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The spatial structure of the transition region between an insulator and an electrolyte solution was studied with x-ray scattering.The electron density profile across the n-hexane/silica sol interface (solutions with 5-nm, 7-nm, and 12-nm…

Soft Condensed Matter · Physics 2009-11-11 Aleksey M. Tikhonov

Many key industrial processes, from electricity production, conversion and storage to electrocatalysis or electrochemistry in general, rely on physical mechanisms occurring at the interface between a metallic electrode and an electrolyte…

Computational Physics · Physics 2021-09-03 Laura Scalfi , Mathieu Salanne , Benjamin Rotenberg

We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the…

Soft Condensed Matter · Physics 2016-10-05 Sidney J. de Carvalho , Ralf Metzler , Andrey G. Cherstvy

Electrochemical devices often consist of multicomponent electrolyte solutions. Two processes influence the overall dynamics of these devices: the formation of electrical double layers and chemical conversion due to redox reactions. However,…

Chemical Physics · Physics 2022-06-20 Nathan Jarvey , Filipe Henrique , Ankur Gupta

Ionic liquids are widely used as electrolytes in electrochemical devices. In this context, many experimental and theoretical approaches have been recently developed for characterizing their interface with electrodes. In this perspective…

Materials Science · Physics 2017-09-13 Céline Merlet , Benjamin Rotenberg , Paul Madden , Mathieu Salanne

We utilize the self-consistent field theory to explore the mechanical and electrical properties of charged surfaces immersed in polyelectrolyte solutions that could be potentially useful for electrochemical applications. Our research…

Soft Condensed Matter · Physics 2023-08-25 Yu. A. Budkov , N. N. Kalikin

The ongoing scientific interest in the properties and structure of electric double layers (EDLs) stems from their pivotal role in (super)capacitive energy storage, energy harvesting, and water treatment technologies. Classical density…

Soft Condensed Matter · Physics 2016-04-28 Andreas Härtel , Sela Samin , Rene van Roij

We discuss the possibility of the ``mixed state'' in incommensurate charge density waves with three-dimensional order. It is shown that the mixed state can be created by applying an electric field perpendicular to the chains. This state…

Condensed Matter · Physics 2016-08-31 Masahiko Hayashi , Hideo Yoshioka

When a three-dimensional material is constructed by stacking different two-dimensional layers into an ordered structure, new and unique physical properties can emerge. An example is the delafossite PdCoO2, which consists of alternating…

We investigate the effect of sliding motion of layers in Moir\'e heterostructures on the electronic state. We show that the sliding Moir\'e heterostructure can generate nontrivial topology characterized by the first and second Chern number…

Materials Science · Physics 2020-02-05 Ying Su , Shi-Zeng Lin

Two dimensional electric potential maps based on voltage detection in conducting paper are common practice in many physics courses in college. Most frequently, students work on `capacitor-like' geometries with current flowing between two…

Physics Education · Physics 2018-11-14 A. Badia-Majos , E. de Lorenzo Poza

We study the role of the electrical double layer (EDL) in the formation of the quasistatic electrical conductivity of suspensions of nanosized particles. A suspension is viewed as a system of hard-core--penetrable-shell particles. The…

Soft Condensed Matter · Physics 2024-01-15 M. Ya. Sushko , S. D. Balika

Because micro-ions accumulate around highly charged colloidal particles in electrolyte solutions, the relevant parameter to compute their interactions is not the bare charge, but an effective (or renormalized) quantity, whose value is…

Soft Condensed Matter · Physics 2009-11-07 Lyderic Bocquet , Emmanuel Trizac , Miguel Aubouy

The electric double layer (EDL) that forms at the interface between a polyelectrolyte gel and a salt bath is studied using asymptotic and numerical methods. Specifically, matched asymptotic expansions, based on the smallness of the Debye…

Soft Condensed Matter · Physics 2022-01-28 Matthew G. Hennessy , Giulia L. Celora , Andreas Münch , Barbara Wagner , Sarah L. Waters

Single layer core/shell structures consisting of graphene as core and hexagonal boron nitride as shell are studied using first-principles plane wave method within density functional theory. Electronic energy level structure is analysed as a…

Mesoscale and Nanoscale Physics · Physics 2014-08-05 S. Cahangirov , S. Ciraci

We develop a computational method for modeling electrostatic interactions of arbitrarily-shaped, polarizable objects on colloidal length scales, including colloids/nanoparticles, polymers, and surfactants, dispersed in explicit ion…

Soft Condensed Matter · Physics 2024-06-18 Emily Krucker-Velasquez , James W. Swan , Zachary Sherman

Porous carbon is well known as a good candidate for the development of electrochemical double-layer capacitors. Predominantly, many conventional carbons are microporous and often well described by the assumption of slit pore geometry.…

Soft Condensed Matter · Physics 2022-10-12 A. L. Kolesnikov , D. A. Mazur , Yu. A. Budkov

The electrical double layer at infinite flat solid surface was discussed with respect to the triple layer model. Charge density at the outer Helmholtz plane is assumed to be zero usually. However, the assumption causes the position of the…

Chemical Physics · Physics 2007-05-23 Jong U. Kim

The relative orientation (twist) of successive layers of stacked two-dimensional (2D) materials creates variations in the interlayer atomic registry. The variations often form a super lattice, called a moir\'e pattern, which can alter…

Mesoscale and Nanoscale Physics · Physics 2020-08-05 Stephen Carr , Daniel Massatt , Mitchell Luskin , Efthimios Kaxiras

We study the nucleation of nearly-hard charged colloidal particles. We use Monte Carlo simulations in combination with free-energy calculations to accurately predict the phase diagrams of these particles and map them via the freezing…

Soft Condensed Matter · Physics 2024-06-12 Marjolein de Jager , Laura Filion