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Related papers: Ehrenfest+R Dynamics II: A Semiclassical QED Frame…

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The optical response of an electronic two-level system (TLS) coupled to an incident continuous wave (cw) electromagnetic (EM) field is simulated explicitly in one dimension by the following five approaches: (i) the coupled Maxwell-Bloch…

Optics · Physics 2019-03-19 Tao E. Li , Hsing-Ta Chen , Joseph E. Subotnik

The thawed Gaussian Ehrenfest dynamics is a single-trajectory method that partially includes both nuclear quantum and electronically nonadiabatic effects by combining the thawed Gaussian wavepacket dynamics with Ehrenfest dynamics. First,…

Chemical Physics · Physics 2025-04-09 Alan Scheidegger , Jiří J. L. Vaníček

We report observations of novel dynamic behavior in resonantly-enhanced stimulated Raman scattering in Rb vapor. In particular, we demonstrate a dynamic hysteresis of the Raman scattered optical field in response to changes of the drive…

Quantum Physics · Physics 2009-11-10 I. Novikova , A. S. Zibrov , D. F. Phillips , A. Andre , R. L. Walsworth

Metastable qubits in atomic systems can enable large-scale quantum computing by simplifying hardware requirements and adding efficient erasure conversion to the pre-existing toolbox of high-fidelity laser-based control. For trapped atomic…

Raman scattering underlies a broad range of spectroscopic and light-generation techniques, yet its conventional description, based on the Raman gain spectrum, accurately describes only long-pulse, steady-state dynamics. We present a…

Charge-charge, current-current and Raman correlation functions are derived in a consistent way using the unified response theory. The theory is based on the improved description of the conduction electron coupling to the external…

Strongly Correlated Electrons · Physics 2007-05-23 Ivan Kupcic , Slaven Barisic

We present an exact solution for electronic Raman scattering in a single-band, strongly correlated material, including nonresonant, resonant and mixed contributions. Results are derived for the spinless Falicov-Kimball model, employing…

Strongly Correlated Electrons · Physics 2007-05-23 A. M. Shvaika , O. Vorobyov , J. K. Freericks , T. P. Devereaux

We consider the dynamics of interacting quantum and classical systems in the Heisenberg representation. Unlike the usual construction in standard quantum mechanics, mixed quantum-classical systems involve the interplay of unitary operators…

Chemical Physics · Physics 2025-05-26 David Martínez-Crespo , Cesare Tronci

We use dynamical mean field theory to find an exact solution for inelastic light scattering in strongly correlated materials such as those near a quantum-critical metal-insulator transition. We evaluate the results for $\textbf{q}=0$…

Strongly Correlated Electrons · Physics 2009-11-10 A. M. Shvaika , O. Vorobyov , J. K. Freericks , T. P. Devereaux

Inelastic low-energy Raman and high-energy X-ray scatterings have made great progress in instrumentation to investigate the strong electronic correlations in matter. However, theoretical study of the relevant scattering spectrum is still a…

Superconductivity · Physics 2017-09-18 Yuehua Su

Ehrenfest Dynamics combined with real-time time-dependent density functional theory has proven to be a reliable tool to study non-adiabatic molecular dynamics with a reasonable computational cost. Among other possibilities, it allows for…

Materials Science · Physics 2023-01-05 Ronaldo Rodrigues Pela , Claudia Draxl

We show that spontaneous Raman scattering of incident radiation can be observed in cavity-QED systems without external enhancement or coupling to any vibrational degree of freedom. Raman scattering processes can be evidenced as resonances…

A first-principles coupled electron-nuclear dynamics simulation based on real-time, time-dependent density functional theory and Ehrenfest dynamics quantitatively repro-duces bimodal translational energy loss and angular distributions…

Chemical Physics · Physics 2025-12-05 Jialong Shi , Lingjun Zhu , Florian Nitz , Oliver Bünermann , Alec M. Wodtke , Hua Guo , Bin Jiang

A theoretical model of resonant hyper-Raman scattering by an ensemble of spherical semiconductor quantum dots has been developed. The electronic intermediate states are described as Wannier-Mott excitons in the framework of the envelope…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 E. Menendez-Proupin , C. Trallero-Giner , A. Garcia-Cristobal

We show that standard Ehrenfest dynamics does not conserve linear and angular momentum when using a basis of truncated adiabatic states. However, we also show that previously proposed effective Ehrenfest equations of…

Chemical Physics · Physics 2023-12-15 Zhen Tao , Xuezhi Bian , Yanze Wu , Jonathan Rawlinson , Robert G. Littlejohn , Joseph E. Subotnik

We consider a model of Raman scattering for a two--dimensional $S=1/2$ Heisenberg Anti-Ferromagnet which includes a {\it dynamical} spin--phonon interaction. We observe a broadening of the line shape due to increased coupling with excited…

Condensed Matter · Physics 2009-10-28 Matthew J. Reilly , A. G. Rojo

Plasmon-enhanced Raman scattering can push single-molecule vibrational spectroscopy beyond a regime addressable by classical electrodynamics. We employ a quantum electrodynamics (QED) description of the coherent interaction of plasmons and…

We present a method for calculation of Raman modes of the quantum solid phase I solid hydrogen and deuterium. We use the mean-field assumption that the quantised excitations are localized on one molecule. This is done by explicit solution…

The atomistic resolution recently achieved by ultrafast spectroscopies demands corresponding theoretical advances. Real-time time-dependent density-functional theory (RT-TDDFT) with Ehrenfest dynamics offers an optimal trade-off between…

Materials Science · Physics 2022-10-19 Jannis Krumland , Matheus Jacobs , Caterina Cocchi

We present theoretical results concerning inelastic light (Raman) scattering from semiconductor quantum dots. The characteristics of each dot state (whether it is a collective or single-particle excitation, its multipolarity, and its spin)…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Alain Delgado , Augusto Gonzalez , David J. Lockwood