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Partial pair-correlation functions of colloidal suspensions with continuous polydispersity can be challenging to characterize from optical microscopy or computer simulation data due to inadequate sampling. As a result, it is common to adopt…

Soft Condensed Matter · Physics 2011-10-12 Mark J. Pond , Jeffrey R. Errington , Thomas M. Truskett

The mechanical properties of aggregated colloids depend on the mutual interplay of inter-particle potentials, contact forces, aggregate structure and material properties of the bare particles. Owing to this variety of influences…

Soft Condensed Matter · Physics 2012-05-15 Marcel Roth , Carsten Schilde , Philipp Lellig , Arno Kwade , Günter K. Auernhammer

We critically discuss the application of the Wertheim's theory to classes of complex associating fluids that can be today engineered in the laboratory as patchy colloids and to the prediction of their peculiar gas-liquid phase diagrams. Our…

Soft Condensed Matter · Physics 2016-01-06 Riccardo Fantoni , Giorgio Pastore

We investigate the self-assembly of amphiphilic nanocubes under rest and shear using molecular dynamics (MD) simulations and kinetic Monte Carlo (KMC) calculations. These particles combine both interaction and shape anisotropy, making them…

Soft Condensed Matter · Physics 2023-05-24 Takahiro Yokoyama , Yusei Kobayashi , Noriyoshi Arai , Arash Nikoubashman

We report on the self-assembly of inverse patchy colloids (IPC) using Monte Carlo simulations in two-dimensions. The IPC model considered in this work corresponds to either bipolar colloids or colloids decorated with complementary DNA on…

Soft Condensed Matter · Physics 2017-05-16 Remya Ann Mathews K , Ethayaraja Mani

Self-assembly is traditionally described as the process through which an initially disordered system relaxes towards an equilibrium ordered phase only driven by local interactions between its building blocks. However, This definition is too…

Soft Condensed Matter · Physics 2015-06-15 Lorenzo Di Michele , Francesco Varrato , Jurij Kotar , Simon H. Nathan , Giuseppe Foffi , Erika Eiser

I present a review of the theoretical and computational methodologies that have been used to model the assembly of viral capsids. I discuss the capabilities and limitations of approaches ranging from equilibrium continuum theories to…

Biomolecules · Quantitative Biology 2013-01-09 Michael F. Hagan

A new theory is developed to describe the equilibrium adsorption and self-assembly of patchy colloids in microchannels. The adsorption theory is developed in classical density functional theory, with the adsorbed phase and fluid phase…

Soft Condensed Matter · Physics 2016-08-24 Bennett D. Marshall

Dynamical polydispersity in single-particle properties, for example a fluctuating particle size, shape, charge density, etc., is intrinsic to responsive colloids (RCs), such as biomacromolecules or microgels, but is typically not resolved…

Soft Condensed Matter · Physics 2021-05-26 Upayan Baul , Joachim Dzubiella

We develop coarse-grained models that describe the dynamic encapsidation of functionalized nanoparticles by viral capsid proteins. We find that some forms of cooperative interactions between protein subunits and nanoparticles can…

Biomolecules · Quantitative Biology 2009-11-13 Michael F. Hagan

In recent experiments involving PNIPAM copolymers it has been observed that stable spherical nanoparticles are being formed by association of several chains in poor aqueous solution instead of aggregation. This type of mesoscopic structures…

Soft Condensed Matter · Physics 2007-05-23 E. G. Timoshenko , R. Basovsky , Yu. A. Kuznetsov

In recent years, experimental and theoretical investigations have shown that anisotropic colloids can self-organise into ordered porous monolayers, where the interplay of localised bonding sites, so called patches, with the particle's shape…

Soft Condensed Matter · Physics 2024-05-03 Carina Karner , Emanuela Bianchi

The eye lens is the most characteristic example of mammalian tissues exhibiting complex colloidal behaviour. In this paper we briefly describe how dynamics in colloidal suspensions can help addressing selected aspects of lens cataract which…

Soft Condensed Matter · Physics 2015-05-13 Spyros N. Yannopoulos , Vassiliki Petta

Particles with directional interactions are promising building blocks for new functional materials and may serve as models for biological structures. Mutually attractive nanoparticles that are deformable due to flexible surface groups, for…

Soft Condensed Matter · Physics 2016-07-19 Chris H. J. Evers , Jurriaan A. Luiken , Peter G. Bolhuis , Willem K. Kegel

A coarse-grained computational model is used to investigate the effect of a fluid membrane on patchy-particle assembly into biologically-relevant structures motivated by viral cores and clathrin. For cores, we demonstrate a non-monotonic…

Soft Condensed Matter · Physics 2012-11-09 Richard Matthews , Christos N. Likos

The self-assembly of monoacyl lipids in solution is studied employing a model in which the lipid's hydrocarbon tail is described within the Rotational Isomeric State framework and is attached to a simple hydrophilic head. Mean-field theory…

Statistical Mechanics · Physics 2009-10-31 M. Mueller , M. Schick

Responsive particles, such as biomacromolecules or hydrogels, display a broad and polymodal distribution of conformations and have thus the ability to change their properties (e.g, size, shape, charge density, etc.) substantially in…

Soft Condensed Matter · Physics 2020-10-28 Yi-Chen Lin , Benjamin Rotenberg , Joachim Dzubiella

Inverse Patchy Colloids (IPCs) differ from conventional patchy particles because their patches repel (rather than attract) each other and attract (rather than repel) the part of the colloidal surface that is free of patches. These…

Soft Condensed Matter · Physics 2014-12-12 Silvano Ferrari , Emanuela Bianchi , Yura V. Kalyuzhnyi , Gerhard Kahl

A mixture of solvent particles with short-range, directional interactions and solute particles with short-range, isotropic interactions that can bond multiple times is of fundamental interest in understanding liquids and colloidal mixtures.…

Soft Condensed Matter · Physics 2016-09-21 Artee Bansal , D. Asthagiri , Kenneth R. Cox , Walter G. Chapman

The rapid progress in precisely designing the surface decoration of patchy colloidal particles offers a new, yet unexperienced freedom to create building entities for larger, more complex structures in soft matter systems. However, it is…

Soft Condensed Matter · Physics 2012-06-14 G. Doppelbauer , E. G. Noya , E. Bianchi , G. Kahl