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Coherent control of interfering one- and two-photon processes has for decades been the subject of research to achieve the redirection of photocurrent. The present study develops two-pathway coherent control of ground state helium atom…

Atomic Physics · Physics 2021-06-02 Yimeng Wang , Chris H. Greene

We develop photoelectron interferometry based on laser-assisted extreme ultraviolet ionization for flexible and robust control of photoelectron circular dichroism in randomly oriented chiral molecules. A comb of XUV photons ionizes a sample…

Spectroscopic techniques that are sensitive to molecular chirality are important analytical tools to quantitatively determine enantiomeric excess and purity of chiral molecular samples. Many chiroptical processes however produce weak…

Chemical Physics · Physics 2026-04-02 Sebastian Hartweg , Dusan k. Bozanic , Gustavo A. Garcia-Macias , Laurent Nahon

Chirality causes symmetry breaks in a large variety of natural phenomena ranging from particle physics to biochemistry. We investigate one of the simplest conceivable chiral systems, a laser-excited, oriented, effective one-electron Li…

We report two schemes to generate perfect anisotropy in the photoelectron angular distribution of a randomly oriented ensemble of polyatomic molecules. In order to exert full control over the anisotropy of photoelectron emission, we exploit…

Quantum Physics · Physics 2020-02-24 R. Esteban Goetz , Christiane P. Koch , Loren Greenman

Chiral molecules exhibit enantiosensitive light-matter interactions, with photoelectron circular dichroism (PECD) serving as a sensitive probe of molecular chirality through the asymmetry in the photoelectron wavepacket amplitude. Here, we…

Atomic Physics · Physics 2025-05-07 Zheming Zhou , Yang Li , Xu Zhang , Yueming Zhou , Peixiang Lu

Photoionization of randomly oriented chiral molecules with circularly polarized light leads to a strong forward/backward asymmetry in the photoelectron angular distribution. This chiroptical effect, referred to as Photoelectron Circular…

Photoelectron circular dichroism refers to the forward/backward asymmetry in the photoelectron angular distribution with respect to the propagation axis of circularly polarized light. It has recently been demonstrated in femtosecond…

Quantum Physics · Physics 2017-01-16 R. E. Goetz , T. A. Isaev , B. Nikoobakht , R. Berger , C. P. Koch

Photoelectron circular dichroism results from one-photon ionization of chiral molecules by circularly polarized light and manifests itself in forward-backward asymmetry of electron emission in the direction orthogonal to the light…

Atomic Physics · Physics 2019-04-24 Andres F. Ordonez , Olga Smirnova

We demonstrate a fully integrable and reconfigurable platform for controlling quantum emission by harnessing chiral exceptional bound states in the continuum (BICs) as a higher-order non-Hermitian singularity. Our architecture employs…

Optics · Physics 2026-03-09 Jin Li , Kexun Wu , Qi Hao , Yan Chen , Jiawei Wang

Chirality is ubiquitous in nature and fundamental in science, from particle physics to metamaterials.The most established technique of chiral discrimination - photoabsorption circular dichroism - relies on the magnetic properties of a…

Angular distribution of photoelectrons released by the ionization of randomly-oriented molecules with two laser fields of carrier frequencies $\omega$ and $2\omega$, which are linearly polarized in two mutually-orthogonal directions, is…

Quantum Physics · Physics 2019-06-11 Philipp V. Demekhin

Measuring and controlling the ionization dynamics by intense laser fields has recently led to important breakthroughs, from the investigation of tunneling time delays to attosecond molecular imaging by electron holography. In these…

We consider the role of quantum mechanics in a specific coherent control scenario, designing a "coherent control interferometer" as the essential tool that links coherent control to quantum fundamentals. Building upon this allows us to…

Quantum Physics · Physics 2014-11-27 Torsten Scholak , Paul Brumer

On-chip integrated photonic circuits are crucial to further progress towards quantum technologies and in the science of quantum optics. Here we report precise control of single photon states and multi-photon entanglement directly on-chip.…

Quantum Physics · Physics 2009-11-09 Jonathan C. F. Matthews , Alberto Politi , Andre Stefanov , Jeremy L. O'Brien

Controlling the polarization state of electromagnetic radiation enables the investigation of fundamental symmetry properties of matter through chiroptical processes. Many strategies have been developed to reveal structural or dynamical…

Enantioselective photochemistry provides access to unique molecular structures and functions, with deep implications for fundamental science and industrial applications. Current methods for highly enantioselective photochemistry critically…

Chemical Physics · Physics 2025-03-07 Andrés Ordóñez , Patricia Vindel-Zandbergen , David Ayuso

We investigate how optimal control theory can be used to improve Circular Dichroism (CD) signals for A--band of fenchone measured via the photoionization yield upon further excitation. These transitions are electric dipole forbidden to…

It is commonly accepted that the magnitude of a photoelectron circular dichroism (PECD) is governed by the ability of an outgoing photoelectron wave packet to probe the chiral asymmetry of a molecule. To be able to accumulate this…

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