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Model Hamiltonians with long-range interaction yield energies that are corrected taking into account the universal behavior of the electron-electron interaction at short range. Although the intention of the paper is to explore the…

Chemical Physics · Physics 2020-10-28 Andreas Savin

We present an accurate and efficient framework for real-space Hubbard-corrected density functional theory. In particular, we obtain expressions for the energy, atomic forces, and stress tensor suitable for real-space finite-difference…

Computational Physics · Physics 2025-10-20 Sayan Bhowmik , Andrew J. Medford , Phanish Suryanarayana

Density functional theory is one of the most efficient and widely used computational methods of quantum mechanics, especially in fields such as solid state physics and quantum chemistry. From the theoretical perspecive, its central object…

Chemical Physics · Physics 2025-11-25 Mihály A. Csirik , Andre Laestadius , Mathias Oster

We present a metric-space approach to quantify the performance of density-functional approximations for interacting many-body systems and to explore the validity of the Hohenberg-Kohn-type theorem on fermionic lattices. This theorem…

Quantum Physics · Physics 2018-03-06 V. V. França , J. P. Coe , I. D'Amico

Density functional theory (DFT) offers a desirable balance between quantitative accuracy and computational efficiency in practical many-electron calculations. Its central component, the exchange-correlation energy functional, has been…

Machine learning methods are applied to finding the Green's function of the Anderson impurity model, a basic model system of quantum many-body condensed-matter physics. Different methods of parametrizing the Green's function are…

Strongly Correlated Electrons · Physics 2015-06-22 Louis-François Arsenault , Alejandro Lopez-Bezanilla , O. Anatole von Lilienfeld , Andrew J. Millis

We show that deep neural networks can be integrated into, or fully replace, the Kohn-Sham density functional theory scheme for multi-electron systems in simple harmonic oscillator and random external potentials with no feature engineering.…

Materials Science · Physics 2021-02-25 Kevin Ryczko , David Strubbe , Isaac Tamblyn

Density-functional theory with extended Hubbard functionals (DFT+$U$+$V$) provides a robust framework to accurately describe complex materials containing transition-metal or rare-earth elements. It does so by mitigating self-interaction…

Materials Science · Physics 2025-01-30 Martin Uhrin , Austin Zadoks , Luca Binci , Nicola Marzari , Iurii Timrov

In this chapter, we discuss recent advances and new opportunities through methods of machine learning for the field of classical density functional theory, dealing with the equilibrium properties of thermal nano- and micro-particle systems…

Statistical Mechanics · Physics 2024-06-12 Alessandro Simon , Martin Oettel

An extended electron model fully recovers many of the experimental results of quantum mechanics while it avoids many of the pitfalls and remains generally free of paradoxes. The formulation of the many-body electronic problem here resembles…

Computational Physics · Physics 2018-12-03 Thomas Pope , Werner Hofer

A generalization of the Density Functional Theory is proposed. The theory developed leads to single-particle equations of motion with a quasi-local mean-field operator, which contains a quasi-particle position-dependent effective mass and a…

Nuclear Theory · Physics 2009-11-07 V. B. Soubbotin , V. I. Tselyaev , X. Vinas

The Hohenberg-Kohn theorem of density functional theory (DFT) for the case of electrons interacting with an external magnetic field (that couples to spin only) is examined in more detail than previously. A unexpected generalization is…

Strongly Correlated Electrons · Physics 2009-10-31 H. Eschrig , W. E. Pickett

Based on recent progress on fermionic exchange symmetry we propose a way to develop new functionals for reduced density matrix functional theory. For some settings with an odd number of electrons, by assuming saturation of the inequalities…

Strongly Correlated Electrons · Physics 2018-10-23 Carlos L. Benavides-Riveros , Miguel A. L. Marques

We demonstrate that a machine learning framework based on kernel ridge regression can encode and predict the self-energy of one-dimensional Hubbard models using only mean-field features such as static and dynamic Hartree-Fock quantities and…

Strongly Correlated Electrons · Physics 2026-05-08 Mateo Cárdenes Wuttig

The fermionic and bosonic sectors of the 2-site Hubbard model have been exactly solved by means of the equation of motion and Green's function formalism. The exact solution of the t-J model has been also reported to investigate the…

Strongly Correlated Electrons · Physics 2007-05-23 Adolfo Avella , Ferdinando Mancini , Taiichiro Saikawa

A framework for developing new approximate electronic structure methods is presented, in which the correlation energy of a many-electron system in the ground state is computed as in the single-reference second-order many-body perturbation…

Chemical Physics · Physics 2011-06-15 Dimitri Laikov

Correlated many-body problems ubiquitously appear in various fields of physics such as condensed matter physics, nuclear physics, and statistical physics. However, due to the interplay of the large number of degrees of freedom, it is…

Strongly Correlated Electrons · Physics 2018-02-12 Hiroyuki Fujita , Yuya O. Nakagawa , Sho Sugiura , Masaki Oshikawa

We develop a variational method to obtain many-body ground states of the Bose-Hubbard model using feedforward artificial neural networks. A fully-connected network with a single hidden layer works better than a fully-connected network with…

Disordered Systems and Neural Networks · Physics 2018-01-17 Hiroki Saito , Masaya Kato

Calculating perturbation response properties of materials from first principles provides a vital link between theory and experiment, but is bottlenecked by the high computational cost. Here a general framework is proposed to perform density…

Computational Physics · Physics 2024-03-01 He Li , Zechen Tang , Jingheng Fu , Wen-Han Dong , Nianlong Zou , Xiaoxun Gong , Wenhui Duan , Yong Xu

High throughput screening of materials for technologically relevant areas, like identification of better catalysts, electronic materials, ceramics for high temperature applications and drug discovery, is an emerging topic of research. To…

Chemical Physics · Physics 2020-05-04 Edgar Josué Landinez Borda , Amit Samanta