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We study the site occupancy and magnetic properties of Zn-Sn substituted M-type Sr-hexaferrite SrFe$_{12-x}$(Zn$_{0.5}$Sn$_{0.5}$)$_x$O$_{19}$ with x = 1 using first-principles total-energy calculations. We find that in a ground-state…

Materials Science · Physics 2015-06-11 Laalitha S. I. Liyanage , Sungho Kim , Yang Ki Hong , Ji-Hoon Park , Steven C. Erwin , Seong-Gon Kim

We use first-principles total-energy calculations based on density functional theory to study the site occupancy and magnetic properties of Al-substituted $M$-type strontium hexaferrite SrFe$_{12-x}$Al$_{x}$O$_{19}$ with $x=0.5$ and…

To investigate the structural and magnetic properties of Cr-doped M-type strontium hexaferrite (SrFe$_{12}$O$_{19}$) with x = (0.0, 0.5, 1.0), we perform first-principles total-energy calculations relied on density functional theory. Based…

Materials Science · Physics 2023-06-22 Binod Regmi , Dinesh Thapa , Bipin Lamichhane , Seong-Gon Kim

An important aspect of materials research is the ability to tune different physical properties through controlled alloying. The Ln$_3$M$_4$X$_{13}$ (Ln = Lanthanide, M = Transition Metal, X = Tetrel) filled skutterudite family is of…

Materials Science · Physics 2025-11-10 Jacob W. Fritsky , Hui-Fei Zhai , Yifeng Zhao , Aryan Rauniyar , Antia S. Botana , Jason F. Khoury

The synthesis of aluminum substituted strontium hexaferrite nanoparticles (SrFe12-xAlxO19 with x = 0-3), via three different preparation methods, is investigated. The synthesis methods are hydrothermal autoclave (AC) synthesis, a citrate…

The La-Co co-substituted magnetoplumbite-type (M-type) ferrites $A$Fe$_{12}$O$_{19}$ ($A$ = Ca, Sr and Ba, ion sizes Ca$^{2+}$ $<$ Sr$^{2+}$ $<$ Ba$^{2+}$) with Co compositions around 0.2 have been subjected to $^{59}$Co-NMR. The results…

We report a comprehensive study of the temperature-dependent structural, magnetic, vibrational, and dielectric properties of Al-substituted M-type hexaferrites SrFe$_{12-x}$Al$_x$O$_{19}$. Neutron powder diffraction and M\"ossbauer…

A first-principles approach combining density functional and dynamical mean-field theories in conjunction with a quasi-atomic approximation for the strongly localized 4$f$ shell is applied to Nd$_{2}$Fe$_{14}$B-based hard magnets in order…

Strongly Correlated Electrons · Physics 2022-07-01 James Boust , Alex Aubert , Bahar Fayyazi , Konstantin P. Skokov , Yurii Skourski , Oliver Gutfleisch , Leonid V. Pourovskii

The mechanisms underlying the enhancement of magnetic anisotropies (MAs) of Sm ions, owing to valence electrons at the Sm site and the screened nuclear charges of ligands, are clarified using a detailed analysis of crystal fields (CF). In…

Materials Science · Physics 2022-01-12 Takuya Yoshioka , Hiroki Tsuchiura , Pavel Novák

This study investigates Mn-Zn ferrites (nominal composition \ce{Mn_{0.5}Zn_{0.5}Fe2O4}, MZF) substituted with tetravalent (\ce{Si^{4+}}), trivalent (\ce{Co^{3+}}), and divalent (\ce{Ca^{2+}}, \ce{Mg^{2+}}, \ce{Sn^{2+}}) ions. We…

Materials Science · Physics 2025-06-10 Jiahao Li , Kusma Kumari Cheepurupalli , Niall J. English , Sateesh Bandaru , Xuefeng Zhang

By performing density functional calculations, we find a giant magnetocrystalline anisotropy (MCA) constant in abundant element cerium (Ce) substituted M-type hexaferrite, in the energetically favorable strontium site, assisted by a quantum…

Materials Science · Physics 2023-08-21 Churna Bhandari , Durga Paudyal

In the search for improved permanent magnets, fueled by the geostrategic and environmental issues associated with rare-earth-based magnets, magnetically hard (high anisotropy)-soft (high magnetization) composite magnets hold promise as…

We report magnetocrystalline anisotropy of pure and Fe/Si substituted SmCo5. The calculations were performed using the advanced density functional theory (DFT) including onsite electron-electron correlation and spin orbit coupling. Si…

Materials Science · Physics 2019-12-10 Rajiv K. Chouhan , A. K. Pathak , D. Paudyal

We have carried out \textit{ab-initio} calculations of local structure of Mn and Ni in Mn$_{2}$Ni$_{1.5}$In$_{0.5}$ alloy with different site occupancies in order to understand the similarities in martensitic and magnetic properties of…

Materials Science · Physics 2017-01-31 D. N. Lobo , K. R. Priolkar , A. Koide , S. Emura

A delicate balance between various factors such as site occupancy, composition and magnetic ordering seems to affect the stability of the martensitic phase in Mn$_{2}$Ni$_{1+x}$Sn$_{1-x}$. Using first-principles DFT calculations, we explore…

Materials Science · Physics 2018-01-17 Ashis Kundu , Subhradip Ghosh

A series of Ni0.6-x/2Zn0.4-x/2SnxFe2O4 (x = 0.0, 0.05, 0.1, 0.15, 0.2 and 0.3) (NZSFO) ferrite composites have been synthesized from nano powders using standard solid state reaction technique. The spinel cubic structure of the investigated…

Materials Science · Physics 2017-08-02 M. A. Ali , M. M. Uddin , M. N. I. Khan , F. -U. -Z. Chowdhury , S. M. Hoque , S. I. Liba

We investigate the effect of Mn substitution in Fe$_2$Ti$_{1-x}$Mn$_x$Sn on electronic structure and magnetic and electrical transport properties. The spin-polarized density of states calculations using density-functional theory (DFT)…

Materials Science · Physics 2025-08-20 Kulbhushan Mishra , Shishir Kumar Pandey , S. Chaudhuri , Rajeev Rawat , P. A. Bhobe

Theoretical and experimental investigation of the electronic and magnetic structure of transition metal atoms on an insulating interface with a metallic substrate at low temperatures is quite challenging. In this paper, we show a density…

Recent experimental studies on Fe substituted spinel CoCr$_{2}$O$_{4}$ have discovered multiple functional properties in the system such as temperature and composition dependent magnetic compensation, tunable exchange bias and…

Materials Science · Physics 2018-08-29 Debashish Das , Subhradip Ghosh

The structural and magnetic properties of ZnFe2O4 nanoparticles embedded in a non-magnetic ZnO matrix are presented. X-ray diffractograms and Transmission Electron Microscopy (TEM) images showed that the resulting samples are composed of…

Materials Science · Physics 2012-12-13 G. F. Goya , E. R. Leite
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