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The binary polyhydrides of heavy rare earth lutetium that shares a similar valence electron configuration to lanthanum have been experimentally discovered to be superconductive. The lutetium polyhydrides were successfully synthesized at…

High-pressure hydrogen-rich compounds have long been regarded as promising room-temperature superconductor candidates; however, their practical applications are limited by their reliance on extreme compression. This study explores…

Superconductivity · Physics 2026-02-04 Qun Wei , Xinyu Wang , Jing Luo , Meiguang Zhang , Bing Wei

Clathrates are a class of inclusion compounds that offer various useful and surprising phenomena, including superconductivity, thermoelectricity, and the potential for high-density ion storage. Stability conditions within the…

Materials Science · Physics 2026-04-08 Frank Cerasoli , Xiaochen Jin , Genevieve Amobi , Kirill Kovnir , Davide Donadio

Niobium polyhydride was synthesized at high pressure and high temperature conditions by using diamond anvil cell combined with in situ high pressure laser heating techniques. High pressure electric transport experiments demonstrate that…

Early quantum mechanical models suggested that pressure drives solids towards free-electron metal behavior where the ions are locked into simple close-packed structures. The prediction and subsequent discovery of high-pressure electrides…

Materials Science · Physics 2023-11-06 Stefano Racioppi , Christian V. Storm , Malcolm I. McMahon , Eva Zurek

Single crystals of the compound LaFePO were prepared using a flux growth technique at high temperatures. Electrical resistivity measurements reveal metallic behavior and a resistive transition to the superconducting state at a critical…

Superconductivity · Physics 2008-09-10 J. J. Hamlin , R. E. Baumbach , D. A. Zocco , T. A. Sayles , M. B. Maple

In the last decade, there has been great progress in predicting and synthesizing polyhydrides that exhibit superconductivity when squeezed. Dopants allow these compounds to become metals at pressures lower than those required to metallize…

Materials Science · Physics 2024-05-21 Xiaoyu Wang , Nisha Geng , Kyla de Villa , Burkard Militzer , Eva Zurek

We study the stability of Li-O compounds as a function of pressure, with Li ion battery applications and fundamental chemical interest in mind. Using the ab initio evolutionary algorithm, we predict stability of novel compounds LiO4, Li5O3…

Materials Science · Physics 2019-10-29 Xiao Dong , Yan-Ling Li , Artem R. Oganov , Kuo Li , Haiyan Zheng , Ho-kwang Mao

The dependence of the superconducting transition temperature T_{c} on nearly hydrostatic pressure has been determined to 67 GPa in an ac susceptibility measurement for a Li sample embedded in helium pressure medium. With increasing…

Superconductivity · Physics 2009-11-10 Shanti Deemyad , James S. Schilling

AgSbTe2 is a well-known thermoelectric material with a high Seebeck coefficient and intrinsically low thermal conductivity, but its behavior under pressure remains largely unexplored. Here we report a systematic investigation of the…

Over the past six years, superconductivity at high temperatures has been reported in a variety of hydrogen-rich compounds under high pressure. That high-temperature superconductivity should exist in these materials is expected according to…

Superconductivity · Physics 2021-04-14 J. E. Hirsch , F. Marsiglio

Motivated by the recent report of superconductivity above 200 K in ultra-dense hydrogen sulfide, we search for high-\tc\ conventional superconductivity in the phase diagram of the binary Li-S system, using {\em ab-initio} methods for…

Superconductivity · Physics 2016-08-10 Christian Kokail , Christoph Heil , Lilia Boeri

Very recently carbon-rich NaC6 with sodalite-like structure has been predicted to show superconducting transition temperature above 100 K at relatively low applied (compared to high-Tc hydrides) hydrostatic pressures. We have investigated…

Superconductivity · Physics 2021-09-08 Nazmun Sadat Khan , B. Rahman Rano , Ishtiaque M. Syed , R. S. Islam , S. H. Naqib

In Phys. Rev. Lett. 102, 197002 (2009) it was reported that the element Eu becomes superconducting in the pressure and temperature range [84-142GPa], [1.8-2.75K]. The claim was largely based on ac susceptibility measurements. Recently…

Superconductivity · Physics 2021-12-10 J. E. Hirsch

Recently, C. M. P\'epin \textit{et al.} [Science \textbf{357}, 382 (2017)] reported the formation of several new iron polyhydrides FeH$_x$ at pressures in the megabar range, and spotted FeH$_5$, which forms above 130 GPa, as a potential…

Superconductivity · Physics 2018-06-15 Christoph Heil , Giovanni B. Bachelet , Lilia Boeri

In this letter, we report the discovery of superconductivity in Li3Ca2C6. Several graphite intercalation compounds (GICs) with electron donors, are well known as superconductors. It is probably not astonishing, since it is generally…

Since the discovery of superconductivity at 200 K in H3S [1] similar or higher transition temperatures, Tcs, have been reported for various hydrogen-rich compounds under ultra-high pressures [2]. Superconductivity was experimentally proved…

Actinide materials play a special role in condensed matter physics, spanning behaviours of itinerant d-electron and localized 4f-electron materials. An intermediate state, found notably in Pu-based materials whose 5f electrons are neither…

Strongly Correlated Electrons · Physics 2007-05-23 J. D. Thompson , J. L. Sarrao , N. J. Curro , E. D. Bauer , L. A. Morales , F. Wastin , J. Rebizant , J. C. Griveau , P. Boulet , E. Colineau , G. H. Lander

Intermetallic compounds containing f-electron elements display a wealth of superconducting phases, that are prime candidates for unconventional pairing with complex order parameter symmetries. For instance, superconductivity has been found…

Superconductivity · Physics 2010-01-19 C. Pfleiderer

The discovery of a record high superconducting transition temperature (Tc) of 288 K in a pressurized hydride inspires new hope to realize ambient condition superconductivity. Here, we give a perspective on the theoretical and experimental…

Superconductivity · Physics 2021-12-21 Dong Wang , Yang Ding , Ho-Kwang Mao