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Crystallization represents a fundamental process engendering solidification of a material and determines its microstructure. Driven by complex phenomena at the atomic scale, its understanding for alloys still remains elusive. The present…

Materials Science · Physics 2022-10-06 Sébastien Becker , Emilie Devijver , Rémi Molinier , Noël Jakse

The nucleation of crystals in liquids is one of nature's most ubiquitous phenomena, playing an important role in areas such as climate change and the production of drugs. As the early stages of nucleation involve exceedingly small time and…

We present a computer simulation study on the crystal nucleation process in suspensions of hard spheres, fully taking into account the solvent hydrodynamics. If the dynamics of collodial crystallization were purely diffusive, the crystal…

Soft Condensed Matter · Physics 2015-06-12 Marc Radu , Tanja Schilling

The dynamics of homogeneous nucleation and growth of crystalline nickel from the super-cooled melt is examined during rapid quenching using molecular dynamics and a modified embedded atom method potential. The character of the critical…

Materials Science · Physics 2009-11-10 F. J. Cherne , M. I. Baskes , R. B. Schwarz , S. G. Srinivasan , W. Klein

We study the homogeneous nucleation process in Stillinger-Weber silicon in the NVT ensemble. A clear first-order transition from the liquid to crystal phase is observed thermodynamically with kinetic and structural evidence of the…

Materials Science · Physics 2009-11-10 Philippe Beaucage , Normand Mousseau

Constructing an accurate atomistic model for the high-pressure phases of tin (Sn) is challenging because properties of Sn are sensitive to pressures. We develop machine-learning-based deep potentials for Sn with pressures ranging from 0 to…

Materials Science · Physics 2023-05-12 Tao Chen , Fengbo Yuan , Jianchuan Liu , Huayun Geng , Linfeng Zhang , Han Wang , Mohan Chen

Laser-induced forward transfer (LIFT) printing is a versatile technique to realize micro/nano-scale additive manufacturing of functional materials, including metals and semiconductors. However, the crystallization phenomena during LIFT…

Materials Science · Physics 2026-02-03 Youwen Liang , Wan Shou

The interplay between crystal nucleation and the structure of the metastable fluid has been a topic of significant debate over recent years. In particular, it has been suggested that even in simple model systems such as hard or charged…

Soft Condensed Matter · Physics 2025-02-19 Marjolein de Jager , Frank Smallenburg , Laura Filion

Modulating liquid-to-solid transitions and the resulting crystalline structure for tailored properties is much desired. Colloidal systems are exemplary to this end, but the fundamental knowledge gaps in relating the influence of…

Statistical Mechanics · Physics 2025-11-04 Porhouy Minh , Steven W. Hall , Ryan S. DeFever , Sapna Sarupria

Homogeneous nucleation processes are important for understanding solidification and the resulting microstructure of materials. Simulating this process requires accurately describing the interactions between atoms, hich is further…

Materials Science · Physics 2024-10-11 Johannes Sandberg , Thomas Voigtmann , Emilie Devijver , Noel Jakse

The phenomenon of solidification of a substance from its liquid phase is of the greatest practical and theoretical importance, and atomistic simulations can provide precious information towards its understanding and control. Unfortunately,…

Soft Condensed Matter · Physics 2021-03-25 Tarak Karmakar , Michele Invernizzi , Valerio Rizzi , Michele Parrinello

Silicon exhibits several metastable allotropes which recently attracted attention in the quest for materials with superior (e.g. optical) properties, compatible with Si technology. In this work we shed light on the atomic-scale mechanisms…

Materials Science · Physics 2026-03-06 Fabrizio Rovaris , Anna Marzegalli , Francesco Montalenti , Emilio Scalise

Nucleation phenomena commonly observed in our every day life are of fundamental, technological and societal importance in many areas, but some of their most intimate mechanisms remain however to be unraveled. Crystal nucleation, the early…

Materials Science · Physics 2022-02-09 Sébastien Becker , Emilie Devijver , Rémi Molinier , Noël Jakse

The crystal nucleation from liquid in most cases is too rare to be accessed within the limited timescales of the conventional molecular dynamics (MD) simulation. Here, we developed a "persistent embryo" method to facilitate crystal…

Materials Science · Physics 2018-02-27 Yang Sun , Huajing Song , Feng Zhang , Lin Yang , Zhuo Ye , Mikhail I. Mendelev , Cai-Zhuang Wang , Kai-Ming Ho

Recently, it was shown that a theoretical description of nucleation based on fluctuating hydrodynamics and classical density functional theory can be used to determine non-classical nucleation pathways for crystallization (Lutsko, Sci. Adv.…

Chemical Physics · Physics 2024-06-26 James F. Lutsko , Cédric Schoonen

In this paper we have explored computationally the solidification process of large nickel clusters. This process has the characteristic features of the first order phase transition occurring in a finite system. The focus of our research is…

Computational Physics · Physics 2012-10-15 Alexander V. Yakubovich , Gennady Sushko , Stefan Schramm , Andrey V. Solov'yov

Crystallization is one of the most important phase transformations of first order. In the case of metals and alloys, the liquid phase is the parent phase of materials production. The conditions of the crystallization process control the…

Materials Science · Physics 2016-11-03 Diter M. Herlach , Thomas Palberg

We report on a large scale computer simulation study of crystal nucleation in hard spheres. Through a combined analysis of real and reciprocal space data, a picture of a two-step crystallization process is supported: First dense, amorphous…

Soft Condensed Matter · Physics 2015-05-18 T. Schilling , H. J. Schope , M. Oettel , G. Opletal , I. Snook

In this article, we present a systematic study in developing machine learning force fields (MLFF) for crystalline silicon. While the main-stream approach of fitting a MLFF is to use a small and localized training sets from molecular…

Computational Physics · Physics 2020-08-26 Howard Yanxon , David Zagaceta , Brandon C. Wood , Qiang Zhu

Crystallization, a prototypical self-organization process during which a disordered state spontaneously transforms into a crystal characterized by a regular arrangement of its building blocks, usually proceeds by nucleation and growth. In…

Computational Physics · Physics 2017-10-06 Swetlana Jungblut , Christoph Dellago