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A procedure for defining virtual spaces, and the periodic one-electron and two-electron integrals, for plane-wave second quantized Hamiltonians has been developed and demonstrated using full configuration interaction (FCI) simulations and…

We present a novel energy-based localization procedure able to localize molecular orbitals into specific spatial regions. The method is applied to several cases including both conjugated and non-conjugated systems. The obtained localized…

Chemical Physics · Physics 2022-09-13 Tommaso Giovannini , Henrik Koch

Astronomy is presently experiencing profound growth in the deployment of machine learning to explore large datasets. However, transient quasi-periodic oscillations (QPOs) which appear in power density spectra of many X-ray binary system…

High Energy Astrophysical Phenomena · Physics 2023-06-28 Thaddaeus J. Kiker , James F. Steiner , Cecilia Garraffo , Mariano Mendez , Liang Zhang

The projection of the eigenfunctions obtained in standard plane-wave first-principle electronic-structure calculations into atomic-orbital basis sets is proposed as a formal and practical link between the methods based on plane waves and…

Condensed Matter · Physics 2009-10-28 Daniel Sanchez-Portal , Emilio Artacho , Jose M. Soler

We adapt the simulated annealing algorithm to the search of periodic orbits for classical multi-electron atomic systems. This is done by minimizing the n-th return distance to the initial position on a Poincare surface of section under an…

Atomic Physics · Physics 2011-02-17 Francois Mauger , Cristel Chandre , Turgay Uzer

We generalize our recent approach to reconstruction of phase dynamics of coupled oscillators from data [B. Kralemann et al., Phys. Rev. E, 77, 066205 (2008)] to cover the case of small networks of coupled periodic units. Starting from the…

Chaotic Dynamics · Physics 2015-05-27 Björn Kralemann , Arkady Pikovsky , Michael Rosenblum

Tobasco et al. [Physics Letters A, 382:382-386, 2018; see https://doi.org/10.1016/j.physleta.2017.12.023] recently suggested that trajectories of ODE systems that optimize the infinite-time average of a certain observable can be localized…

New effective operators, describing the photons with given polarization at given position with respect to a source are proposed. These operators can be used to construct the near and intermediate zones quantum optics. It is shown that the…

Quantum Physics · Physics 2007-05-23 Alexander S. Shumovsky , Alexander A. Klyachko

We formulate an adiabatic connection for the exchange-correlation energy in terms of pairing matrix fluctuation. This connection opens new channels for density functional approximations based on pairing interactions. Even the simplest…

Chemical Physics · Physics 2015-06-16 Helen van Aggelen , Yang Yang , Weitao Yang

Oscillators are ubiquitous in nature, and usually associated with the existence of an asymptotic phase that governs the long-term dynamics of the oscillator. % We show that asymptotic phase can be estimated using a carefully chosen series…

Dynamical Systems · Mathematics 2022-03-10 Simon Wilshin , Matthew D. Kvalheim , Clayton Scott , Shai Revzen

It has recently been shown that optical parametric oscillator (OPO) Ising machines, consisting of coupled optical pulses circulating in a cavity with parametric gain, can be used to probabilistically find low-energy states of Ising spin…

In order for methods combining ab initio density-functional theory and many-body techniques to become routinely used, a flexible, fast, and easy-to-use implementation is crucial. We present an implementation of a general charge…

We present an optimized random phase approximation method (optRPA26) that significantly improves upon conventional RPA. The method employs an empirically constructed hybrid functional to generate DFT orbitals to evaluate the RPA correlation…

Chemical Physics · Physics 2026-02-06 Neung-Kyung Yu , Johannes Voss , Andrew J. Medford

The particle-particle random phase approximation (pp-RPA) has been shown to be capable of describing double, Rydberg, and charge transfer excitations, for which the conventional time-dependent density functional theory (TDDFT) might not be…

Computational Physics · Physics 2017-04-26 Jianfeng Lu , Haizhao Yang

Density functional theory offers accurate structure prediction at acceptable computational cost, but commonly used approximations suffer from delocalization error; this results in inaccurate predictions of quantities such as energy band…

Materials Science · Physics 2022-08-17 Aaron Mahler , Jacob Z. Williams , Neil Qiang Su , Weitao Yang

Variational quantum eigensolvers (VQE) are among the most promising approaches for solving electronic structure problems on near-term quantum computers. A critical challenge for VQE in practice is that one needs to strike a balance between…

Out-of-time-order correlators (OTOCs) are central probes of quantum scrambling, and their generalizations have recently become key primitives for both benchmarking quantum advantage and learning the structure of Hamiltonians. Yet their…

Quantum Physics · Physics 2025-12-01 Keisuke Fujii

While the dynamical origin of the variability observed in Galactic Black hole systems, such as quasi-periodic oscillations (QPOs), are still a matter of debate, insight into the radiative components responsible for such behaviour can be…

High Energy Astrophysical Phenomena · Physics 2020-09-30 Akash Garg , Ranjeev Misra , Somasri Sen

Optical parametric oscillations (OPOs) - a non-linear process involving the coherent coupling of an optically excited two particle pump state to a signal and an idler states with different energies - is a relevant mechanism for optical…

Other Condensed Matter · Physics 2020-03-04 Alexander S. Kuznetsov , Galbadrakh Dagvadorj , Klaus Biermann , Marzena Szymanska , Paulo V. Santos

We present a new method for modeling disordered solid solutions, based on the virtual crystal approximation (VCA). The VCA is a tractable way of studying configurationally disordered systems; traditionally, the potentials which represent…

Materials Science · Physics 2009-10-31 Nicholas J. Ramer , Andrew M. Rappe