton and plexciton, we develop a classic oscillator model to describe the…

Optics · Physics 2022-07-12 Yuqing Cheng , Mengtao Sun

Chiral phonon-polaritonic states are of interest for handedness-dependent light-matter interactions, yet their realization and magnetic control remain challenging, while direct magneto-optical tunability of phonon-polaritonic media is…

Optics · Physics 2026-04-15 Yu Sun , Jue Li , Wei Li , Bo Li , Qinghua Song , Mengyao Li

Exciton-polaritons are mutually interacting quantum hybridizations of confined photons and electronic excitations. Here we demonstrate a system of optically guided, electrically polarized exciton-polaritons ('dipolaritons') that displays up…

Mesoscale and Nanoscale Physics · Physics 2018-04-18 Itamar Rosenberg , Dror Liran , Yotam Mazuz-Harpaz , Kenneth West , Loren Pfeiffer , Ronen Rapaport

The paper investigates cold molecules formation in the photoassociation of two cold atoms by a strong laser pulse applied at short interatomic distances, which lead to a molecular dynamics taking place in the light-induced (adiabatic)…

Quantum Physics · Physics 2009-07-23 M. Vatasescu

The ultrafast non-radiative relaxation of a molecular ensemble coupled to a cavity mode is considered theoretically and by real-time quantum dynamics. For equal coupling strength of single molecules to the cavity mode, the non-radiative…

Chemical Physics · Physics 2018-12-26 Oriol Vendrell

We analyze the real-time electron-photon dynamics in long-range polariton-mediated energy transfer using a real-time quantum electrodynamics coupled cluster (RT-QED-CC) model, which allows for spatial and temporal visualization of transport…

Chemical Physics · Physics 2024-04-16 Matteo Castagnola , Marcus T. Lexander , Enrico Ronca , Henrik Koch

Polaritons - hybrid light-matter states formed from the strong coupling of a bright molecular transition with a confined photonic mode - may offer new opportunities for optical control of molecular behavior. Vibrational strong coupling…

Chemical Physics · Physics 2025-11-19 Liying Chen , Alexander M. McKillop , Ashley P. Fidler , Marissa L. Weichman

We develop a theory for light propagating in an atomic Bose-Einstein condensate in the presence of strong interactions. The resulting many-body correlations are shown to have profound effects on the optical properties of this interacting…

Quantum Gases · Physics 2020-05-06 A. Camacho-Guardian , K. Knakkergaard Nielsen , T. Pohl , G. M. Bruun

Achieving precise control of photoinduced molecular charge transfer reactions underpins key emerging technologies. As such, the use of hybrid light-matter molecular exciton-polariton states has been proposed as a scheme to directly modify…

We present a microscopic semi-analytical theory for the description of organic molecules interacting strongly with a cavity mode. Exciton-vibration coupling within the molecule and exciton-cavity interaction are treated on an equal footing…

Mesoscale and Nanoscale Physics · Physics 2016-11-15 Ning Wu , Johannes Feist , Francisco J. Garcia-Vidal

Thanks to their exceptional spatial, spectral and temporal resolution, highly-coherent free-electron beams have emerged as powerful probes for material excitations, enabling their characterization even in the quantum regime. Here, we…

Quantum Physics · Physics 2023-12-12 J. Abad-Arredondo , A. I. Fernández-Domínguez

We investigate theoretically the influence of strong light-matter coupling on the initial steps of the photo-triggered singlet-fission process. In particular we focus on intra-molecular singlet fission in a TIPS-pentacene dimer derivative…

Chemical Physics · Physics 2024-06-07 Lisamaria Wallner , Charlotte Remnant , Oriol Vendrell

We construct a model describing the response of a hybrid system where the electromagnetic field - in particular, surface plasmon polaritons - couples strongly with electronic excitations of atoms or molecules. Our approach is based on the…

Quantum Physics · Physics 2020-01-01 K. S. U. Kansanen , A. Asikainen , J. J. Toppari , G. Groenhof , T. T. Heikkilä

Achieving and controlling strong light-matter interactions in many-body systems is of paramount importance both for fundamental understanding and potential applications. In this paper we demonstrate both experimentally and theoretically how…

Mesoscale and Nanoscale Physics · Physics 2016-12-26 Pierre Fauche , Christian Gebhardt , Maxim Sukharev , Renaud A. L. Vallee

An ensemble of identical, intrinsically non-interacting molecules exposed to quantum light is discussed. Their interaction with the quantum light induces interactions between the molecules. The resulting hybrid light-matter states exhibit…

Chemical Physics · Physics 2024-06-19 Lorenz S. Cederbaum

We present a comprehensive investigation of the light-matter interaction dynamics in two-dimensional materials coupled with a spectrally isolated cavity mode in the strong coupling regime. The interaction between light and matter breaks the…

Mesoscale and Nanoscale Physics · Physics 2023-12-18 Maria Vittoria Gurrieri , Emil V. Denning , Kristian Seegert , Philip T. Kristensen , Jesper Mørk