Related papers: Colossal barocaloric effects in plastic crystals
Refrigeration systems based on compression of greenhouse gases are environmentally threatening and cannot be scaled down to on-chip dimensions. In the vicinity of a phase transition caloric materials present large thermal responses to…
We performed calorimetric studies of 26 metallic glasses and calculated the excess entropy and excess enthalpy with respect to their counterpart crystals. On this basis, we introduced a dimensionless entropy-based parameter {\sigma}scl,…
We describe magneto-, baro- and elastocaloric effects (MCEs, BCEs and eCEs) in materials which possess both discontinuous (first-order) and continuous (second-order) magnetic phase transitions. Our ab initio theory of the interacting…
The electrocaloric (EC) effect and energy storage properties of eco-friendly ferroelectric Ba0.9Sr0.1Ti1-xSnxO3 (BSTS-x) ceramics prepared by the conventional solid-state reaction method were studied. Significant energy efficiency exceeding…
Recent progress on caloric effects are reviewed. The application of external stimuli such as magnetic field, hydrostatic pressure, uniaxial stress and electric field give rise respectively to magnetocaloric, barocaloric, elastocaloric and…
Lead-free BaTi0.89Sn0.11O3 (BTSn) ceramic was elaborated via a solid-state reaction method and its dielectric, ferroelectric, energy storage, electromechanical as well as electrocaloric properties were investigated at 25 kV/cm. Pure…
Giant electrocaloric (EC) effect is observed in BaTiO3 multilayer thick film structure. The temperature change is as high as 4.0 oC under an applied electric field of 352 kV/cm. Most importantly, the EC effect is found to depend on the…
We report on a novel class of nanocrystalline/amorphous Gd$_3$Ni/Gd$_{65}$Ni$_{35}$ composite microwires, which was created directly by melt-extraction through controlled solidification. X-ray diffraction (XRD) and transmission electron…
The global emphasis on sustainable technologies has become a paramount concern for nations worldwide. Specifically, numerous sustainable methods are being explored as promising alternatives to the well-established vapor-compression…
We review well-known signatures of disorder in crystallographic and inelastic neutron scattering data. We show that these can arise from different types of disorder, corresponding to different values of the system entropy. Correlating the…
The electrocaloric (EC) effect is calculated for Gd-substituted PMN (x = 0 to 0.1) relaxors from temperature dependent heat capacity and polarization measurements, using a thermodynamic Maxwell equation. Polarization change with temperature…
There is a surge of interest in developing environmentally friendly cooling technology based on the solid--state electrocaloric effect (ECE). Here, we point out that negative ECE with a fast cooling rate ($\approx$10$^{11}$ K/s) can be…
Recently, materials exhibiting colossal dielectric constant ($CDC$) have attracted significant attention because of their high dielectric constant and potential applications in electronic devices, such as high dielectric capacitors,…
The elastocaloric effect (eCE), referring to the thermal effect triggered by a uniaxial stress, provides a promising and versatile routine for green and high efficient thermal management. However, current eCE materials generally suffer from…
Magnetocaloric effect (MCE) was investigated in the single crystal of CsGd(MoO$_4$)$_2$ in the temperature range from 2 to 30 K and fields up to 5 T applied along the easy and hard magnetic axis. The analysis of specific heat and…
Compression of greenhouse gases still dominates the market of refrigeration devices. Although well stablished and efficient, this technology is neither safe for the environment nor able to be scaled down to nanoscale. Solid-state cooling…
Structural, dielectric, ferroelectric, energy storage properties, and electrocaloric effect were studied in lead-free ceramic Ba$_{0.95}$Ca$_{0.05}$Ti$_{0.89}$Sn$_{0.11}$O$_3$ (BCTSn) elaborated by sol-gel method. Phase purity structure was…
Solid state-refrigerants have generated worldwide interest owing to their growing potential for use in efficient and green cooling devices. Caloric effects could be obtained by manipulating their degrees of freedom such as magnetization,…
An applied electric field can reversibly change the temperature of an electrocaloric material under adiabatic conditions, and the effect is strongest near phase transitions. This phenomenon has been largely ignored because only small…
Metal-stuffed B$-$C compounds with sodalite clathrate structure have captured increasing attention due to their predicted exceptional superconductivity above liquid nitrogen temperature at ambient pressure. However, by neglecting the…