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Nanocrystalline pure FCC metals and some alloys are known to exhibit abnormal grain growth. Addition of solutes, such as W, has led to improved grain size stability in nanocrystalline Ni. While several groups have investigated grain growth…

Applied Physics · Physics 2024-10-22 Keerti Pandey , Aman Prasad

Radiation-induced segregation (RIS) poses a significant challenge for ferritic Fe-Cr alloys under irradiation, as it can compromise mechanical integrity and increase susceptibility to intergranular corrosion. Yet, the mechanisms governing…

Materials Science · Physics 2026-03-17 Russell Oplinger , Mukesh Bachhav , Karim Ahmed , Sourabh Bhagwan Kadambi

Solute segregation in alloys is a key phenomenon which affects various material characteristics such as embrittlement, grain growth and precipitation kinetics. In this work, the segregation energies of Y, Zr, and Nb to a \textgreek{S}5…

Materials Science · Physics 2025-03-06 Hariharan Umashankar , Daniel Scheiber , Vsevolod I. Razumovskiy , Matthias Militzer

The mechanical behavior of two nanocrystalline Al alloys, Al-Mg-Y and Al-Fe-Y, is investigated with in-situ micropillar compression testing. Both alloys were strengthened by a hierarchical microstructure including grain boundary…

Materials Science · Physics 2022-08-02 Tianjiao Lei , Esther C. Hessong , Jungho Shin , Daniel S. Gianola , Timothy J. Rupert

While it is known that alloy components can segregate to grain boundaries (GBs), and that the atomic mobility in GBs greatly exceeds the atomic mobility in the lattice, little is known about the effect of GB segregation on GB diffusion.…

Materials Science · Physics 2020-08-17 R. K. Koju , Y. Mishin

Nanocrystalline materials are defined by their fine grain size, but details of the grain boundary character distribution should also be important. Grain boundary character distributions are reported for ball milled, sputter deposited, and…

Materials Science · Physics 2016-01-27 David B. Bober , Amirhossein Khalajhedayati , Mukul Kumar , Timothy J. Rupert

We examined the proximity effect in granular films made of Pb, a superconductor, and Ni, a ferromagnet, with various compositions. Slow decay of the critical temperature as a function of the relative volume concentration of Ni per sample…

Superconductivity · Physics 2018-01-30 Hadar Greener , Victor Shelukhin , Michael Karpovski , Moshe Goldstein , Alexander Palevski

The components of the wide binary HIP64030=HD 113984 show a large (about 0.25 dex) iron content difference (Desidera et al.~2006 A&A 454, 581). The positions of the components on the color magnitude diagram suggest that the primary is a…

Astrophysics · Physics 2007-05-23 S. Desidera , R. Gratton , S. Lucatello , M. Endl , S. Udry

Modeling solute segregation to grain boundaries at near first-principles accuracy is a daunting task, particularly at finite concentrations and temperatures that require accurate assessments of solute-solute interactions and excess…

Materials Science · Physics 2025-02-13 Nutth Tuchinda , Christopher A. Schuh

Microalloying elements tend to segregate to the matrix-precipitate phase boundaries to reduce the interfacial energy. The segregation mechanism is emerging as a novel design strategy for developing precipitation-hardened alloys with…

Materials Science · Physics 2022-01-11 Sourabh Bhagwan Kadambi , Srikanth Patala

Grain boundary complexions have been observed to affect the mechanical behavior of nanocrystalline metals, improving both strength and ductility. While an explanation for the improved ductility exists, the observed effect on strength…

Materials Science · Physics 2018-03-28 Vladyslav Turlo , Timothy J. Rupert

This paper studies how solute segregation and its relationship to grain boundary energy in binary alloys is captured in the phase field crystal (PFC) formalism, a continuum method that incorporates atomic scale elasto-plastic effects on…

Materials Science · Physics 2013-04-10 Jonathan Stolle , Nikolas Provatas

Tailoring and improving material properties by alloying is a long-known and used concept. Recent research has demonstrated the potential of ab initio calculations in understanding the material properties at the nanoscale. Here we present a…

Materials Science · Physics 2013-10-16 David Holec , Liangcai Zhou , Richard Rachbauer , Paul H. Mayrhofer

We have systematically investigated the grain boundary (GB) angle dependence of transport properties for NdFeAs(O,F) fabricated on [001]-tilt symmetric MgO bicrystal substrates. In our previous study, NdFeAs(O,F) bicrystal films showed a…

Superconductivity · Physics 2019-04-09 Kazumasa Iida , Taito Omura , Takuya Matsumoto , Takafumi Hatano , Hiroshi Ikuta

We present here the application of a model for a mass circulation mechanism in between the H-burning shell and the base of the convective envelope of low mass AGB stars, aimed at studying the isotopic composition of those presolar grains…

Solar and Stellar Astrophysics · Physics 2017-02-21 Sara Palmerini , Oscar Trippella , Maurizio Busso

Determining the full five-parameter grain boundary characteristics from experiments is essential for understanding grain boundaries impact on material properties, improving related models, and designing advanced alloys. However, achieving…

Grain boundary structural transitions can lead to significant changes in the properties and performance of materials. In multi-principal element alloys, understanding these transitions becomes complex due to phenomena such as local chemical…

Materials Science · Physics 2024-03-13 Ian Geiger , Diran Apelian , Xiaoqing Pan , Penghui Cao , Jian Luo , Timothy J. Rupert

A mixture of dissipative hard grains generically exhibits a breakdown of kinetic energy equipartition. The undriven and thus freely cooling binary problem, in the tracer limit where the density of one species becomes minute, may exhibit an…

Statistical Mechanics · Physics 2015-03-13 Vicente Garzó , Nagi Khalil , Emmanuel Trizac

The binary alloy of titanium-tungsten (TiW) is an established diffusion barrier in high-power semiconductor devices, owing to its ability to suppress the diffusion of copper from the metallisation scheme into the surrounding silicon…

In this paper we present iron abundance analysis for 23 wide binaries with main sequence components in the temperture range 4900-6300 K, taken from the sample of the pairs currently included in the radial velocity planet search on going at…