Related papers: Protonated CO2 in massive star-forming clumps
The interstellar medium contains dust and gas, in which at high densities and cold conditions molecules can proliferate. Interstellar Complex Organic Molecules (iCOMs) are C-bearing species that contain at least six atoms. As they are…
Carbon monoxide (CO) is the second most abundant molecule in the gas-phase of the interstellar medium. In dense molecular clouds, it is also present in the solid-phase as a constituent of the mixed water-dominated ices covering dust grains.…
We present numerical computations and analytic scaling relations for interstellar ion-molecule gas phase chemistry down to very low metallicities ($ 10^{-3} \times$ solar), and/or up to high driving ionization rates. Relevant environments…
The formation of deuterated molecules is favoured at low temperatures and high densities. Therefore, the deuteration fraction D$_{frac}$ is expected to be enhanced in cold, dense prestellar cores and to decrease after protostellar birth.…
C$_2$H is a representative hydrocarbon that is abundant and ubiquitous in the interstellar medium (ISM). To study its chemical properties, we present Submillimeter Array (SMA) observations of the C$_2$H $N=3-2$ and HC$_3$N $J=30-29$…
The chemical evolution in star forming regions is driven by the interplay between gas and ice mantles. Identifying the ice compositions at the early stage of star formation thus provides constraints on the chemical processes inaccessible…
CO has long been thought to be the best tracer to measure gas masses as it is readily detected at (sub)mm wavelengths in many disks. Inferred gas masses from CO in recent ALMA observations of large samples of disks seem inconsistent with…
Observations of carbon monoxide (CO) emission in high redshift (z>2) galaxies indicate the presence of large amounts of molecular gas. Many of these galaxies contain an active galactic nucleus (AGN) powered by accretion of gas onto a…
Context. he study of prestellar cores is essential to understanding the initial stages of star formation. With $Herschel$ more cold clumps have been detected than ever before. For this study we have selected 21 cold clumps from 20…
Even though water is the main constituent in interstellar icy mantles, its chemical origin is not well understood. Three different formation routes have been proposed following hydrogenation of O, O2, or O3, but experimental evidence is…
Context. Radio frequency molecular absorption lines appear along sight lines with AV well below 1 mag, revealing the presence of H2 in diffuse gas even when 2.6mm CO emission is absent. Aims. We discuss absorption lines of HCO+, C2H, HCN,…
Carbon monoxide (CO) is the most commonly used tracer of molecular gas in the inner regions of protoplanetary disks. CO can be used to constrain the excitation and structure of the circumstellar environment. Absorption line spectroscopy…
The interaction of carbon atoms with solid carbon monoxide (CO) is a fundamental process in astrochemistry, influencing the formation of complex organic molecules in interstellar environments. This study investigates the adsorption and…
There has always been a great deal of interest in the formation of H2 as well as in the binding energy released upon its formation on the surface of dust grains. The present work aims at collecting experimental evidence for how the bond…
Methods: The microscopic equations of H2-formation and protonation are integrated numerically over time in such a manner that the overall structures evolve self-consistently under benign conditions. Results: The equilibrium H2 formation…
iCOMs are species commonly found in the interstellar medium. They are believed to be crucial seed species for the build-up of chemical complexity in star forming regions as well as our own Solar System. Thus, understanding how their…
We present the results of a survey of CO emission in 43 of the 48 representative E/S0 galaxies observed in the optical with the SAURON integral-field spectrograph. The CO detection rate is 12/43 or 28%. This is lower than previous studies…
I review recent observations of molecular gas in the halo of the Milky Way and in the Magellanic Clouds. Far-ultraviolet absorption line studies of molecular hydrogen (H_2) with ORFEUS and FUSE have unveiled the presence of a diffuse…
Determining molecular abundance ratios is important not only for the study of the Galactic chemistry but also because they are useful to estimate physical parameters in a large variety of interstellar medium environments. The CO is one of…
Aims: Ices in dense star-forming cores contain the bulk of volatile molecules apart from H2 and thus represent a large fraction of dark cloud chemistry budget.To directly constrain the freeze-out profile of CO, the formation route of CO2…