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Related papers: Fluctuating Hydrodynamics and Debye-H\"uckel-Onsag…

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In this letter we analyze the effects of an externally applied electric field on thermal fluctuations for a fluid containing charged species. We show in particular that the fluctuating Poisson-Nernst-Planck equations for charged…

At mesoscopic scales electrolyte solutions are modeled by the fluctuating generalized Poisson-Nernst-Planck (PNP) equations [J.-P. P\'eraud et al., Phys. Rev. F, 1(7):074103, 2016]. However, at length and time scales larger than the Debye…

Computational Physics · Physics 2019-04-10 Aleksandar Donev , Andrew J. Nonaka , Changho Kim , Alejandro L. Garcia , John B. Bell

We evaluate the exponentially rare fluctuations of the ionic current for a dilute electrolyte by means of macroscopic fluctuation theory. We consider the fluctuating hydrodynamics of a fluid electrolyte described by a stochastic…

Statistical Mechanics · Physics 2025-07-25 Jafar Farhadi , David T. Limmer

We study the transport properties of dilute electrolyte solutions on the basis of the fluctuating hydrodynamic equation, which is a set of nonlinear Langevin equations for the ion densities and flow velocity. The nonlinearity of the…

Statistical Mechanics · Physics 2022-09-22 Ryuichi Okamoto

The stochastic dynamics of tracers arising from hydrodynamic fluctuations in a driven electrolyte is studied using a self-consistent field-theory framework in all dimensions. A plethora of scaling behaviour that includes two distinct…

Soft Condensed Matter · Physics 2026-02-12 Ramin Golestanian

Near-critical thermodynamics in the hard-sphere (1,1) electrolyte is well described, at a classical level, by Debye-Hueckel (DH) theory with (+,-) ion pairing and dipolar-pair-ionic-fluid coupling. But DH-based theories do not address…

Condensed Matter · Physics 2009-10-28 Benjamin P. Lee , Michael E. Fisher

We formulate and study computationally the low Mach number fluctuating hydrodynamic equations for electrolyte solutions. We are interested in studying transport in mixtures of charged species at the mesoscale, down to scales below the Debye…

The paper presents a mean field theory of electrolyte solutions, extending the classical Debye-H\"{u}ckel-Onsager theory to provide a detailed description of the electrical conductivity in strong electrolyte solutions. The theory…

Soft Condensed Matter · Physics 2024-09-27 N. N. Kalikin , Yu. A. Budkov

Dissipative processes in relativistic fluids are known to be important in the analyses of the hot QCD matter created in high-energy heavy-ion collisions. In this work, I consider dissipative corrections to energy and conserved charge…

Nuclear Theory · Physics 2018-10-08 Akihiko Monnai

A Maxwell-Stefan system for fluid mixtures with driving forces depending on Cahn-Hilliard-type chemical potentials is analyzed. The corresponding parabolic cross-diffusion equations contain fourth-order derivatives and are considered in a…

Analysis of PDEs · Mathematics 2022-05-16 Xiaokai Huo , Ansgar Jüngel , Athanasios E. Tzavaras

Starting from the kinetic equations for the fluctuations and correlations of a dilute gas of inelastic hard spheres or disks, a Boltzmann-Langevin equation for the one-particle distribution function of the homogeneous cooling state is…

Statistical Mechanics · Physics 2015-05-13 J. Javier Brey , P. Maynar , M. I. Garcia de Soria

The conductivity of ionic solutions is arguably their most important trait, being widely used in electrochemical, biochemical, and environmental applications. The Debye-H\"uckel-Onsager theory successfully predicts the conductivity at very…

Soft Condensed Matter · Physics 2023-01-03 Yael Avni , Ram M. Adar , David Andelman , Henri Orland

Electrolyte solutions play an important role in energy storage devices, whose performance highly relies on the electrokinetic processes at sub-micron scales.\ Although fluctuations and stochastic features become more critical at small…

Soft Condensed Matter · Physics 2022-06-08 Mingge Deng , Faisal Tushar , Luis Bravo , Anindya Ghoshal , George Karniadakis , Zhen Li

We present a method to embed local electroneutrality within Onsager-Stefan-Maxwell electrolytic-transport models, circumventing their formulation as differential systems with an algebraic constraint. Flux-explicit transport laws are…

Fluid Dynamics · Physics 2022-11-28 Alexander Van-Brunt , Patrick E. Farrell , Charles W. Monroe

In this paper we discuss the formulation of the fuctuating Navier-Stokes (FNS) equations for multi-species, non-reactive fluids. In particular, we establish a form suitable for numerical solution of the resulting stochastic partial…

Fluid Dynamics · Physics 2014-01-17 Kaushik Balakrishnan , Alejandro L. Garcia , Aleksandar Donev , John B. Bell

We study thermal fluctuation corrections to charge and heat conductivity in systems with locally conserved energy and charge, but without locally conserved momentum. Thermal fluctuations may naturally lead to a lower bound on diffusion…

Statistical Mechanics · Physics 2015-07-22 Pavel Kovtun

The authors in a previous paper proved the hydrodynamic incompressible limit in $d\ge 3$ for a thermal lattice gas, namely a law of large numbers for the density, velocity field and energy. In this paper the equilibrium fluctuations for…

Mathematical Physics · Physics 2007-05-23 O. Benois , R. Esposito , R. Marra

We consider a binary mixture of chemically active particles, that produce or consume solute molecules, and that interact with each other through the long-range concentrations fields they generate. We analytically calculate the effective…

Soft Condensed Matter · Physics 2024-04-09 Pierre Illien , Ramin Golestanian

The existence of large-data weak solutions to a steady compressible Navier-Stokes-Fourier system for chemically reacting fluid mixtures is proved. General free energies are considered satisfying some structural assumptions, with a pressure…

Analysis of PDEs · Mathematics 2024-06-19 Miroslav Buliček , Ansgar Jüngel , Milan Pokorný , Nicola Zamponi

We obtain the equations of fluctuating hydrodynamics for many-particle systems whose microscopic units have both translational and rotational motion. The orientational dynamics of each element are studied in terms of the rotational Brownian…

Statistical Mechanics · Physics 2025-01-20 Akira Yoshimori , Shankar P. Das
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