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Pristine, single-crystalline graphene displays a unique collection of remarkable electronic properties that arise from its two-dimensional, honeycomb structure. Using in-situ low-energy electron microscopy, we show that when deposited on…

Using kinetic Monte Carlo simulations, we develop a framework to relate morphological properties and microscopic dynamics during island growth, coalescence, and initial formation of continuous heteroepitaxial films. The average island width…

Materials Science · Physics 2021-07-22 Tung B. T. To , Renan A. L. Almeida , Sukarno O. Ferreira , Fábio D. A. Aarão Reis

Growth of epitaxial graphene on the C-face of SiC has been investigated. Using a confinement controlled sublimation (CCS) method, we have achieved well controlled growth and been able to observe propagation of uniform monolayer graphene.…

Materials Science · Physics 2012-11-29 Rui Zhang , Yunliang Dong , Wenjie Kong , Wenpeng Han , Pingheng Tan , Zhimin Liao , Xiaosong Wu , Dapeng Yu

Using ab initio thermodynamics, the stability of a wide range of hydrocarbon adsorbates under various chemical vapor deposition (CVD) conditions (temperature, methane and hydrogen pressures) used in experimental graphene growth protocols at…

Materials Science · Physics 2019-06-14 Mie Andersen , Juan Santiago Cingolani , Karsten Reuter

Recent experiments show that the islanding behavior during chemical vapor deposition (CVD) of Si on Si(111) using disilane (Si${_2}$H${_6}$) is quite different from that due to molecular beam epitaxy (MBE). While the latter can be…

Condensed Matter · Physics 2007-05-23 K. E. Khor , Sankar Das Sarma

Recent studies on graphene hydrogenation processes showed that hydrogenation occurs via island growing domains, however how the substrate can affect the hydrogenation dynamics and/or pattern formation has not been yet properly investigated.…

Despite the large literature focused on the growth of graphene (Gr) on 6H-SiC(0001) by chemical vapour deposition (CVD), some important issues have not been solved and full wafer scale epitaxy of Gr remains challenging, hampering…

Multilayer graphene (MLG) films were grown by chemical vapour deposition (CVD) on molybdenum carbide ($MoC_{x}$) substrates. We fabricated the catalytic $MoC_{x}$ films by plasma enhanced atomic layer deposition (PEALD). The mechanism of…

Applied Physics · Physics 2020-01-01 Eldad Grady , Chenhui Li , Oded Raz , W. M. M. Kessels , Ageeth A. Bol

Graphene, a flat monolayer of carbon atoms packed tightly into a two dimensional hexagonal lattice, has unusual electronic properties which have many promising nanoelectronic applications. Recent Low Energy Electron Microscopy (LEEM)…

Materials Science · Physics 2016-02-05 J H Lloyd-Williams

Density functional theory has been employed to study graphene on the (111), (100) and (110) surfaces of silicon (Si) substrates. There are several interesting findings. First, carbon atoms in graphene form covalent bonds with Si atoms, when…

Materials Science · Physics 2021-07-14 Y. W. Sun , D. Holec , D. Gehringer , L. Li , O. Fenwick , D. J. Dunstan , C. J. Humphreys

In this work we present a simple pathway to obtain large single-crystal graphene on copper (Cu) foils with high growth rates using a commercially available cold-wall chemical vapour deposition (CVD) reactor. We show that graphene nucleation…

Atomically resolved imaging and spectroscopic characteristics of graphene grown by chemical vapor deposition (CVD) on copper are investigated by means of scanning tunneling microscopy and spectroscopy (STM/STS). For CVD-grown graphene…

Strongly Correlated Electrons · Physics 2012-01-27 N. -C. Yeh , M. L. Teague , S. Yeom , B. L. Standley , D. A. Boyd , M. W. Bockrath

Titanium-island formation on graphene as a function of defect density is investigated. When depositing titanium on pristine graphene, titanium atoms cluster and form islands with an average diameter of about 10nm and an average height of a…

Chemical Physics · Physics 2015-03-17 T. Mashoff , D. Convertino , V. Miseikis , C. Coletti , V. Piazza , V. Tozzini , F. Beltram , S. Heun

Diffusion of small two dimensional Cu islands (containing up to 10 atoms) on Cu(111) has been studied using the newly developed self-learning Kinetic Monte Carlo SLKMC method. It is based on a database of diffusion processes and their…

Using first-principles calculations within density functional theory, we study the energetics and kinetics of carbon nucleation in the early stages of epitaxial graphene growth on three representative stepped metal surfaces: Ir(111),…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 Hua Chen , Wenguang Zhu , Zhenyu Zhang

From both fundamental and technical points of view, a precise control of the layer number of graphene samples is very important. To reach this goal, atomic scale mechanisms of multilayer graphene growth on metal surfaces should be…

Materials Science · Physics 2014-03-19 Ping Wu , Xiaofang Zhai , Zhenyu Li , Jinlong Yang

In graphene growth, island symmetry can become lower than the intrinsic symmetries of both graphene and the substrate. First-principles calculations and Monte Carlo modeling explain the shapes observed in our experiments and earlier studies…

Materials Science · Physics 2015-03-25 Vasilii I. Artyukhov , Yufeng Hao , Rodney S. Ruoff , Boris I. Yakobson

In this work, the effect of the ion fluence-dependent defect formation on the modification of surface electronic and optical properties of graphene has been investigated. The chemical vapor deposited (CVD) graphene was irradiated with swift…

Materials Science · Physics 2022-06-14 Tanmay Mahanta , Sanjeev Kumar , D. Kanjilal , Tanuja Mohanty

This work presents a comparison of the structural, chemical and electronic properties of multi-layer graphene grown on SiC(000-1) by using two different growth approaches: thermal decomposition and chemical vapor deposition (CVD). The…

Materials Science · Physics 2018-05-03 D. Convertino , A. Rossi , V. Miseikis , V. Piazza , C. Coletti

As the synthesis of graphene on copper became one of the primary preparation methods for both fundamental research and industrial application, Raman spectra of graphene/Cu systems need to be quantitatively understood regarding how their…

Materials Science · Physics 2020-08-07 Jieun Choi , Seonghyun Koo , Myeongin Song , Daeyool Jung , Sungyool Choi , Sunmin Ryu