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We present a stochastic approach for ion transport at the mesoscopic level. The description takes into account the self-consistent electric field generated by the fixed and mobile charges as well as the discrete nature of these latter. As…

Statistical Mechanics · Physics 2015-03-17 David Andrieux , Pierre Gaspard

We derive an equation capable of treating both the electrostatic and non-electrostatic interactions in the charged liquids. The equation derived is a complex version of the Poisson-Boltzmann equation, in which the non-electrostatic…

Soft Condensed Matter · Physics 2025-02-12 Li Wan

Semi-linear elliptic Partial Differential Equations (PDEs) such as the non-linear Poisson Boltzmann Equation (nPBE) is highly relevant for non-linear electrostatics in computational biology and chemistry. It is of particular importance for…

Numerical Analysis · Mathematics 2023-09-29 Brian Choi , Jie Xu , Trevor Norton , Mark Kon , Julio Enrique Castrillon-Candas

In this letter we analyze the effects of an externally applied electric field on thermal fluctuations for a fluid containing charged species. We show in particular that the fluctuating Poisson-Nernst-Planck equations for charged…

The behavior of electrolyte solutions close to a charged surface is studied theoretically. A modified Poisson-Boltzmann equation which takes into account the volume excluded by the ions in addition to the electrostatic interactions is…

Soft Condensed Matter · Physics 2007-05-23 I. Borukhov , D. Andelman , H. Orland

Ionic Bose polarons are quantum entities emerging from the interaction between an ion and a Bose-Einstein condensate (BEC), featuring long-ranged interactions that can compete with the gas healing length. This can result in strong…

Quantum Gases · Physics 2024-09-11 Ubaldo Cavazos Olivas , Luis A. Peña Ardila , Krzysztof Jachymski

Poisson-Boltzmann theory allows one to study soft matter and biophysical systems involving point-like charges of low valencies. The inclusion of fluctuation corrections beyond the mean-field approach typically requires the application of…

Soft Condensed Matter · Physics 2018-04-30 R. Blossey , A. C. Maggs

This study investigates the flux ratios of ionic flows using Poisson-Nernst-Planck (PNP) models. The flux ratio measures the effect of permanent charge on the ion fluxes and can exhibit bifurcation, where a small parameter change causes a…

Dynamical Systems · Mathematics 2023-11-07 Hamid Mofidi

We present a method that generalises the standard mean field theory of correlated lattice bosons to include amplitude and phase fluctuations of the $U(1)$ field that induces onsite particle number mixing. This arises formally from an…

Strongly Correlated Electrons · Physics 2018-07-19 Abhishek Joshi , Pinaki Majumdar

Dissipation and fluctuations of one-body observables in heavy-ion reactions around the Coulomb barrier are investigated with a microscopic stochastic mean-field approach. By projecting the stochastic mean-field dynamics on a suitable…

Nuclear Theory · Physics 2017-03-22 Kouhei Washiyama , Denis Lacroix , Sakir Ayik , Bülent Yilmaz

Comparing quantities to analyze charged fluctuations in heavy ion experiments the dispersion of the charges in a central rapidity box was found to be best suited. Various energies and different nuclear sizes are considered in an explicit…

High Energy Physics - Phenomenology · Physics 2007-05-23 Fritz W. Bopp , Johannes Ranft

We consider in this paper random batch interacting particle methods for solving the Poisson-Nernst-Planck (PNP) equations, and thus the Poisson-Boltzmann (PB) equation as the equilibrium, in the external unbounded domain. To justify the…

Numerical Analysis · Mathematics 2022-03-25 Lei Li , Jian-Guo Liu , Yijia Tang

At mesoscopic scales electrolyte solutions are modeled by the fluctuating generalized Poisson-Nernst-Planck (PNP) equations [J.-P. P\'eraud et al., Phys. Rev. F, 1(7):074103, 2016]. However, at length and time scales larger than the Debye…

Computational Physics · Physics 2019-04-10 Aleksandar Donev , Andrew J. Nonaka , Changho Kim , Alejandro L. Garcia , John B. Bell

The main interest of the present work is the generalization of the Boltzmann-Gibbs distributions and the fluctuation theory based on the consideration of the reparametrization invariance of the microcanonical ensemble. This approach allows…

Statistical Mechanics · Physics 2007-05-23 L. Velazquez

In computational biochemistry and biophysics, understanding the role of electrostatic interactions is crucial for elucidating the structure, dynamics, and function of biomolecules. The Poisson-Boltzmann (PB) equation is a foundational tool…

Biomolecules · Quantitative Biology 2024-10-08 Yongxian Wu , Qiang Zhu , Ray Luo

A large number of effects related to the phenomenon of Bose-Einstein Condensation (BEC) can be understood in terms of lowest order mean field theory, whereby the entire system is assumed to be condensed, with thermal and quantum…

Other Condensed Matter · Physics 2015-05-13 N. P. Proukakis

A Poisson-Nernst-Planck-Fermi (PNPF) theory is developed for studying ionic transport through biological ion channels. Our goal is to deal with the finite size of particle using a Fermi like distribution without calculating the forces…

Biological Physics · Physics 2015-06-23 Jinn-Liang Liu , Bob Eisenberg

The adsorption of large ions from solution to a charged surface is investigated theoretically. A generalized Poisson--Boltzmann equation, which takes into account the finite size of the ions is presented. We obtain analytical expressions…

Soft Condensed Matter · Physics 2009-10-31 I. Borukhov , D. Andelman , H. Orland

A mean-field model to describe electron transfer processes in ion-molecule collisions at the $\hbar =0$ level is presented and applied to collisions involving water and ammonia molecules. Multicenter model potentials account for the…

Atomic Physics · Physics 2023-11-21 Alba Jorge , Marko Horbatsch , Tom Kirchner

Comparing proposed quantities to analyze charged particle fluctuations in heavy ion experiments we find the dispersion of the charges in a central rapidity box as best suited. Various energies and different nuclear sizes were considered in…

High Energy Physics - Phenomenology · Physics 2007-05-23 Fritz W. Bopp , Johannes Ranft