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Density-functional theory is a formally exact description of a many-body quantum system in terms of its density; in practice, however, approximations to the universal density functional are required. In this work, a model based on deep…

Computational Physics · Physics 2016-08-02 Jeffrey M. McMahon

We introduce a machine-learning density-functional-theory formalism for the spinless Hubbard model in one dimension at both zero and finite temperature. In the zero-temperature case this establishes a one-to-one relation between the site…

Strongly Correlated Electrons · Physics 2021-06-16 James Nelson , Rajarshi Tiwari , Stefano Sanvito

We propose a density functional to find the ground state energy and density of interacting particles, where both the density and the pair density can adjust in the presence of an inhomogeneous potential. As a proof of principle we formulate…

Strongly Correlated Electrons · Physics 2015-06-11 J. Lorenzana , Z. -J. Ying , V. Brosco

This review explains the relationship between density functional theory and strongly correlated models using the simplest possible example, the two-site Hubbard model. The relationship to traditional quantum chemistry is included. Even in…

Strongly Correlated Electrons · Physics 2015-09-30 Diego Carrascal , Jaime Ferrer , Justin C. Smith , Kieron Burke

We revisit the machine-learning (ML) approach to the universal density functional $F[\mathbf{n}]$ of the one-dimensional Hubbard model with a site-dependent random potential $\mathbf{v}=\{v_{i}\}$. We generate exact ground-state data via…

Disordered Systems and Neural Networks · Physics 2026-03-03 Octavio D. R. Salmon , Minos A. Neto , J. Roberto Viana , Griffith Mendonça

The Hubbard model provides a test bed to investigate the complex behaviour arising from electron-electron interaction in strongly-correlated systems and naturally emerges as the foundation model for lattice density functional theory (DFT).…

Strongly Correlated Electrons · Physics 2025-01-29 Eoghan Cronin , Rajarshi Tiwari , Stefano Sanvito

Density functional theory underlies the most successful and widely used numerical methods for electronic structure prediction of solids. However, it has the fundamental shortcoming that the universal density functional is unknown. In…

Disordered Systems and Neural Networks · Physics 2020-09-23 M. Michael Denner , Mark H. Fischer , Titus Neupert

One of the great challenges of electronic structure theory is the quest for the exact functional of density functional theory. Its existence is proven, but it is a complicated multivariable functional that is almost impossible to…

Chemical Physics · Physics 2016-05-04 Aron J. Cohen , Paula Mori-Sánchez

We describe how density-functional theory, well-known for its many uses in ab initio calculations of electronic structure, can be used to study the ground state of inhomogeneous model Hamiltonians. The basic ideas and concepts are discussed…

Materials Science · Physics 2007-05-23 Valter L. Libero , Klaus Capelle

A striking consequence of the Hohenberg-Kohn theorem of density functional theory is the existence of a bijection between the local density and the ground-state many-body wave function. Here we study the problem of constructing…

Disordered Systems and Neural Networks · Physics 2020-08-17 Javier Robledo Moreno , Giuseppe Carleo , Antoine Georges

Machine learning methods for solving the equations of dynamical mean-field theory are developed. The method is demonstrated on the three dimensional Hubbard model. The key technical issues are defining a mapping of an input function to an…

Strongly Correlated Electrons · Physics 2015-07-01 Louis-François Arsenault , O. Anatole von Lilienfeld , Andrew J. Millis

Machine learning is a powerful tool to design accurate, highly non-local, exchange-correlation functionals for density functional theory. So far, most of those machine learned functionals are trained for systems with an integer number of…

We present a deep neural network (DNN)-based model (HubbardNet) to variationally find the ground state and excited state wavefunctions of the one-dimensional and two-dimensional Bose-Hubbard model. Using this model for a square lattice with…

Strongly Correlated Electrons · Physics 2023-09-04 Ziyan Zhu , Marios Mattheakis , Weiwei Pan , Efthimios Kaxiras

In the present work, we employ exact diagonalization for model systems on a real-space lattice to explicitly construct the exact density-to-potential and for the first time the exact density-to-wavefunction map that underly the…

Chemical Physics · Physics 2016-08-24 Tanja Dimitrov , Heiko Appel , Johanna I. Fuks , Angel Rubio

The principles of density-functional theory are studied for finite lattice systems represented by graphs. Surprisingly, the fundamental Hohenberg-Kohn theorem is found void in general, while many insights into the topological structure of…

Quantum Physics · Physics 2022-01-13 Markus Penz , Robert van Leeuwen

A density functional theory for many-body lattice models is considered in which the single-particle density matrix is the basic variable. Eigenvalue equations are derived for solving Levy's constrained search of the interaction energy…

Strongly Correlated Electrons · Physics 2009-10-31 R. Lopez-Sandoval , G. M. Pastor

Given a vector space of microscopic quantum observables, density functional theory is formulated on its dual space. A generalized Hohenberg-Kohn theorem and the existence of the universal energy functional in the dual space are proven. In…

Nuclear Theory · Physics 2009-09-25 G. Rosensteel , Ts. Dankova

An interacting lattice model describing the subspace spanned by a set of strongly-correlated bands is rigorously coupled to density functional theory to enable ab initio calculations of geometric and topological material properties. The…

Strongly Correlated Electrons · Physics 2019-03-26 Ryan Requist , E. K. U. Gross

Accurate description of deformed atomic nuclei by the orbital-free density functional theory has been a longstanding textbook challenge, due to the difficulty in accounting for the intricate quantum shell effects that are present in such…

Nuclear Theory · Physics 2024-12-31 X. H. Wu , Z. X. Ren , P. W. Zhao

Learning from data has led to a paradigm shift in computational materials science. In particular, it has been shown that neural networks can learn the potential energy surface and interatomic forces through examples, thus bypassing the…

Strongly Correlated Electrons · Physics 2019-02-18 Jianhua Ma , Puhan Zhang , Yaohua Tan , Avik W. Ghosh , Gia-Wei Chern
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