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N-type Bi100-xSbx alloys have the highest thermoelectric figure of merit (zT) of all materials below 200K; here we investigate how filling multiple valence band pockets at T and H-points of the Brillouin zone produces high zT in p-type…

Materials Science · Physics 2013-08-13 Hyungyu Jin , Christopher M. Jaworski , Joseph P. Heremans

The electronic and transport properties of (10, 0) single-walled carbon nanotube are studied by performing the first-principles calculations and semi-classical Boltzmann theory. It is found that the (10, 0) tube exhibits considerably large…

Mesoscale and Nanoscale Physics · Physics 2016-01-06 P. H. Jiang , H. J. Liu , D. D. Fan , L. Cheng , J. Wei , J. Zhang , J. H. Liang , J. Shi

Whereas thermoelectric performance is normally limited by the figure of merit ZT, transverse thermoelectrics can achieve arbitrarily large temperature differences in a single leg even with inferior ZT by being geometrically tapered. We…

Materials Science · Physics 2015-06-15 Chuanle Zhou , S. Birner , Yang Tang , K. Heinselman , M. Grayson

An experimental setup for determining the electrical resistivity of several types of thermoelectric materials over the temperature range 20 < T < 550 C is described in detail. One resistivity measurement during temperature cycling is also…

Materials Science · Physics 2012-12-05 K. C. Lukas , W. S. Liu , Q. Jie , Z. F. Ren , C. P. Opeil

In this work, we try to understand the experimental thermoelectric (TE) properties of a ZrNiSn sample with DFT and semiclassical transport calculations using SCAN functional. SCAN and mBJ provide the same band gap $E_{g}$ of $\sim$0.54 eV.…

Strongly Correlated Electrons · Physics 2020-06-24 Shivprasad S. Shastri , Sudhir K. Pandey

We explore a material design strategy to optimize the thermoelectric power factor. The approach is based on screening the band structure changes upon a controlled volume change. The methodology is applied to the binary silicides and…

Materials Science · Physics 2015-09-30 Sandip Bhattacharya , Georg K. H. Madsen

This paper demonstrates the significant benefits of exploiting highly aligned porosity in piezoelectric and pyroelectric materials for improved energy harvesting performance. Porous lead zirconate (PZT) ceramics with aligned pore channels…

Applied Physics · Physics 2019-02-04 Yan Zhang , Mengying Xie , James Roscow , Yinxiang Bao , Kechao Zhou , Dou Zhang , Chris R. Bowen

The thermoelectric figures of merit of pristine two-dimensional materials are predicted to be significantly less than unity, making them uncompetitive as thermoelectric materials. Here we elucidate a new strategy that overcomes this…

Mesoscale and Nanoscale Physics · Physics 2016-11-07 Hatef Sadeghi , Sara Sangtarash , Colin J. Lambert

Adding thermal conductivity enhancements to increase thermal power in solid-liquid phase-change thermal energy storage modules compromises volumetric energy density and often times reduces the mass and volume of active phase change material…

Materials Science · Physics 2020-11-26 Darin J. Sharar , Asher C. Leff , Adam A. Wilson , Andrew Smith

We present a model for P-N-P abrupt heterostructures vertical to temperature gradient to improve the thermoelectric performance. The P-N-P heterostructure is considered as an abrupt bipolar junction transistor due to an externally applied…

Materials Science · Physics 2020-09-24 Bohang Nan , Guiying Xu , Quanxin Yang , Tao Guo

Identification of novel materials with enhanced thermoelectric (TE) performance is critical for advancing TE research. In this direction, this is the first report on TE properties of low-cost, nontoxic, and abundant core-shell Cu@Cu2O…

Mesoscale and Nanoscale Physics · Physics 2020-12-02 Vikash Sharma , Gunadhor Singh Okram , Divya Verma , Niranjan Prasad Lalla , Yung-Kang Kuo

By using the semi-wet synthesis method, lead-free ferroelectric materials Ba0.9Sr0.1Ti1-xSnxO3 with x = 0, 0.02, 0.05, and 0.10 (abbreviated as BSTS) were prepared and their structural, electric and electrocaloric properties were…

Polycrystalline lead-free Ba$_{0.85}$Ca$_{0.15}$Zr$_{0.10}$Ti$_{0.90}$O$_3$ (BCZT), BaTi$_{0.89}$Sn$_{0.11}$O$_3$ (BTSn) and 0.4Ba$_{0.85}$Ca$_{0.15}$Zr$_{0.10}$Ti$_{0.90}$O$_3$-0.6BaTi$_{0.89}$Sn$_{0.11}$O$_3$ (0.4BCZT-0.6BTSn)…

Materials Science · Physics 2023-06-13 S. Khardazi , H. Zaitouni , A. Neqali , S. Lyubchyk , D. Mezzane , M. Amjoud , E. Choukri , S. Lyubchyk , Z. Kutnjak

We report the thermoelectric (TE) properties of (1-x)LaCoO3.xLa0.7Sr0.3MnO3 (0 < x < 0.10) composite in a temperature range 320-800 K. Addition of La0.7Sr0.3MnO3 to LaCoO3 in small amount (5 weight %) improves the overall Seebeck…

Materials Science · Physics 2023-04-11 Ashutosh Kumar , Karuna Kumari , B. Jayachandran , D. Sivaprahasam , Ajay D Thakur

Low dimensional materials provide the possibility of improved thermoelectric performance due to the additional length scale degree of freedom for engineering their electronic and thermal properties. As a result of suppressed phonon…

Mesoscale and Nanoscale Physics · Physics 2010-06-23 Neophytos Neophytou , Martin Wagner , Hans Kosina , Siegfried Selberherr

Half-Heusler compounds have emerged as promising thermoelectric materials that offer huge compositional space to tune their thermoelectric performance. A class of stable half Heusler compounds formed from elements of three specific groups…

Materials Science · Physics 2020-11-17 Parul R. Raghuvanshi , Suman Mondal , Amrita Bhattacharya

Using first-principles density-functional theory calculations, we predict the potential for unprecedented thermoelectric efficiency $zT=5$ at 800 K in $n$-type Ba$_{2}$BiAu full-Heusler compound. Such a high efficiency arises from an…

Materials Science · Physics 2019-02-06 Junsoo Park , Yi Xia , Vidvuds Ozoliņš

Samples of heavy fermion compound CeCu6 were prepared by hot-press technique. Temperature-dependent (5-300 K) thermoelectric transport properties of the samples were measured. The dimensionless figure-of-merit (ZT) was optimized by varying…

Materials Science · Physics 2013-12-16 Mani Pokharel , Tulashi Dahal , Zhifeng Ren , Cyril Opeil

Recent reported very high thermal conductivities in the cubic boron arsenide (BAs) and boron phosphide (BP) crystals could potentially provide a revolutionary solution in the thermal management of high power density devices. To fully…

A high Seebeck coefficient (S), large electrical conductivity ({\sigma}), and reduced thermal conductivity ({\kappa}) are required to achieve a high figure-of-merit (zT) in an ideal thermoelectric (TE) system, which is challenging in a…

Materials Science · Physics 2023-03-09 Ashutosh Kumar , D. Sivaprahasam , Ajay D. Thakur