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A quantitative first-principles description of complex substitutional materials like alloys is challenging due to the vast number of configurations and the high computational cost of solving the quantum-mechanical problem. Therefore,…

Materials Science · Physics 2025-06-24 Adrian Stroth , Claudia Draxl , Santiago Rigamonti

Density functional theory (DFT)-based simulations of materials have first-principles accuracy, but are very computationally expensive. For simulating various properties of multi-component alloys, the cluster expansion (CE) technique has…

Materials Science · Physics 2026-04-01 Jacob Jeffries , Bochuan Sun , Enrique Martinez

The Cluster Expansion (CE) Method encounters significant computational challenges in multicomponent systems due to the computational expense of generating training data through density functional theory (DFT) calculations. This work aims to…

Materials Science · Physics 2024-12-10 Guillermo Vazquez , Daniel Sauceda , Raymundo Arróyave

Cluster expansions are commonly employed as surrogate models to link the electronic structure of an alloy to its finite-temperature properties. Using cluster expansions to model materials with several alloying elements is challenging due to…

Materials Science · Physics 2025-01-31 Yann L. Müller , Anirudh Raju Natarajan

Long-standing challenges in cluster expansion (CE) construction include choosing how to truncate the expansion and which crystal structures to use for training. Compressive sensing (CS), which is emerging as a powerful tool for model…

Materials Science · Physics 2013-10-30 Lance J Nelson , Vidvuds Ozolins , Shane Reese , Fei Zhou , Gus L. W. Hart

Cluster expansion (CE) is effective in modeling the stability of metallic alloys, but sometimes cluster expansions fail. Failures are often attributed to atomic relaxation in the DFT-calculated data, but there is no metric for quantifying…

Materials Science · Physics 2017-07-19 Andrew H. Nguyen , Conrad W. Rosenbrock , C. Shane Reese , Gus L. W. Hart

The cluster expansion model (CEM) provides a powerful computational framework for rapid estimation of configurational properties in disordered systems. However, the traditional CEM construction procedure is still plagued by two fundamental…

Disordered Systems and Neural Networks · Physics 2023-07-24 Bibek Dash , Suhail Haque , Abhijit Chatterjee

Crystalline alloys and related mixed systems make up a large family of materials with high tunability which have been proposed as the solution to a large number of energy related materials design problems. Due to the presence of chemical…

Materials Science · Physics 2025-01-28 Pernilla Ekborg-Tanner , Petter Rosander , Erik Fransson , Paul Erhart

Identifying a suitable set of descriptors for modeling physical systems often utilizes either deep physical insights or statistical methods such as compressed sensing. In statistical learning, a class of methods known as structured sparsity…

Materials Science · Physics 2019-10-30 Zhidong Leong , Teck Leong Tan

Alloy cluster expansions (CEs) provide an accurate and computationally efficient mapping of the potential energy surface of multi-component systems that enables comprehensive sampling of the many-dimensional configuration space. Here, we…

We present the Python package CELL, which provides a modular approach to the cluster expansion (CE) method. CELL can treat a wide variety of substitutional systems, including one-, two-, and three-dimensional alloys, in a general…

Materials Science · Physics 2023-10-30 Santiago Rigamonti , Maria Troppenz , Martin Kuban , Axel Hübner , Claudia Draxl

Machine learning interatomic potentials are revolutionizing large-scale, accurate atomistic modelling in material science and chemistry. Many potentials use atomic cluster expansion or equivariant message passing frameworks. Such frameworks…

Computational Physics · Physics 2024-07-31 Bingqing Cheng

We present an atomic cluster expansion (ACE) for carbon that improves over available classical and machine learning potentials. The ACE is parameterized from an exhaustive set of important carbon structures at extended volume and energy…

Materials Science · Physics 2023-06-13 Minaam Qamar , Matous Mrovec , Yury Lysogorskiy , Anton Bochkarev , Ralf Drautz

We have developed a method to improve the doping computation efficiency, this method is based on first principles calculations and cluster expansion. First principles codes produce highly accurate total energies and optimized geometries for…

Materials Science · Physics 2017-03-02 Zongguo Wang , Xiaoyu Yang , Xushan Zhao , Ligen Wang , Juan Wang , Mingming Zhang , Jie Ren

Finite temperature disordered solid solutions and magnetic materials are difficult to study directly using first principles calculations, due to the large unit cells and many independent samples that are required. In this work, we develop a…

Materials Science · Physics 2019-05-22 Kevin F. Garrity

Cluster analysis plays a very important role in data analysis. In these years, cluster ensemble, as a cluster analysis tool, has drawn much attention for its robustness, stability, and accuracy. Many efforts have been done to combine…

Computer Vision and Pattern Recognition · Computer Science 2019-04-19 Xuelong Li , Quanmao Lu , Yongsheng Dong , Dacheng Tao

Finding Minimum Energy Configurations (MECs) is essential in fields such as physics, chemistry, and materials science, as they represent the most stable states of the systems. In particular, identifying such MECs in multi-component alloys…

Materials Science · Physics 2025-01-27 Md Rajib Khan Musa , Yichen Qian , Jie Peng , David Cereceda

We present a novel cluster-expansion (CE) approach for the first-principles modeling of temperature and concentration dependent alloy properties. While the standard CE method includes temperature effects only via the configurational entropy…

Materials Science · Physics 2013-05-30 D. Reith , M. Stöhr , R. Podloucky , T. C. Kerscher , S. Müller

A Magnetic Cluster Expansion (MCE) model for ternary face-centered cubic Fe-Ni-Cr alloys has been developed using DFT data spanning binary and ternary alloy configurations. Using this MCE model Hamiltonian, we perform Monte Carlo…

Materials Science · Physics 2016-11-24 M. Y. Lavrentiev , J. S. Wróbel , D. Nguyen-Manh , S. L. Dudarev , M. G. Ganchenkova

Excited-state electronic structure in strongly correlated systems remains challenging due to the exponential scaling of the many-body Hilbert space and the difficulty of constructing systematically controlled active spaces. Building on the…

Chemical Physics · Physics 2026-05-05 Annabelle Canestraight , Russell Miller , Libor Veis , Vojtech Vlcek
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