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$^{75}$As NMR measurements were performed on a polycrystalline sample of spin-1/2 alternating-spin-chain Heisenberg antiferromagnet AgVOAsO$_4$. Temperature-dependent NMR shift $K(T)$, which is a direct measure of the intrinsic spin…

Materials Science · Physics 2017-12-27 N. Ahmed , P. Khuntia , H. Rosner , M. Baenitz , A. A. Tsirlin , R. Nath

We present the synthesis and a detailed investigation of structural and magnetic properties of polycrystalline NH$_4$[(V$_2$O$_3$)$_2$(4,4$^\prime$-$bpy$)$_2$(H$_2$PO$_4$)(PO$_4$)$_2$]$\cdot$0.5H$_2$O by means of x-ray diffraction, magnetic…

Materials Science · Physics 2017-05-24 U. Arjun , V. Kumar , P. K. Anjana , A. Thirumurugan , J. Sichelschmidt , A. V. Mahajan , R. Nath

We report on the crystal structure and magnetic behavior of the spin-1/2 compound AgVOAsO4. Magnetic susceptibility, high-field magnetization, and electron spin resonance measurements identify AgVOAsO4 as a gapped quantum magnet with a spin…

Structural and magnetic properties of a quasi-one-dimensional spin-$1/2$ compound NaVOPO$_4$ are explored by x-ray diffraction, magnetic susceptibility, high-field magnetization, specific heat, electron spin resonance, and $^{31}$P nuclear…

Strongly Correlated Electrons · Physics 2019-10-30 Prashanta K. Mukharjee , K. M. Ranjith , B. Koo , J. Sichelschmidt , M. Baenitz , Y. Skourski , Y. Inagaki , Y. Furukawa , A. A. Tsirlin , R. Nath

Thermodynamic properties, $^{31}$P nuclear magnetic resonance (NMR) measurements, and density-functional band-structure calculations for $\varepsilon$-LiVOPO$_4$ are reported. This quantum magnet features a singlet ground state and…

Strongly Correlated Electrons · Physics 2020-06-03 Prashanta K. Mukharjee , K. M. Ranjith , M. Baenitz , Y. Skourski , A. A. Tsirlin , R. Nath

Local-susceptibility measurements via the NMR shifts of $^{31}$P and $^{51}$V nuclei in the high-pressure phase of (VO)$_{2}$P$_{2}$O$_{7}$ confirmed the existence of a unique alternating antiferromagnetic chain with a zero-field spin gap…

Strongly Correlated Electrons · Physics 2007-05-23 J. Kikuchi , K. Motoya , T. Saito , M. Azuma , M. Takano

Employing first-principles modelling and many-body methods, the magnetic properties of spin-1/2 chain compound NaVOPO$_4$ are explored. The extensive first-principles calculations establish an intricate three-dimensionally coupled model…

Strongly Correlated Electrons · Physics 2024-08-30 Manoj Gupta , Manodip Routh , Manoranjan Kumar , Tanusri Saha Dasgupta

Nuclear magnetic resonance (NMR) of 31P and 51V nuclei has been measured in a spin-1/2 alternating-chain compound (VO)_2P_2O_7. By analyzing the temperature variation of the 31P NMR spectra, we have found that (VO)_2P_2O_7 has two…

Strongly Correlated Electrons · Physics 2009-10-31 Jun Kikuchi , Kiyoichiro Motoya , Touru Yamauchi , Yutaka Ueda

We report a single-crystal study on the magnetism of the rare-earth compound PrTiNbO$_6$ that experimentally realizes the zigzag pseudospin-$\frac{1}{2}$ quantum antiferromagnetic chain model. Random crystal electric field caused by the…

Strongly Correlated Electrons · Physics 2018-06-05 Yuesheng Li , Sebastian Bachus , Yoshifumi Tokiwa , Alexander A. Tsirlin , Philipp Gegenwart

We report the structural and magnetic properties of a new spin-$\frac12$ antiferromagnet NaZnVOPO$_4$(HPO$_4$) studied via x-ray diffraction, magnetic susceptibility, high-field magnetization, specific heat, and $^{31}$P nuclear magnetic…

