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The exact conditions for density functionals and density matrix functionals in terms of fractional charges and fractional spins are known, and their violation in commonly used functionals has been shown to be the root of many major failures…

Other Condensed Matter · Physics 2015-06-16 Weitao Yang , Paula Mori-Sanchez , Aron J. Cohen

In Coupled-Cluster (CC) theory, unphysical complex energies may arise in the presence of strong magnetic fields, near conical intersections, or in systems exhibiting complex Abelian point group symmetries. This issue originates from the…

Chemical Physics · Physics 2025-07-28 Laura Grazioli , Marios-Petros Kitsaras , Stella Stopkowicz

Cluster perturbation theory in combination with the Lanczos method is used to compute the one-electron spectral function of the Holstein polaron in one and two dimensions. It is shown that the method allows reliable calculations using…

Strongly Correlated Electrons · Physics 2007-06-13 Martin Hohenadler , Markus Aichhorn , Wolfgang von der Linden

One-body Green's function theories implemented on the real frequency axis offer a natural formalism for the unbiased theoretical determination of quasiparticle spectra in molecules and solids. Self-consistent Green's function methods…

Computational Physics · Physics 2015-05-22 Alicia Rae Welden , Jordan J. Phillips , Dominika Zgid

A linked cluster expansion suitable for the treatment of ground-state properties of complex nuclei, as well as of various particle-nucleus scattering processes, has been used to calculate the ground-state energy, density and momentum…

Nuclear Theory · Physics 2009-11-11 M. Alvioli , C. Ciofi degli Atti , H. Morita

Approximate full configuration interaction (FCI) calculations have recently become tractable for systems of unforeseen size thanks to stochastic and adaptive approximations to the exponentially scaling FCI problem. The result of an FCI…

Strongly Correlated Electrons · Physics 2017-10-25 Susi Lehtola , Norm M. Tubman , K. Birgitta Whaley , Martin Head-Gordon

We have studied electron correlations in the doped two-dimensional (2D) Hubbard model by using the coupled-cluster method (CCM) to investigate whether or not the method can be applied to correct the independent particle approximations…

Strongly Correlated Electrons · Physics 2009-10-31 Yoshihiro Asai , Hideki Katagiri

The electromagnetic Green's function is a crucial ingredient for the theoretical study of modern photonic quantum devices, but is often difficult or even impossible to calculate directly. We present a numerically efficient framework for…

Mesoscale and Nanoscale Physics · Physics 2026-04-15 Robert Meiners Fuchs , Juanjuan Ren , Stephen Hughes , Marten Richter

We introduce a novel class of coupled cluster (CC) methods that leverage the seniority concept to enhance efficiency and accuracy in electronic structure calculations. While existing approaches, such as the pair coupled cluster doubles…

Non-unitary theories are commonly seen in the classical simulations of quantum systems. Among these theories, the method of moments of coupled-cluster equations (MMCCs) and the ensuing classes of the renormalized coupled-cluster (CC)…

Quantum Physics · Physics 2022-12-13 Bo Peng , Karol Kowalski

We present a hybrid quantum-classical Green's function Monte Carlo (GFMC) algorithm for estimating the excited states of the nuclear shell model. The conventional GFMC method, widely used to find the ground state of a quantum many-body…

Quantum Physics · Physics 2025-08-25 Yongdan Yang , Ruyu Yang , Xiaosi Xu

Many-body Green's functions theory within the GW approximation and the Bethe-Salpeter Equation (BSE) is implemented in the open-source VOTCA-XTP software, aiming at the calculation of electronically excited states in complex molecular…

We present a quantum Monte-Carlo algorithm for computing the perturbative expansion in power of the coupling constant $U$ of the out-of-equilibrium Green's functions of interacting Hamiltonians of fermions. The algorithm extends the one…

Strongly Correlated Electrons · Physics 2019-09-23 Corentin Bertrand , Olivier Parcollet , Antoine Maillard , Xavier Waintal

Introducing an active space approximation is inevitable for the quantum computations of chemical systems. However, this approximation ignores the electron correlations related to non-active orbitals. Here, we propose a computational method…

Quantum Physics · Physics 2024-06-06 Luca Erhart , Yuichiro Yoshida , Viktor Khinevich , Wataru Mizukami

We implement a highly efficient strong-coupling expansion for the Green's function of the Hubbard model. In the limit of extreme correlations, where the onsite interaction is infinite, the evaluation of diagrams simplifies dramatically…

Strongly Correlated Electrons · Physics 2014-06-06 Ehsan Khatami , Edward Perepelitsky , Marcos Rigol , B. Sriram Shastry

Boundary effects produced by a Chern-Simons (CS) extension to electrodynamics are analyzed exploiting the Green's function (GF) method. We consider the electromagnetic field coupled to a $\theta$-term in a way that has been proposed to…

Other Condensed Matter · Physics 2015-12-23 A. Martín-Ruiz , M. Cambiaso , L. F. Urrutia

The second-order Matsubara Green's function method (GF2) is a robust temperature dependent quantum chemistry approach, extending beyond the random-phase approximation. However, till now the scope of GF2 applications was quite limited as…

Chemical Physics · Physics 2017-09-20 Daniel Neuhauser , Roi Baer , Dominika Zgid

We present an overview of electronic device modeling using non-equilibrium Green function techniques. The basic approach developed in the early 1970s has become increasingly popular during the last 10 years. The rise in popularity was…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Roger K. Lake , Rajeev R. Pandey

The Green-function technique, termed the irreducible Green functions (IGF) method, that is a certain reformulation of the equation-of motion method for double-time temperature dependent Green functions is presented. This method was…

Strongly Correlated Electrons · Physics 2007-05-23 A. L. Kuzemsky

A method based on the consistent use of the Green function formalism has been developed to calculate the distribution of the single-particle strength in odd nuclei with pairing. The method takes into account the quasiparticle-phonon…

Nuclear Theory · Physics 2009-11-06 A. V. Avdeenkov , S. P. Kamerdzhiev
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