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The olivine compound Mn2GeO4 is shown to feature both a ferroelectric polarization and a ferromagnetic magnetization that are directly coupled and point along the same direction. We show that a spin spiral generates ferroelectricity (FE),…

Materials Science · Physics 2012-08-07 J. S. White , T. Honda , K. Kimura , T. Kimura , Ch. Niedermayer , O. Zaharko , A. Poole , B. Roessli , M. Kenzelmann

The interplay between covalency and magnetism is non-trivial and can be harnessed for designing new functional magnetic materials. Based on a survey using density functional calculations, we show that $TM\unicode{x2013}O$ bond covalency can…

Materials Science · Physics 2020-04-24 M. H. N. Assadi , H. Katayama-Yoshida

Neutron and X-ray diffraction, magnetic susceptibility, and specific heat measurements have been used to investigate the magnetic and structural phase transitions of the spinel system Fe1+xCr2-xO4(0.0<=x<=1.0). The temperature versus Fe…

We examine the evolution of magnetic properties in the normal spinel oxides Mg(1-x)Cu(x)Cr2O4 using magnetization and heat capacity measurements. The end-member compounds of the solid solution series have been studied in some detail because…

Materials Science · Physics 2012-09-11 Moureen C. Kemei , Stephanie L. Moffitt , Daniel P. Shoemaker , Ram Seshadri

Nowdays, multiferroic materials with magnetoelectric coupling have many real-world applications in the fields of novel memory devices. It is challenging is to create multiferroic materials with strongly coupled ferroelectric and…

Materials Science · Physics 2018-05-29 Deobrat Singh , Sanjeev K. Gupta , Haiying He , Yogesh Sonvane

The structural and magnetic properties of ZnFe2O4 nanoparticles embedded in a non-magnetic ZnO matrix are presented. X-ray diffractograms and Transmission Electron Microscopy (TEM) images showed that the resulting samples are composed of…

Materials Science · Physics 2012-12-13 G. F. Goya , E. R. Leite

Spin supersolids and spin superfluids reveal complex canted spin structures with independent order of longitudinal and transverse spin components. This work addresses the question whether these exotic phases can exhibit spin-driven…

Co$_3$O$_4$, ZnFe$_2$O$_4$, CoFe$_2$O$_4$, ZnCo$_2$O$_4$, and Fe$_3$O$_4$ thin films were fabricated by pulsed laser deposition at high and low temperatures resulting in crystalline single-phase normal, inverse, as well as disordered spinel…

Ultrasound velocity measurements were performed on a single crystal of spin-frustrated ferrite spinel ZnFe$_2$O$_4$ from 300 K down to 2 K. In this cubic crystal, all the symmetrically-independent elastic moduli exhibit softening with a…

Strongly Correlated Electrons · Physics 2015-11-26 Tadataka Watanabe , Shota Takita , Keisuke Tomiyasu , Kazuya Kamazawa

Spinel oxides demonstrate significant technological promise due to the vast array of interrelated physical properties that their unique structure supports. Specifically, the Fe1+xV2-xO4 spinel system garners extensive interest due to the…

The crystal and magnetic structures of stoichiometric ZnCr2Se4 have been investigated using synchrotron X-ray and neutron powder diffraction, muon spin relaxation (muSR) and inelastic neutron scattering. Synchrotron X-ray diffraction shows…

Strongly Correlated Electrons · Physics 2017-04-12 P. Zajdel , W-Y. Li , W. Van Beek , A. Lappas , A. Ziolkowska , S. Jaskiewicz , C. Stock , M. A. Green

Our measured dielectric constant and mechanical response of multiferroic BiFeO3 indicate four phase transitions below room temperature. Features correlate with those reported at 50K (from a peak in the zero-field-cooled magnetic…

Materials Science · Physics 2008-06-23 S. A. T. Redfern , C. Wang , J. W. Hong , G. Catalan , J. F. Scott

Cubic spinel GeNi2O4 exhibits intriguing magnetic properties with two successive antiferromagnetic phase transitions (TN1 12.1 and TN2 11.4 K) with the absence of any structural transition. We have performed detailed heat capacity and…

Strongly Correlated Electrons · Physics 2020-12-02 T. Basu , T. Zou , Z. Dun , C. Q. Xu , C. R. Dela Cruz , Tao Hong , H. B. Cao , K. M. Taddei , H. D. Zhou , X. Ke

The efficient coupling between lattice degrees of freedom and spin degrees of freedom in magnetic materials can be used for refrigeration and energy conversion. This coupling is enhanced in materials exhibiting the giant magnetocaloric…

Controlling multiferroic behavior in materials will enable the development of a wide variety of technological applications. However, the exact mechanisms driving multiferroic behavior are not well understood in most materials. Two such…

Materials Science · Physics 2018-06-27 B. Wolin , X. Wang , T. Naibert , S. L. Gleason , G. J. MacDougall , H. D. Zhou , S. L. Cooper , R. Budakian

Solid solutions of nominal composition [ZnGa$_2$O$_4$]$_{1-x}$[Fe$_3$O$_4$]$_x$, of the semiconducting spinel ZnGa$_2$O$_4$ with the ferrimagnetic spinel Fe$_3$O$_4$ have been prepared with $x$ = 0.05, 0.10, and 0.15. All samples show…

Materials Science · Physics 2007-05-23 A. S. Risbud , R. Seshadri , J. Ensling , C. Felser

We report a neutron diffraction study of the multiferroic mechanism in (ND4)2FeCl5D2O, a molecular compound that exhibits magnetically induced ferroelectricity. This material exhibits two successive magnetic transitions on cooling: a…

GeCo$_2$O$_4$ is a unique system in the family of cobalt spinels ACo$_2$O$_4$ (A= Sn, Ti, Ru, Mn, Al, Zn, Fe, etc.) in which magnetic Co ions stabilize on the pyrochlore lattice exhibiting a large degree of orbital frustration. Due to the…

The spinel FeV2O4 is known to exhibit peculiar physical properties, which is generally ascribed to the unusual presence of two cations showing a pronounced interplay between spin, orbital and lattice degrees of freedom (Fe2+ and V3+ on the…

Materials Science · Physics 2012-02-16 Q. Zhang , K. Singh , F. Guillou , C. Simon , Y. Breard , V. Caignaert , V. Hardy

We report magnetoresistance measurements on thin Pt bars grown on epitaxial (001) and (111) CoFe2O4 (CFO) ferrimagnetic insulating films. The results can be described in terms of the recently discovered spin Hall magnetoresistance (SMR).…