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Detailed understanding of solid-solid interface structure-function relations is critical for the improvement and wide deployment of all solid-state batteries. The interfaces between lithium phosphorous oxynitride ("LiPON") solid electrolyte…

We have demonstrated a fiber lithium ion battery (LIB) fabricated by co-twisting a LiFePO4 composite-coated copper wire (cathode) together with an aluminum wire (anode). An all-solid LiPF6 composite layer functioning both as the electrolyte…

Applied Physics · Physics 2019-03-20 H. Qu , X. Lu , M. Skorobogatiy

Dendrite free electrodeposition of lithium metal is necessary for the adoption of high energy density rechargeable lithium metal batteries. Here, we demonstrate a new mechanism of using a liquid crystalline electrolyte to suppress dendrite…

Applied Physics · Physics 2020-10-29 Zeeshan Ahmad , Zijian Hong , Venkatasubramanian Viswanathan

Lithium intercalated anatase used in Li-ion batteries has some special features: coexistence of Li-rich and Li-poor phases as well as two possible positions for Li ions in the oxygen tetrahedron. A theoretical description of the compound…

Materials Science · Physics 2009-07-06 O. V. Velychko , I. V. Stasyuk

A comprehensive understanding of interactions between cathode, electrolyte, anode, and packaging during battery operation is crucial for advancing performances but remains overlooked due to the lack of characterisation technics capable of…

The sequential group-by-group charging/discharging in Li batteries with phase-separation thermodynamics was detected by numerical simulations and justified by several experiments published in literature. The present work is the first to…

Pattern Formation and Solitons · Physics 2021-04-22 Moshe Sheintuch , Olga Nekhamkina

We carefully investigated the storage of lithium in titania films on various substrates as a function of thickness. The experiments enable us to precisely separate contributions from bulk and boundary storage. The battery capacity…

Chemical Physics · Physics 2023-03-24 Chuanlian Xiao , Hongguang Wang , Peter A. van Aken , Robert Usiskin , Joachim Maier

Internal short circuits are a leading cause of battery thermal runaway, and hence a major safety issue for electric vehicles. An internal short circuit with low resistance is called a hard internal short, which causes a high internal…

Systems and Control · Electrical Eng. & Systems 2020-10-27 Ting Cai , Peyman Mohtat , Anna G. Stefanopoulou , Jason B. Siegel

Silicon is a promising anode material for next-generation lithium-ion batteries. However, the volume change and the voltage hysteresis during lithiation and delithiation are two substantial drawbacks to their lifetime and performance. We…

Chemical Physics · Physics 2024-02-19 Lukas Köbbing , Arnulf Latz , Birger Horstmann

Owing to their multiple applications, lithium ferrites are relevant materials for several emerging technologies. For instance, LiFeO2 has been spotted as an alternative cathode material in Li-ion batteries, while LiFe5O8 is the lowest…

Despite significant potential as energy storage materials for electric vehicles due to their combination of high energy density per unit cost and reduced environmental and ethical concerns, Co-free lithium ion batteries based off layered Mn…

The atomistic mechanisms during lithiation and delithiation of amorphous Si nanowires ($a$-SiNW) have been investigated over cycles by molecular dynamics simulations. First, the Modified Embedded Atom Method (MEAM) potential from Cui et al.…

Materials Science · Physics 2020-07-01 Julien Godet , Teute Bunjaku , Mathieu Luisier

A new superstructure of layered pristine LiNiO2 (LNO) was obtained optimizing a large supercell of the 166 space group, the one observed experimentally by XRD, and relaxing both cell parameters and internal positions. The crystal structure…

Materials Science · Physics 2023-10-19 Saleem Yousuf , Md Maruf Mridha , Rita Magri

Recently some critical problems and challenges have been exposed, hindering the development and practical application of SSLBs, such as the low room temperature ionic conductivity of solid electrolyte, the risk of short circuit caused by…

Materials Science · Physics 2023-08-01 L. J. Zhang

The existing solid electrolytes for lithium ion batteries suffer from low total ionic conductivity, which restricts its usefulness for the lithium-ion battery technology. Among them, the NASICON-based materials, such as…

Chemical Physics · Physics 2020-08-03 K. Kwatek , W. Ślubowska , J. Trébosc , O. Lafon , J. L. Nowiński

Lithium (Li) metal anodes are essential for developing next-generation high-energy-density batteries. However, Li dendrite/whisker formation caused short-circuiting issue and short cycle life have prevented lithium metal from being viably…

Materials Science · Physics 2022-05-02 Bingyu Lu , Wurigumula Bao , Weiliang Yao , Jean-Marie Doux , Chengcheng Fang , Ying Shirley Meng

Aging limits lithium-ion battery lifetime and must be understood to improve durability and performance, requiring a detailed understanding of how aging alters the availability of cyclable lithium and the integrity of active particles. In…

We have determined Li abundances in 55 metal-poor (3.6 < [Fe/H] < -0.7) stars with extreme orbital kinematics. We find the Li abundance in the Li-plateau stars and examine its decrease in low-temperature, low-mass stars. The Li observations…

Astrophysics · Physics 2009-11-13 Ann Merchant Boesgaard , Alex Stephens , Constantine P. Deliyannis

Silicon suboxide is currently considered as a unique candidate for lithium ion batteries anode materials due to its considerable capacity. However, no adequate information exist about the role of oxygen content on its performance. To this…

Materials Science · Physics 2017-03-28 Obaidur Rahaman , Bohayra Mortazavi , Timon Rabczuk

Lithium-metal batteries employing concentrated glyme-based electrolytes and different cathode chemistries are herein evaluated in view of a safe use of the highly energetic alkali-metal anode. Indeed, diethylene-glycol dimethyl-ether…

Applied Physics · Physics 2021-10-27 Vittorio Marangon , Luca Minnetti , Matteo Adami , Alberto Barlini , Jusef Hassoun