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Related papers: On the Equivalence of von Neumann and Thermodynami…

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Conventional wisdom holds that the von Neumann entropy corresponds to thermodynamic entropy, but Hemmo and Shenker (2006) have recently argued against this view by attacking von Neumann (1955) and his argument. I argue that Hemmo and…

History and Philosophy of Physics · Physics 2023-03-28 Eugene Y. S. Chua

Recently, attention has returned to the now-famous 1932 thought experiment in which John von Neumann establishes the form of the quantum mechanical von Neumann entropy -Tr $ \rho \ln \rho $ ($S_{VN}$), supposedly by arguing for its…

History and Philosophy of Physics · Physics 2020-07-15 Erin Sheridan

Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…

Quantum Physics · Physics 2025-10-08 Smitarani Mishra , Shaon Sahoo

This paper is an introduction to the von Neumann entropy in a historic approach. Von Neumann's gedanken experiment is repeated, which led him to the formula of thermodynamic entropy of a statistical operator. In the analysis of his ideas we…

Mathematical Physics · Physics 2007-05-23 D. Petz

Let $S(\rho)=- Tr (\rho \log\rho)$ be the von Neumann entropy of an $N$-dimensional quantum state $\rho$ and $e_2(\rho)$ the second elementary symmetric polynomial of the eigenvalues of $\rho$. We prove the inequality $S(\rho) \le c(N)…

Quantum Physics · Physics 2009-05-22 Meik Hellmund , Armin Uhlmann

Entropy concept was introduced by Clausius 160 years ago, and has been continually enriched, developed and interpreted by the researchers in many different scientific disciplines ever since. Thermodynamics and other scientific disciplines…

Chemical Physics · Physics 2017-11-21 Marko Popovic

We compare the thermodynamic entropy of a quantum Brownian oscillator derived from the partition function of the subsystem with the von Neumann entropy of its reduced density matrix. At low temperatures we find deviations between these two…

Quantum Physics · Physics 2009-11-13 Christian Hoerhammer , Helmut Buettner

We take the view that the standard von Neumann definition, in which the entropy $S^{vN}$ of a pure state is zero, is in evident conflict with the statement of the second law that the entropy of the universe $S_{univ}$ increases in…

Quantum Physics · Physics 2018-10-25 George L. Barnes , Phillip C. Lotshaw , Michael E. Kellman

When the difference between changes in energy and entropy at a given temperature is correlated with the ratio between the same changes in energy and entropy at zero average free energy of an ensemble of similar but distinct molecule-sized…

General Physics · Physics 2009-06-17 Petr Zimak , Silvia Terenzi , Peter Strazewski

K. He, J. Hou, and M. Li have recently given a sufficient and necessary condition for unitary equivalence of quantum states. This condition is based on the von Neumann entropy. In this note we first give a short proof of their result, and…

Quantum Algebra · Mathematics 2013-12-10 Roman Drnovšek

It is sometimes argued that the unattainability of zero temperature is a consequence of the second law of thermodynamics. Historically, the independence of the unattainability of zero temperature from the second law was proven more than 80…

Statistical Mechanics · Physics 2018-04-06 Koun Shirai

Thermodynamic entropy, as defined by Clausius, characterizes macroscopic observations of a system based on phenomenological quantities such as temperature and heat. In contrast, information-theoretic entropy, introduced by Shannon, is a…

Quantum Physics · Physics 2017-01-04 Mirjam Weilenmann , Lea Krämer , Philippe Faist , Renato Renner

This thesis investigates the connection between quantum theory, thermodynamics and information theory. Theories with structure similar to that of quantum theory are considered, mathematically described by the framework of "Generalized…

Quantum Physics · Physics 2015-08-14 Marius Krumm

Bianchi and Don\`{a} [1] have recently reported a proof to the variance formula of von Neumann entropy, which was conjectured in [2] and firstly proved in [3]. The purpose of this short note is to show that, despite having a different…

Information Theory · Computer Science 2019-06-26 Lu Wei

We derive an inequality relating the entropy difference between two quantum states to their trace norm distance, sharpening a well-known inequality due to M. Fannes. In our inequality, equality can be attained for every prescribed value of…

Quantum Physics · Physics 2009-11-13 Koenraad M. R. Audenaert

Similarity between quantum mechanics and thermodynamics is discussed. It is found that if the Clausius equality is imposed on the Shannon entropy and the analogue of the heat quantity, then the value of the Shannon entropy comes to formally…

Statistical Mechanics · Physics 2015-05-20 Sumiyoshi Abe , Shinji Okuyama

We consider three von Neumann entropy inequalities: subadditivity; Pinsker's inequality for relative entropy; and the monotonicity of relative entropy. For these we state conditions for equality, and we prove some new error bounds away from…

Quantum Physics · Physics 2014-10-21 Eric A. Carlen , Elliott H. Lieb

An alternative method is presented for extracting the von Neumann entropy $-\operatorname{Tr} (\rho \ln \rho)$ from $\operatorname{Tr} (\rho^n)$ for integer $n$ in a quantum system with density matrix $\rho$. Instead of relying on direct…

High Energy Physics - Theory · Physics 2021-02-03 Eric D'Hoker , Xi Dong , Chih-Hung Wu

The microscopic explanation of entropy has been challenged from both experimental and theoretical point of view. The expression of entropy is derived from the first law of thermodynamics indicating that entropy or the second law of…

General Physics · Physics 2007-05-23 Jozsef Garai

The example provided in the comment [arXiv:0803.2241] concerns a situation where the system is initially at negative temperature. It is known that in such cases the Law of Entropy Decrease holds. Nevertheless, this does not challenge the…

Quantum Physics · Physics 2008-04-09 Michele Campisi
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