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Lead halide perovskite solar cells have recently emerged as a very promising photovoltaic technology due to their excellent power conversion efficiencies; however, the toxicity of lead and the poor stability of perovskite materials remain…

Materials Science · Physics 2017-03-10 Xiaolei Li , Xiangli Zhong , Yue Hu , Bochao Li , Yusong Sheng , Yang Zhang , Chao Weng , Ming Feng , Hongwei Han , Jinbin Wang

Lead poisoning and notorious ambient instability in lead-based halide perovskites pave the way for the exploration of alternative materials for affordable and efficient solar cell fabrication. An important prerequisite to this end is the…

The long-term chemical instability and the presence of toxic Pb in otherwise stellar solar absorber APbX$_{3}$ have hindered their large-scale commercialization. Previously explored ways to achieve Pb-free halide perovskites involved…

Materials Science · Physics 2017-05-29 Xin-Gang Zhao , Dongwen Yang , Yuanhui Sun , Tianshu Li , Lijun Zhang , Liping Yu , Alex Zunger

Alkali antimonide semiconductor photocathodes provide a promising platform for the generation of high brightness electron beams, which are necessary for the development of cutting-edge probes including x-ray free electron lasers and…

Lead halide perovskites have catalyzed the rise of main-group metal halide materials as promising candidates for next-generation optoelectronics, including solar cells, light-emitting diodes, lasers, sensors, and photocatalysts. Among…

Alkali-metal antimonides, especially cesium-potassium-antimonide (CsK2Sb), are strong candidates for next-generation photocathodes in linear accelerators due to their low work-function, fast response, high quantum yield, and ability to…

Materials Science · Physics 2025-07-28 Sandip Aryal , Gaoxue Wang , Enrique R. Batista

Antiperovskite nitrides are potential candidates for applications harvesting solar light. With a comprehensive state-of-the-art approach combining hybrid density-functional theory, many-body perturbation theory, the Wannier-Mott model,…

Materials Science · Physics 2024-04-26 Sanchi Monga , Manjari Jain , Claudia Draxl , Saswata Bhattacharya

Chalcogenide perovskites have received considerable interest in photovoltaic research community owing to their stability (thermal and aqueous), non-toxicity and lead free composition. However, to date a theoretical study mainly focusing on…

Materials Science · Physics 2022-07-13 Pooja Basera , Saswata Bhattacharya

Recent advances in experimental techniques and computational methods have significantly expanded the family of alkali antimonides, a class of semiconducting materials used as photocathodes in particle accelerators, unveiling new crystal…

Materials Science · Physics 2025-03-11 Richard Schier , Caterina Cocchi

Conventional semiconductors such as silicon and InGaAs based photodetectors have encountered a bottleneck in modern electronics and photonics in terms of spectral coverage, low resolution, non-transparency, non-flexibility and…

Applied Physics · Physics 2019-04-24 Nengjie Huo , Gerasimos Konstantatos

Transparent oxides are essential building blocks to many technologies, ranging from components in transparent electronics, transparent conductors, to absorbers and protection layers in photovoltaics and photoelectrochemical devices.…

We theoretically investigate Sn(II) phosphates as optoelectronic materials using first principles calculations. We focus on known prototype materials Sn$_n$P$_2$O$_{5+n}$ (n=2, 3, 4, 5) and a previously unreported compound, SnP$_2$O$_6$…

Materials Science · Physics 2016-12-06 Qiaoling Xu , Yuwei Li , Lijun Zhang , Weitao Zheng , David J. Singh , Yanming Ma

Bismuth oxide iodide (BiOI) has been viewed as a suitable environmentally-friendly alternative to lead-halide perovskites for low-cost (opto-)electronic applications such as photodetectors, phototransistors and sensors. To enable its…

Organic-inorganic halide perovskites, especially methylammonium lead halide, have recently led to a remarkable breakthrough in photovoltaic devices. However, due to the environmental and stability concerns of the heavy metal, lead, in these…

Materials Science · Physics 2015-09-29 Shijing Sun , Satoshi Tominaka , Jung-Hoon Lee , Fei Xie , Paul D. Bristowe , Anthony K. Cheetham

The recently emerged organohalide perovskites (e.g., CH3NH3PbI3) have drawn intense attention for high efficiency solar cells. However, with a considerable solubility in many solvents, these perovskites are not typically compatible with…

Halide perovskites are promising materials for light-emitting and light-harvesting applications. In this context, two-dimensional perovskites such as nanoplatelets or Ruddlesden-Popper and Dion-Jacobson layered structures are important…

Applied Physics · Physics 2021-10-25 Sushant Ghimire , Christian Klinke

The nitride semiconductor materials GaN, AlN, and InN, and their alloys and heterostructures have been investigated extensively in the last 3 decades, leading to several technologically successful photonic and electronic devices. Just over…

Wide band gap semiconductors are essential for today's electronic devices and energy applications due to their high optical transparency, as well as controllable carrier concentration and electrical conductivity. There are many categories…

In this work, we conduct a comprehensive first-principles investigation into the design and discovery of novel antimony oxychalcogenide monolayers Sb2X2O (X = S, Se) and Janus Sb2SSeO, examining their structural stability, elastic,…

Mesoscale and Nanoscale Physics · Physics 2026-02-10 Masoud Shahrokhi , Bohayra Mortazavi

Entirely inorganic perovskites have attracted enormous attention of late owing to their outstanding applications in optoelectronics including highly stable perovskite solar cells. In-depth understanding of the optoelectronic and transport…

Materials Science · Physics 2019-09-26 Anupriya Nyayban , Subhasis Panda , Avijit Chowdhury , B. Indrajit Sharma