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While coupled cluster theory accurately models weakly correlated quantum systems, it often fails in the presence of strong correlations where the standard mean-field picture is qualitatively incorrect. In many cases, these failures can be…

Nuclear Theory · Physics 2020-05-14 Y. Qiu , T. M. Henderson , T. Duguet , G. E. Scuseria

We present a coupled cluster and linear response theory to compute properties of many-electron systems at non-zero temperatures. For this purpose, we make use of the thermofield dynamics, which allows for a compact wavefunction…

Chemical Physics · Physics 2020-05-14 Gaurav Harsha , Thomas M. Henderson , Gustavo E. Scuseria

We present a rigorous framework that combines single-particle Green's function theory with density functional theory based on a separation of electron-electron interactions into short-range and long-range components. Short-range…

Chemical Physics · Physics 2018-06-07 Alexei A. Kananenka , Dominika Zgid

In order to assess the accuracy of commonly used approximate exchange-correlation density functionals, we present a comparison of accurate exchange and correlation potentials, exchange energy densities and energy components with the…

Condensed Matter · Physics 2007-05-23 Claudia Filippi , Xavier Gonze , C. J. Umrigar

Metrics have been used to investigate the relationship between wavefunction distances and density distances for families of specific systems. We extend this research to look at random potentials for time-dependent single electron systems,…

Quantum Physics · Physics 2018-09-12 A. H. Skelt , R. W. Godby , I. D'Amico

A simple theory for the leading-order correction g_1(r) to the structure of a hard-sphere liquid with discrete (e.g. square-well) potential perturbations is proposed. The theory makes use of a general approximation that effectively…

Statistical Mechanics · Physics 2007-12-10 Artur B. Adib

The relative energies of different phases or polymorphs of molecular solids can be small, less than a kiloJoule/mol. Reliable description of such energy differences requires high quality treatment of electron correlations, typically beyond…

Chemical Physics · Physics 2024-02-19 Khanh Ngoc Pham , Marcin Modrzejewski , Jiří Klimeš

Heavy baryon chiral perturbation theory is applied to one- and two nucleon processes.

Nuclear Theory · Physics 2015-05-18 F. Myhrer

A scheme within density functional theory is proposed that provides a practical way to generalize to unrestricted geometries the method applied with some success to layered geometries [H. Rydberg, et al., Phys. Rev. Lett. 91, 126402…

Materials Science · Physics 2009-11-10 M. Dion , H. Rydberg , E. Schroder , D. C. Langreth , B. I. Lundqvist

Based on the self-energy-functional approach proposed recently [M. Potthoff, Eur. Phys. J. B 32, 429 (2003)], we present an extension of the cluster-perturbation theory to systems with spontaneously broken symmetry. Our method applies to…

Strongly Correlated Electrons · Physics 2007-05-23 C. Dahnken , M. Aichhorn , W. Hanke , E. Arrigoni , M. Potthoff

The present work proposes to use density-functional theory (DFT) to correct for the basis-set error of wave-function theory (WFT). One of the key ideas developed here is to define a range-separation parameter which automatically adapts to a…

We present a perturbative treatment of the response properties of insulating crystals under a dc bias field, and use this to study the effects of such bias fields on the Born effective charge tensor and dielectric tensor of insulators. We…

Materials Science · Physics 2009-12-17 Xinjie Wang , David Vanderbilt

We present an approach based on density-functional theory for the calculation of fundamental gaps of both finite and periodic two-dimensional (2D) electronic systems. The computational cost of our approach is comparable to that of total…

Materials Science · Physics 2021-08-11 Alberto Guandalini , Alice Ruini , Esa Räsänen , Carlo Andrea Rozzi , Stefano Pittalis

Building on the discussion in PRA 93, 042510 (2016), we present a systematic derivation of gradient corrections to the kinetic-energy functional and the one-particle density, in particular for two-dimensional systems. We derive the leading…

Quantum Gases · Physics 2017-09-08 Martin-Isbjörn Trappe , Yink Loong Len , Hui Khoon Ng , Berthold-Georg Englert

This paper represents one contribution to a larger Roadmap article reviewing the current status of the FHI-aims code. In this contribution, the implementation of density-functional perturbation theory in a numerical atom-centered framework…

We have used density functional theory to study the nonlinear screening properties of a two-dimensional (2D) electron gas. In particular, we consider the screening of an external static point charge of magnitude Z as a function of the…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 E. Zaremba , I. Nagy , P. M. Echenique

Interactions between negatively charged aluminosilicate species and positively charged metal cations are critical to many important engineering processes and applications, including sustainable cements and aluminosilicate glasses. In an…

Materials Science · Physics 2023-01-18 Kai Gong , Kengran Yang , Claire E. White

Differential energy structure of a micro multi-charged-particle system and the beam internal potential energy is derived with consequent property and ecessary inference. Then by combining the energy differential structure with differential…

Accelerator Physics · Physics 2007-05-23 Ji Luo , Chuang Zhang

Using quantum Monte Carlo, exact diagonalization and perturbation theory, we study the spectrum of the $S=1/2$ antiferromagnetic Heisenberg trimer chain by varying the ratio $g=J_2/J_1$ of the intertrimer and intratrimer coupling strengths.…

Strongly Correlated Electrons · Physics 2022-01-13 Jun-Qing Cheng , Jun Li , Zijian Xiong , Han-Qing Wu , Anders W. Sandvik , Dao-Xin Yao

Ab initio density functional theory has been used to analyze flexural modes, elastic constants, and atomic corrugations on single and bi-layer graphene. Frequencies of flexural modes are sensitive to compressive stress; its variation under…

Materials Science · Physics 2013-01-22 P. L. de Andres , F. Guinea , M. I. Katsnelson