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Related papers: Phase separation of stable colloidal clusters

200 papers

We present an approximation scheme to the master kinetic equations for aggregation and gelation with thermal breakup in colloidal systems with variable attraction energy. With the cluster fractal dimension $d_{f}$ as the only…

Soft Condensed Matter · Physics 2013-04-05 Alessio Zaccone , Jerome J. Crassous , Matthias Ballauff

Motivated by recent experimental and theoretical work on the control of phase separation by (electro-)autocatalytic reactions, we analyze pattern formation in externally driven phase separating systems described by a generalization of the…

Chemical Physics · Physics 2023-10-03 Hongbo Zhao , Martin Z. Bazant

We study the nucleation of crystalline cluster phases in the generalized exponential model with exponent n=4. Due to the finite value of this pair potential for zero separation, at high densities the system forms cluster crystals with…

Soft Condensed Matter · Physics 2016-09-01 Christian Leitold , Christoph Dellago

We review some properties of the stationary states of the Fokker - Planck equation for N interacting particles within a mean field approximation, which yields a non-linear integrodifferential equation for the particle density. Analytical…

Statistical Mechanics · Physics 2009-11-07 N. Martzel , C. Aslangul

A simple model of irreversible aggregation under differential sedimentation of particles in a fluid is presented. The structure of the aggregates produced by this process is found to feed back on the dynamics in such a way as to stabilise…

Atmospheric and Oceanic Physics · Physics 2009-11-10 C. D. Westbrook , R. C. Ball , P. R. Field , A. J. Heymsfield

We show that short-range correlations have a dramatic impact on the steady-state phase diagram of quantum driven-dissipative systems. This effect, never observed in equilibrium, follows from the fact that ordering in the steady state is of…

Statistical Mechanics · Physics 2016-07-29 Jiasen Jin , Alberto Biella , Oscar Viyuela , Leonardo Mazza , Jonathan Keeling , Rosario Fazio , Davide Rossini

We report an extensive numerical study of a charged colloidal system with competing short-range depletion attraction and long-range electrostatic repulsion. By analizing the cluster properties, we identify two distinct regions in the phase…

Soft Condensed Matter · Physics 2009-03-18 Juan Carlos Fernandez Toledano , Francesco Sciortino , Emanuela Zaccarelli

We present molecular dynamics simulations of aggregation kinetics in a colloidal suspension modeled as a highly asymmetric binary mixture. Starting from a configuration with largely uncorrelated colloidal particles the system relaxes by…

Statistical Mechanics · Physics 2007-05-23 Sorin Bastea

We develop a mesoscopic field theory for the collective nonequilibrium dynamics of multicomponent mixtures of interacting active (i.e., motile) and passive (i.e., nonmotile) colloidal particles with isometric shape in two spatial…

Soft Condensed Matter · Physics 2018-02-12 Raphael Wittkowski , Joakim Stenhammar , Michael E. Cates

Nonequilibrium steady states in an open system connecting two reservoirs of platelike colloidal particles are investigated by means of a recently proposed phenomenological dynamic density functional theory [M. Bier and R. van Roij, Phys.…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Rene van Roij

An electric-field-induced phase transition and pattern formation in a binary dielectric fluid layer are studied using a coarse-grained free energy functional. The electrostatic part of the free energy is a nonlinear functional of the…

Soft Condensed Matter · Physics 2007-05-23 M. D. Johnson , X. Duan , Brett Riley , Aniket Bhattacharya , Weili Luo

The formation of the beam halo in charged particle accelerators is studied in the framework of a stochastic-hydrodynamic model for the collective motion of the particle beam. In such a stochastic-hydrodynamic theory the density and the…

Statistical Mechanics · Physics 2009-11-10 Nicola Cufaro Petroni , Salvatore De Martino , Silvio De Siena , Fabrizio Illuminati

Metastable phases may be spontaneously formed from other metastable phases through nucleation. Here we demonstrate the spontaneous formation of a metastable phase from an unstable equilibrium by spinodal decomposition, which leads to a…

Soft Condensed Matter · Physics 2016-10-10 Ricard Alert , Pietro Tierno , Jaume Casademunt

Binary aggregation is known to lead, under certain kinetic rules, to the coexistence of two populations, one consisting of finite-size clusters (sol), and one that contains a single cluster that carries a finite fraction of the total mass…

Statistical Mechanics · Physics 2015-03-17 Themis Matsoukas

Colloidal gels formed by strongly attractive particles at low particle volume fractions are composed of space-spanning networks of uniformly sized clusters. We study the thermal fluctuations of the clusters using differential dynamic…

Soft Condensed Matter · Physics 2021-03-31 Jae Hyung Cho , Irmgard Bischofberger

By means of classical density functional theory and its dynamical extension, we consider a colloidal fluid with spherically-symmetric competing interactions, which are well known to exhibit a rich bulk phase behavior. This includes complex…

Soft Condensed Matter · Physics 2018-06-11 Daniel Stopper , Roland Roth

The order-disorder transition of a sphere-forming block copolymer thin film was numerically studied through a Cahn-Hilliard model. Simulations show that the fundamental mechanisms of pattern formation are spinodal decomposition and…

Soft Condensed Matter · Physics 2017-08-28 Leopoldo R. Gómez , Nicolás A. García , Richard A. Register , Daniel A. Vega

We report event-driven molecular dynamics simulations of the irreversible gelation of hard ellipsoids of revolution containing several associating groups, characterizing how the cluster size distribution evolves as a function of the extent…

Using a phase field crystal model we study the structure and dynamics of a drop of colloidal suspension during evaporation of the solvent. We model an experimental system where contact line pinning of the drop on the substrate is…

Soft Condensed Matter · Physics 2012-09-06 Nirmalendu Ganai , Arnab Saha , Surajit Sengupta

A mixture of hard-sphere particles and model emulsion droplets is studied with a Brownian dynamics simulation. We find that the addition of nonwetting emulsion droplets to a suspension of pure hard spheres can lead to both gas-liquid and…

Soft Condensed Matter · Physics 2015-03-13 Andrea Fortini