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Related papers: The origin of the vanadium dioxide transition entr…

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Nine of the known vanadium oxides, VO$_{2-1/n}$ (n - a positive or negative integer) with n=2 - 6, 8, 9, $\infty$ and -6, undergo metal-insulator transitions accompanied by structural transitions, at various temperatures T$_{MIT}$…

Strongly Correlated Electrons · Physics 2015-12-09 B. Fisher , J. Genossar , G. M. Reisner

The nature of the insulator-to-metal phase transition in vanadium dioxide (VO2) is one of the longest-standing problems in condensed-matter physics. Ultrafast spectroscopy has long promised to determine whether the transition is primarily…

Vanadium dioxide (VO$_{2}$) undergoes a first-order metal-insulator transition (MIT) upon cooling near room temperature, concomitant with structural change from rutile to monoclinic. Accurate characterization of lattice vibrations is vital…

Materials Science · Physics 2017-11-22 Yi Xia , Maria K. Y. Chan

We present a density functional perturbation theory approach to estimate the transition temperature of the charge density wave transition of TiSe2. The softening of the phonon mode at the L-point where in TiSe2 a giant Kohn anomaly occurs,…

Materials Science · Physics 2015-12-02 Dinh Loc Duong , Marko Burghard , J. Christian Schoen

New calculations for vanadium dioxide, one of the most controversely discussed materials for decades, reveal that band theory as based on density functional theory is well capable of correctly describing the electronic and magnetic…

Strongly Correlated Electrons · Physics 2011-07-07 V. Eyert

Vanadium dioxide (VO2) undergoes a phase transition at a temperature of 340 K between an insulating monoclinic M1 phase and a conducting rutile phase. Accurate measurements of possible anisotropy of the electronic properties and phonon…

Strongly Correlated Electrons · Physics 2013-07-24 T. J. Huffman , Peng Xu , M. M. Qazilbash , E. J. Walter , H. Krakauer , Jiang Wei , D. H. Cobden , H. A. Bechtel , M. C. Martin , G. L. Carr , D. N. Basov

Vanadium dioxide (VO2) has drawn significant attention for its near room temperature insulator to metal transition and associated structural phase transition. The underlying Physics behind the temperature induced insulator to metal and…

Materials Science · Physics 2023-04-19 S. R. Sahu , S. S. Majid , A. Ahad , A. Tripathy , K. Dey , S. Pal , B. K. De , Wen-Pin Hsieh , R. Rawat , V. G. Sathe , D. K. Shukla

Vanadium dioxide is a correlated electron system that features a metal-insulator phase transition (MIT) above room temperature and is of interest in high speed switching devices. Here, we integrate VO2 into two-terminal coplanar waveguides…

Materials Science · Physics 2013-06-04 Sieu D. Ha , You Zhou , Christopher J. Fisher , Shriram Ramanathan , Jacob P. Treadway

Nonequilibrium phase transitions driven by light pulses represent a rapidly developing field in condensed matter physics. As one of the archetypal strongly correlated materials, vanadium dioxide (VO2) undergoes a structural phase transition…

Strongly Correlated Electrons · Physics 2025-04-02 Lin Zhang , Utso Bhattacharya , Maria Recasens , Tobias Grass , Ravindra W. Chhajlany , Maciej Lewenstein , Allan S. Johnson

The vibrational entropy of a solid at finite temperature is investigated from the perspective of information theory. Ab initio molecular dynamics (AIMD) simulations generate ensembles of atomic configurations at finite temperature from…

Statistical Mechanics · Physics 2022-05-11 Yang Huang , Michael Widom

Vibrational entropy plays a central role in determining phase stability and temperature dependent behavior in materials, yet its calculation from first-principles phonon methods remains computationally demanding. In this work, we combine…

Materials Science · Physics 2026-04-28 Shivam Tripathi , Jatin Kawatra , Varun Malviya , Krishna Mehta

Vanadium dioxide(VO$_2$) is a paradigmatic example of a strongly correlated system that undergoes a metal-insulator transition at a structural phase transition. To date, this transition has necessitated significant post-hoc adjustments to…

Strongly Correlated Electrons · Physics 2017-12-20 Huihuo Zheng , Lucas K. Wagner

The insulator-to-metal transition (IMT) of the simple binary compound of vanadium dioxide VO$_2$ at $\sim 340$ K has been puzzling since its discovery more than five decades ago. A wide variety of photon and electron probes have been…

Strongly Correlated Electrons · Physics 2014-12-18 Brian T. O'Callahan , Joanna M. Atkin , Andrew C. Jones , Jae Hyung Park , David Cobden , Markus B. Raschke

The pressure-induced transition of vanadium from BCC to rhombohedral structures is unique and intriguing among transition metals. In this work, the stability of these phases is revisited by using density functional theory. At finite…

Materials Science · Physics 2016-11-07 Yi X. Wang , Q. Wu , Xiang R. Chen , Hua Y. Geng

We apply ultrafast spectroscopy to establish a time-domain hierarchy between structural and electronic effects in a strongly-correlated electron system. We discuss the case of the model system VO2, a prototypical non-magnetic compound that…

Strongly Correlated Electrons · Physics 2007-05-23 A. Cavalleri , Th. Dekorsy , H. H. Chong , J. C. Kieffer , R. W. Schoenlein

We studied the isotropic Compton profile of the prototypical oxide VO$_2$ across the temperature induced electronic and structural phase transition at T$_C$ $\approx$ 340 K. We show that the phase transition leaves an observable signal,…

Strongly Correlated Electrons · Physics 2018-10-17 Kari O. Ruotsalainen , Juho Inkinen , Tuomas Pylkkänen , Thomas Buslaps , Mikko Hakala , Keijo Hämäläinen , Simo Huotari

In the present study, we demonstrate a vacuum thermal switch based on near-field thermal radiation between phase transition materials, i.e., vanadium dioxide (VO2), whose phase changes from insulator to metal at 341 K. Similar modulation…

Mesoscale and Nanoscale Physics · Physics 2014-12-30 Yue Yang , Soumyadipta Basu , Liping Wang

The metal-insulator transition and unconventional metallic transport in vanadium dioxide (VO$_2$) are investigated with a combination of spectroscopic ellipsometry and reflectance measurements. The data indicates that electronic…

Strongly Correlated Electrons · Physics 2009-11-11 M. M. Qazilbash , K. S. Burch , D. Whisler , D. Shrekenhamer , B. G. Chae , H. T. Kim , D. N. Basov

Ultrafast photoexcitation is an emerging route to selective control of phase transitions. However, it is difficult to determine which modes govern the transformation and how effectively they are targeted by photoexcitation. This is…

Strongly Correlated Electrons · Physics 2026-03-06 Shreya Bagchi , Ernest Pastor , José Santiso , Allan S. Johnson , Simon E. Wall

Insulator-to-metal (MI) phase transition in vanadium dioxide (VO2) thin films with controlled lattice distortion was investigated by thermopower measurements. VO2 epitaxial films with different crystallographic orientations, grown on (0001)…

Strongly Correlated Electrons · Physics 2015-07-15 Takayoshi Katase , Kenji Endo , Hiromichi Ohta
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