Related papers: Macroscopic Observables, Thermodynamic Completenes…
The extension of thermodynamic principles to active matter remains a challenge due to the non-equilibrium nature inherent to active systems. In this study, we introduce a framework to assess entropy in our minimal macroscopic experiment…
From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…
This paper is a non-technical, informal presentation of our theory of the second law of thermodynamics as a law that is independent of statistical mechanics and that is derivable solely from certain simple assumptions about adiabatic…
Firstly, we calculate quantitatively decrease of entropy by the known formulas in the ordering phenomena and nucleation of thermodynamics of microstructure. They show again that a necessary condition of decrease of entropy in isolated…
To understand under which conditions thermodynamics emerges from the microscopic dynamics is the ultimate goal of statistical mechanics. Despite the fact that the theory is more than 100 years old, we are still discussing its foundations…
Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…
The division by N! in the expression of statistical entropy is usually justified to students by the statement that classical particles should be counted as indistinguishable. Sometimes, quantum indistinguishability is invoked to explain it.…
The second law of thermodynamics states that entropy increases (or does not change) by time in an isolated system. As microscopic physical laws are reversible, the origin of irreversibility is not straightforward. Although the outcome of a…
We review recent progress in understanding certain aspects of the thermodynamics of black holes and other horizons. Our discussion centers on various ``entropy bounds'' which have been proposed in the literature and on the current…
Entropy can signify different things: For instance, heat transfer in thermodynamics or a measure of information in data analysis. Many entropies have been introduced and it can be difficult to ascertain their different importance and…
In this chapter we address the topic of quantum thermodynamics in the presence of additional observables beyond the energy of the system. In particular we discuss the special role that the generalized Gibbs ensemble plays in this theory,…
We numerically determine the entropy for heat-conducting states, which is connected to the so-called excess heat considered as a basic quantity for steady-state thermodynamics in nonequilibrium. We adopt an efficient method to estimate the…
In systems far from equilibrium, the statistics of observables are connected to entropy production, leading to the Thermodynamic Uncertainty Relation (TUR). However, the derivation of TURs often involves constraining the parity of…
Noncommutativity of observables is a central feature of quantum physics. It plays a fundamental role in the formulation of the uncertainty principle for complementary variables and strongly affects the laws of thermodynamics for systems…
We show how statistical thermodynamics can be formulated in situations in which thermodynamics applies, while equilibrium statistical mechanics does not. A typical case is, in the words of Landau and Lifshitz, that of partial (or…
These notes provide a brief primer on the basic aspects of "observational entropy" (also known as "quantum coarse-grained entropy"), a general framework for applying the concept of coarse-graining to quantum systems. We review the basic…
We introduce a constructive framework for assigning thermodynamic structure to an arbitrary data system from its measured microstates. Starting from an empirical distribution over configurations, we first infer a data-driven energy function…
Observational entropy provides a general notion of quantum entropy that appropriately interpolates between Boltzmann's and Gibbs' entropies, and has recently been argued to provide a useful measure of out-of-equilibrium thermodynamic…
A thermodynamic-like formalism is developed for superstatistical systems based on conditional entropies. This theory takes into account large-scale variations of intensive variables of systems in nonequilibrium stationary states. Ordinary…
Thermodynamics relies on the possibility to describe systems composed of a large number of constituents in terms of few macroscopic variables. Its foundations are rooted into the paradigm of statistical mechanics, where thermal properties…