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Magnetic moment of the Fe2+ ion in FeO, FeS and FeBr2 has been calculated within the quantum atomistic solid-state theory to substantially exceed a value of 4 muB in the magnetically-ordered state at 0 K. In all compounds the large orbital…

Strongly Correlated Electrons · Physics 2007-05-23 R. J. Radwanski , Z. Ropka

First principles density functional calculations within the local spin density approximation (LSDA) and the generalized gradient approximation (GGA) are reported for pyrochlore Cd$_2$Os$_2$O$_7$ and Cd$_{2}$Re$_{2}$O$_7$. The transition…

Condensed Matter · Physics 2009-11-07 D. J. Singh , P. Blaha , K. Schwarz , J. O. Sofo

Re-based double perovskites (DPs) exhibit a complex interplay of structural and metal-insulator transitions. Here we systematically study the ground state electronic and structural properties for a family of Re-based DPs $A_2B$ReO$_6$…

Strongly Correlated Electrons · Physics 2018-01-10 Alex Taekyung Lee , Chris A. Marianetti

We investigate the electronic structure of BaIrO3, an interesting compound exhibiting charge density wave transition in its insulating phase and ferromagnetic transition at the same temperature, using full potential linearized augmented…

Strongly Correlated Electrons · Physics 2009-11-11 Kalobaran Maiti

The Local Density Approximation combined with Dynamical Mean-Field Theory (LDA+DMFT method) is applied to the study of the paramagnetic and magnetically ordered phases of hematite Fe$_2$O$_3$ as a function of volume. As the volume is…

Strongly Correlated Electrons · Physics 2009-04-07 J. Kunes , Dm. M. Korotin , M. A. Korotin , V. I. Anisimov , P. Werner

Spin correlations in metallic and insulating phases of $V_2O_3$ and its derivatives are investigated using magnetic neutron scattering. Metallic samples have incommensurate spin correlations varying little with hole doping. Paramagnetic…

Strongly Correlated Electrons · Physics 2009-10-28 Wei Bao , C. Broholm , G. Aeppli , P. Dai , J. M. Honig , P. Metcalf

The role of orbital differentiation on the emergence of superconductivity in the Fe-based superconductors remains an open question to the scientific community. In this investigation, we employ a suitable microscopic spin probe technique,…

Superconductivity · Physics 2014-02-11 P. F. S. Rosa , C. Adriano , T. M. Garitezi , T. Grant , Z. Fisk , R. R. Urbano , P. G. Pagliuso

Spin-state ordering - a periodic pattern of ions with different spin-state configurations along a crystal lattice - is a rare phenomenon, and its possible interrelation with other electronic degrees of freedom remains little explored. Here…

Strongly Correlated Electrons · Physics 2024-03-27 E. Granado , C. W. Galdino , B. D. Moreno , G. King , D. C. Freitas

KO2 exhibits concomitant antiferromagnetic (AFM) and structural transitions, both of which originate from the open-shell 2p electrons of O$_{2}^{-}$ molecules. The structural transition is accompanied by the coherent tilting of O$_{2}^{-}$…

Strongly Correlated Electrons · Physics 2010-03-24 Minjae Kim , Beom Hyun Kim , Hong Chul Choi , B. I. Min

The magnetic and electronic structures of Fe4O5 have been investigated at ambient and high pressures via a combination of representation analysis, density functional theory (DFT+U) calculations, and M\"ossbauer spectroscopy. A few spin…

Materials Science · Physics 2023-01-10 V. S. Zhandun , N. V. Kazak , I. Kupenko , D. M. Vasiukov , X. Li , E. Blackburn , S. G. Ovchinnikov

Spin fluctuations were studied over a wide momentum ($\hbar Q$) and energy ($E$) space in the frustrated $d$-electron heavy-fermion metal LiV$_2$O$_4$ by time-of-flight inelastic neutron scattering. We observed the overall $Q$$-$$E$…

Strongly Correlated Electrons · Physics 2015-03-10 K. Tomiyasu , K. Iwasa , H. Ueda , S. Niitaka , H. Takagi , S. Ohira-Kawamura , T. Kikuchi , K. Nakajima , K. Yamada

Using spin density functional theory we have carried out a comparative study of chemical bonding and magnetism in Fe_4N, Fe_3N and Fe_2N. All of these compounds form close packed Fe lattices, while N occupies octahedral interstitial…

Materials Science · Physics 2009-10-31 M. Sifkovits , H. Smolinski , S. Hellwig , W. Weber

Properties of iron oxides at the extreme conditions are of essential importance in condensed matter physics and Geophysics. The recent discovery of a new type of iron oxide, Fe4O5, at high pressure and high temperature of Earth's deep…

Strongly Correlated Electrons · Physics 2021-09-14 Aiqin Yang , Qiaoying Qin , Xiangru Tao , Shengli Zhang , Yongtao Zhao , Peng Zhang

Here, we investigated the interrelationship between pressure and correlation in the LaFeAsO compound by the density functional theory method combined with the dynamical mean field theory (DFT+DMFT) method. The spectral function and the…

Strongly Correlated Electrons · Physics 2018-10-01 Mehdi Hesani , Ahmad Yazdani

The effect of hydrostatic pressure on the electronic structures of iron pnictide superconducting compounds LiFeAs and NaFeAs through density functional theory based first principles studies are presented, using the predicted crystal…

Superconductivity · Physics 2021-08-18 Soumyadeep Ghosh , Haranath Ghosh

We have investigated electronic structures of antiferromagnetic YBaCo_2O_5 using the local spin-density approximation (LSDA) + U method. The charge and orbital ordered insulating ground state is correctly obtained with the strong on-site…

Strongly Correlated Electrons · Physics 2009-10-31 S. K. Kwon , B. I. Min

We present evidence for quantum oscillations in the pressure-induced metallic state of the 4$d$ layered perovskite Ca$_2$RuO$_4$. A complicated oscillation spectrum is observed, which is both temperature and field dependent, with unusually…

Strongly Correlated Electrons · Physics 2012-05-15 Swee K. Goh , P. L. Alireza , Lina E. Klintberg , T. Murphy , F. Nakamura , David J. Singh , Mike Sutherland

The 3d electronic structure and phase transition in pure and Cr doped V2O3 are theoretically investigated in relation to the 3d spin-orbit interaction and lattice distortion. A model consisting of the nearest-neighbor V ion pair with full…

Strongly Correlated Electrons · Physics 2016-08-31 Arata Tanaka

We present a survey of the structural and magnetic properties of submonolayer transition metal dioxides on the (001) surfaces of the heavy face-centered cubic (fcc) noble metals Ir and Pt performed by spin-averaged scanning tunneling…

Materials Science · Physics 2019-10-08 M. Schmitt , C. H. Park , P. Weber , A. Jäger , J. Kemmer , M. Vogt , M. Bode

Double perovskites like Sr$_2$FeMoO$_6$ are materials with half-metallic ground states and ferrimagnetic T$_{\rm{c}}$'s well above room temperature. This paper is the second of our comprehensive theory for half metallic double perovskites.…

Strongly Correlated Electrons · Physics 2013-04-08 Onur Erten , O. Nganba Meetei , Anamitra Mukherjee , Mohit Randeria , Nandini Trivedi , Patrick Woodward