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Molecular dynamics simulations were employed to study the wetting behavior of nanoscale aqueous hydrophilic and hydrophobic Imidazolium based ionic liquid (IL) droplets on a solid graphite substrate subjected to the perpendicular electric…

Soft Condensed Matter · Physics 2020-12-09 Sanchari Bhattacharjee , Sandip Khan

Ionic liquids are promising candidates for electrolytes in energy-storage systems. We demonstrate that mixing two ionic liquids allows to precisely tune their physical properties, like the dc conductivity. Moreover, these mixtures enable…

Soft Condensed Matter · Physics 2018-02-27 E. Thoms , P. Sippel , D. Reuter , M. Weiß , A. Loidl , S. Krohns

Recent advances in experimental and computational techniques have allowed for an accurate description of the adsorption of ionic liquids on metallic electrodes. It is now well established that they adopt a multi-layered structure, and that…

Materials Science · Physics 2016-03-15 Benjamin Rotenberg , Mathieu Salanne

This work describes the experimental and theoretical study of the nonlinear optical properties of the imidazolium cation based ionic liquids and the corresponding thermo-optical parameters. Experimental results of nonlinear optical…

The behavior of liquid water under an electric field is a crucial phenomenon in science and engineering. However, its detailed description at a microscopic level is difficult to achieve experimentally. Here we report on the first ab initio…

Soft Condensed Matter · Physics 2012-05-16 A. Marco Saitta , Franz Saija , Paolo V. Giaquinta

Absorption spectra of liquid water at 300 K are calculated from both classical and density functional theory molecular dynamics simulation data, which together span from 1 MHz to hundreds of THz, agreeing well with experimental data…

Chemical Physics · Physics 2020-09-09 Shane Carlson , Florian N. Brünig , Philip Loche , Douwe Jan Bonthuis , Roland R. Netz

Experimental studies were carried out on the motions and transformations of liquid metal in ionic liquid under applied electric field. The induced vortex rings and flows of ionic liquid were determined via the photographs taken sequentially…

Fluid Dynamics · Physics 2017-04-13 Fujun Liu , Yongze Yu , Jing Liu

Future laser-interferometric gravitational wave detectors (GWDs) will potentially employ test mass mirrors from crystalline silicon and a laser wavelength of $1550\,\rm{nm}$, which corresponds to a photon energy below the silicon bandgap.…

We report optical absorption imaging of ultracold neutral plasmas.Images are used to measure the ion absorption spectrum, which is Doppler-broadened. Through the spectral width, we monitor ion equilibration in the first 250ns after plasma…

Atomic Physics · Physics 2009-11-10 C. E. Simien , Y. C. Chen , P. Gupta , S. Laha , Y. N. Martinez , P. G. Mickelson , S. B. Nagel , T. C. Killian

Electronic charge delocalization on the molecular backbones of ionic liquid-forming ions substantially impacts their molecular polarizabilities. Density functional theory calculations of polarizabilities and volumes of many cations and…

Soft Condensed Matter · Physics 2024-01-31 C. D. Rodriguez-Fernandez , E. Lopez Lago , C. Schroder , L. M. Varela

In this study, we examined the thickness of the electrical double layer (EDL) in ionic liquids using density functional theory (DFT) calculations and molecular dynamics (MD) simulations. We focused on the BF4- anion adsorption from…

The structure of ionic adsorption layers is studied via a proper thermodynamic treatment of the electrostatic and non-electrostatic interactions between the surfactant ions as well as of the effect of thermodynamic non-locality. The…

Soft Condensed Matter · Physics 2014-10-28 R. Tsekov

The photomolecular effect has been hypothesized to enhance evaporation of water at visible wavelengths. This study develops a measurement technique to investigate its presence and magnitude at the liquid-vapor interface of water. The…

Optics · Physics 2026-03-19 Preston Bohm , Mingjun Li , Akanksha K. Menon , Zhuomin M. Zhang

This paper presents a new technique to study the adsorption and desorption of ions and electrons on insulating surfaces in the presence of strong electric fields in cryoliquids. The experimental design consists of a compact cryostat coupled…

The isotope effects in x-ray absorption spectra of liquid water are studied by a many-body approach within electron-hole excitation theory. The molecular structures of both light and heavy water are modeled by path-integral molecular…

Disordered Systems and Neural Networks · Physics 2020-09-29 Chunyi Zhang , Linfeng Zhang , Jianhang Xu , Fujie Tang , Biswajit Santra , Xifan Wu

Experimental measurements of interactions in ionic liquids and concentrated electrolytes over the past decade or so have revealed simultaneous monotonic and oscillatory decay modes. These observations have been hard to interpret using…

Soft Condensed Matter · Physics 2024-02-28 Timothy S. Groves , Susan Perkin

The ionic-liquid-gating technique can be applied to the search for novel physical phenomena at low temperatures because of its wide controllability of the charge carrier density. Ionic-liquid gated field-effect transistors are often fragile…

In this experiment liquid water is subject to an inhomogeneous electric field (${\nabla}^2 E_a {\approx} 10^{10} \frac{V}{m^2}$ ) using a high voltage (20 kV) point-plane electrode system. With interferometry it was found that the…

Mesoscale and Nanoscale Physics · Physics 2016-06-29 Adam D. Wexler , Sandra Drusová , Jakob Woisetschläger , Elmar C. Fuchs

We use a string of confined $^{40}$Ca$^+$ ions to measure perturbations to a trapping potential which are caused by light-induced charging of an anti-reflection coated window and of insulating patches on the ion-trap electrodes. The…

Quantum Physics · Physics 2010-09-28 Maximilian Harlander , Michael Brownnutt , Wolfgang Hänsel , Rainer Blatt

The optical properties of silicon can be greatly tuned by applying strain and opening new perspectives, particularly in applications where infrared is key. In this work, we use a recent model for the indirect light absorption of silicon and…

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