Materials Science · Physics 2022-08-17 S. Guchhait , D. V. Ambika , Qing-Ping Ding , M. Uhlarz , Y. Furukawa , A. A. Tsirlin , R. Nath

We report a 51V nuclear magnetic resonance investigation of the frustrated spin-1/2 chain compound LiCuVO4, performed in pulsed magnetic fields and focused on high-field phases up to 55 T. For the crystal orientations H // c and H // b we…

We have investigated the low-temperature magnetism of sodium superoxide (NaO$_{2}$), in which spin, orbital, and lattice degrees of freedom are closely entangled. The magnetic susceptibility shows anomalies at $T_{1}=220$ K and $T_{2}=190$…

We report spin wave and DMRG studies of the ground and low-lying excited states of uniform and dimerized alternating spin chains. The DMRG procedure is also employed to obtain low-temperature thermodynamic properties of the system. The…

Condensed Matter · Physics 2016-08-31 Swapan K. Pati , S. Ramasesha , Diptiman Sen

We report $^{23}$Na-NMR study on a candidate one-dimensional quantum spin system NaO$_2$. The Knight shift, linewidth, and spin-lattice relaxation rate $1/T_1$ were investigated down to 0.3 K under fields up to 16 T. The results reveal the…

Strongly Correlated Electrons · Physics 2025-10-17 Takayuki Goto , Mizuki Miyajima , Takashi Kambe

CuMoO4 is a triclinic quantum magnet based on S = 1/2 moments at the Cu2+ site. It has recently attracted interest due to the remarkable changes in its chromic and volumetric properties at high temperatures, and in its magnetic properties…

Strongly Correlated Electrons · Physics 2015-05-28 S. Haravifard , K. Fritsch , T. Asano , J. P. Clancy , Z. Yamani , G. Ehlers , T. Nishimura , Y. Inagaki , T. Kawae , I. Swainson , B. D. Gaulin

Magnetic susceptibility and specific heat versus temperature measurements on polycrystalline samples of Sr3Cr2O8 and the isostructural, nonmagnetic compound Sr3V2O8 are reported. A Curie-Wiess fit to the high-temperature susceptibility data…

Strongly Correlated Electrons · Physics 2010-11-17 Yogesh Singh , D. C. Johnston

We report the local (NMR) and bulk (magnetization and heat capacity) properties of the vanadium-based S=1/2 uniform spin chain compound Bi6V3O16(Bi4V2O10.66). In the low-temperature {\alpha} phase, the magnetic ions (V4+) are arranged in…

Strongly Correlated Electrons · Physics 2019-09-19 T. Chakrabarty , I. Heinmaa , V. Yu. Verchenko , P. L. Paulose , R. Stern

We have performed $^{75}$As nuclear magnetic resonance (NMR) Knight shift measurements on single crystals of NaFe$_{0.975}$Co$_{0.025}$As to show that its superconductivity is a spin-paired, singlet state consistent with predictions of the…

Superconductivity · Physics 2013-05-23 Sangwon Oh , A. M. Mounce , J. S. Lee , W. P. Halperin , C. L. Zhang , S. Carr , Pengcheng Dai

We report a comprehensive investigation of the quadruple perovskite Ba$_4$NaRu$_3$O$_{12}$, in which we discover a robust spin-lattice coupled ground state characterized by a long-range antiferromagnetic ordering at $T_N \sim$ 257 K. The…

Strongly Correlated Electrons · Physics 2025-04-17 Shruti Chakravarty , Pascal Manuel , Antonio Cervellino , Sunil Nair

We report our nuclear magnetic resonance (NMR) study on the structurally spin chain compound Ni$_2$NbBO$_6$ with complex magnetic coupling. The antiferromagnetic transition is monitored by the line splitting resulting from the staggered…

Strongly Correlated Electrons · Physics 2021-07-16 K. Y. Zeng , Long Ma , L. M. Xu , Z. M. Tian , L. S. Ling , Li Pi
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